Generation of Nickel Siloxycarbene Complexes from Acylsilanes for the Catalytic Synthesis of Silyl Enol Ethers DOI

Akihisa Matsuura,

Yuri Ito,

Tetsuya Inagaki

и другие.

ACS Catalysis, Год журнала: 2024, Номер unknown, С. 18216 - 18222

Опубликована: Ноя. 25, 2024

A catalytic protocol has been developed to access Fischer carbene nickel complexes using acylsilanes as stable and readily available precursors. The as-generated exhibit versatile reactivity, including cyclopropanation with alkenes, α-C–H insertion reactions, two-component C–H addition norbornene, which demonstrates the broad utility of nickel(0)/acylsilane system for applications complexes.

Язык: Английский

Radical Brook rearrangement: past, present, and future DOI
Yunxiao Zhang, Gang Zhou, Shanshan Liu

и другие.

Chemical Society Reviews, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

This review aims to provide an overview of radical Brook rearrangement, which is organized by grouping three type reactive species generated via the unique rearrangement process.

Язык: Английский

Процитировано

1
Generation of Nickel Siloxycarbene Complexes from Acylsilanes for the Catalytic Synthesis of Silyl Enol Ethers DOI

Akihisa Matsuura,

Yuri Ito,

Tetsuya Inagaki

и другие.

ACS Catalysis, Год журнала: 2024, Номер unknown, С. 18216 - 18222

Опубликована: Ноя. 25, 2024

A catalytic protocol has been developed to access Fischer carbene nickel complexes using acylsilanes as stable and readily available precursors. The as-generated exhibit versatile reactivity, including cyclopropanation with alkenes, α-C–H insertion reactions, two-component C–H addition norbornene, which demonstrates the broad utility of nickel(0)/acylsilane system for applications complexes.

Язык: Английский

Процитировано

1