Journal of Materials Chemistry A,
Год журнала:
2020,
Номер
8(42), С. 21947 - 21960
Опубликована: Янв. 1, 2020
This
review
summarizes
recent
progress
in
the
development
of
metal-based
electrocatalysts
for
reduction
CO2
to
formic
acid/formate.
The
current
challenges
and
future
research
directions
materials
are
also
proposed.
Angewandte Chemie International Edition,
Год журнала:
2021,
Номер
60(16), С. 8798 - 8802
Опубликована: Янв. 29, 2021
Abstract
Formic
acid
(HCOOH)
is
one
of
the
most
promising
chemical
fuels
that
can
be
produced
through
CO
2
electroreduction.
However,
catalysts
for
electroreduction
to
HCOOH
in
aqueous
solution
often
suffer
from
low
current
density
and
limited
production
rate.
Herein,
we
provide
a
bismuth/cerium
oxide
(Bi/CeO
x
)
catalyst,
which
exhibits
not
only
high
(149
mA
cm
−2
),
but
also
unprecedented
rate
(2600
μmol
h
−1
with
Faradaic
efficiency
(FE,
92
%)
generation
media.
Furthermore,
Bi/CeO
shows
favorable
stability
over
34
h.
We
hope
this
work
could
offer
an
attractive
strategy
develop
efficient
superior
activity
desirable
stability.
Advanced Functional Materials,
Год журнала:
2020,
Номер
31(10)
Опубликована: Дек. 8, 2020
Abstract
Bismuth
(Bi),
as
a
nontoxic
and
inexpensive
diamagnetic
heavy
metal,
has
recently
been
utilized
for
the
preparation
of
variety
nanomaterials,
such
nanoparticles,
nanowires,
nanotubes,
nanosheets,
etc.,
with
tunable
bandgap,
unique
structure,
excellent
physicochemical
properties,
compositional
features
versatile
near‐infrared
absorbance,
high
X‐ray
attenuation
coefficient,
photothermal
conversion
efficiency,
long
circulation
half‐life.
These
have
endowed
mono‐elemental
Bi
nanomaterials
desirable
performances
electronics/optoelectronics,
energy
storage
conversion,
catalysis,
nonlinear
photonics,
sensors,
biomedical
applications,
etc.
This
review
summarizes
controlled
synthesis
different
shapes
sizes,
highlights
state‐of‐the‐art
progress
desired
applications
presents
some
personal
insights
on
challenges
future
opportunities
in
this
research
area.
It
is
hoped
that
controllable
manipulation
techniques
along
their
can
shed
light
next‐generation
devices
based
nanostructures
Bi‐related
nanomaterials.
Chemical Society Reviews,
Год журнала:
2019,
Номер
49(1), С. 263 - 285
Опубликована: Дек. 11, 2019
This
review
explores
the
fundamentals
of
2D
bismuth,
its
improved
fabrication
methods,
and
theoretical–experimental
achievements
in
energy-related
applications.
Journal of Materials Chemistry A,
Год журнала:
2020,
Номер
8(42), С. 21947 - 21960
Опубликована: Янв. 1, 2020
This
review
summarizes
recent
progress
in
the
development
of
metal-based
electrocatalysts
for
reduction
CO2
to
formic
acid/formate.
The
current
challenges
and
future
research
directions
materials
are
also
proposed.