Industrial carbon dioxide capture and utilization: state of the art and future challenges

Chemical Society Reviews, Год журнала: 2020, Номер 49(23), С. 8584 - 8686

Опубликована: Янв. 1, 2020

This review covers the sustainable development of advanced improvements in CO₂capture and utilization.

Язык: Английский

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Electrocatalysis for CO₂conversion: from fundamentals to value-added products

Chemical Society Reviews, Год журнала: 2021, Номер 50(8), С. 4993 - 5061

Опубликована: Янв. 1, 2021

This timely and comprehensive review mainly summarizes advances in heterogeneous electroreduction of CO₂: from fundamentals to value-added products.

Язык: Английский

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Continuous production of pure liquid fuel solutions via electrocatalytic CO2 reduction using solid-electrolyte devices

Nature Energy, Год журнала: 2019, Номер 4(9), С. 776 - 785

Опубликована: Сен. 2, 2019

Язык: Английский

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Structural defects on converted bismuth oxide nanotubes enable highly active electrocatalysis of carbon dioxide reduction

Nature Communications, Год журнала: 2019, Номер 10(1)

Опубликована: Июнь 26, 2019

Abstract Formic acid (or formate) is suggested to be one of the most economically viable products from electrochemical carbon dioxide reduction. However, its commercial viability hinges on development highly active and selective electrocatalysts. Here we report that structural defects have a profound positive impact electrocatalytic performance bismuth. Bismuth oxide double-walled nanotubes with fragmented surface are prepared as template, cathodically converted defective bismuth nanotubes. This electrocatalyst enables reduction formate excellent activity, selectivity stability. Most significantly, current density reaches ~288 mA cm −2 at −0.61 V versus reversible hydrogen electrode within flow cell reactor under ambient conditions. Using functional theory calculations, activity rationalized outcome abundant sites stabilize *OCHO intermediate. Furthermore, this coupled silicon photocathodes achieves high-performance photoelectrochemical

Язык: Английский

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Multifunctional Transition Metal‐Based Phosphides in Energy‐Related Electrocatalysis

Advanced Energy Materials, Год журнала: 2019, Номер 10(11)

Опубликована: Сен. 24, 2019

Abstract The exploitation of cheap and efficient electrocatalysts is the key to make energy‐related electrocatalytic techniques commercially viable. In recent years, transition metal phosphides (TMPs) have gained a great deal attention owing their multifunctional active sites, tunable structure, composition, as well unique physicochemical properties. This review summarizes up‐to‐date progress on TMPs in electrocatalysis from diversified synthetic methods, ingenious‐modulated strategies, novel applications. order set forth theory–structure–performance relationships upon TMPs, corresponding reaction mechanisms, electrocatalytsts' structure/composition designs desired electrochemical performance are jointly discussed, along with demonstrating practical applications overall water splitting, metal–air batteries, lithium–sulfur etc. end, some underpinning issues research orientations toward briefly proposed.

Язык: Английский

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Promises of Main Group Metal–Based Nanostructured Materials for Electrochemical CO₂ Reduction to Formate

Advanced Energy Materials, Год журнала: 2019, Номер 10(11)

Опубликована: Дек. 13, 2019

Abstract Selective CO 2 reduction to formic acid or formate is the most technologically and economically viable approach realize electrochemical valorization. Main group metal–based (Sn, Bi, In, Pb, Sb) nanostructured materials hold great promise, but are still confronted with several challenges. Here, current status, challenges, future opportunities of main for reviewed. Firstly, fundamentals presented, including technoeconomic viability different products, possible reaction pathways, standard experimental procedure, performance figures merit. This then followed by detailed discussions about types electrocatalyst materials, an emphasis on underlying material design principles promoting activity, selectivity, stability. Subsequently, recent efforts flow cells membrane electrode assembly reviewed so as promote density well mechanistic studies using in situ characterization techniques. To conclude a short perspective offered directions this exciting field.

Язык: Английский

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Heterogeneous Single‐Atom Catalysts for Electrochemical CO₂ Reduction Reaction

Advanced Materials, Год журнала: 2020, Номер 32(34)

Опубликована: Июль 9, 2020

The electrochemical CO2 reduction reaction (CO2 RR) is of great importance to tackle the rising concentration in atmosphere. RR can be driven by renewable energy sources, producing precious chemicals and fuels, with implementation this process largely relying on development low-cost efficient electrocatalysts. Recently, a range heterogeneous potentially single-atom catalysts (SACs) containing non-precious metals coordinated earth-abundant elements have emerged as promising candidates for RR. Unfortunately, real catalytically active centers key factors that govern catalytic performance these SACs remain ambiguous. Here, ambiguity addressed developing fundamental understanding RR-to-CO SACs, CO accounts major product from SACs. mechanism, rate-determining steps, control activity selectivity are analyzed both experimental theoretical studies. Then, synthesis, characterization, discussed. Finally, challenges future pathways highlighted hope guiding design promote understand

Язык: Английский

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Active Site Engineering in Porous Electrocatalysts

Advanced Materials, Год журнала: 2020, Номер 32(44)

Опубликована: Июль 14, 2020

Abstract Electrocatalysis is at the center of many sustainable energy conversion technologies that are being developed to reduce dependence on fossil fuels. The past decade has witnessed significant progresses in exploitation advanced electrocatalysts for diverse electrochemical reactions involved electrolyzers and fuel cells, such as hydrogen evolution reaction (HER), oxygen reduction (ORR), CO 2 (CO RR), nitrogen (NRR), (OER). Herein, recent research advances made porous these five important reviewed. In discussions, an attempt highlight advantages multiobjective optimization surface active sites including not only their density accessibility but also intrinsic activity. First, current knowledge about electrocatalytic briefly summarized. Then, mechanisms above‐mentioned (HER, ORR, RR, NRR, OER), challenges faced by reactions, efforts meet using examined. Finally, future directions synthetic strategies leading materials, insights into sites, standardized tests performance requirements discussed.

Язык: Английский

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An industrial perspective on catalysts for low-temperature CO2 electrolysis

Nature Nanotechnology, Год журнала: 2021, Номер 16(2), С. 118 - 128

Опубликована: Янв. 11, 2021

Язык: Английский

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Bismuthene for highly efficient carbon dioxide electroreduction reaction

Nature Communications, Год журнала: 2020, Номер 11(1)

Опубликована: Фев. 27, 2020

Abstract Bismuth (Bi) has been known as a highly efficient electrocatalyst for CO 2 reduction reaction. Stable free-standing two-dimensional Bi monolayer (Bismuthene) structures have predicted theoretically, but never realized experimentally. Here, we show the first simple large-scale synthesis of Bismuthene, to our knowledge, and demonstrate its high electrocatalytic efficiency formate (HCOO − ) formation from The catalytic performance is evident by Faradaic (99% at −580 mV vs. Reversible Hydrogen Electrode (RHE)), small onset overpotential (<90 mV) durability (no decay after 75 h annealing 400 °C). Density functional theory calculations structure-sensitivity reaction over Bismuthene thicker nanosheets, suggesting that selective HCOO indeed can proceed easily on (111) facet due unique compressive strain. This work paves way extensive experimental investigation in many different fields.

Язык: Английский

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