Renewable and Sustainable Energy Reviews,
Год журнала:
2024,
Номер
200, С. 114577 - 114577
Опубликована: Май 21, 2024
Digitalization
of
lithium-ion
batteries
can
significantly
advance
the
performance
improvement
by
enabling
smarter
controlling
strategies
during
operation
and
reducing
risk
expenses
in
design
development
phase.
Accurate
physics-based
models
play
a
crucial
role
digitalization
providing
an
in-depth
understanding
system.
Unfortunately,
high
accuracy
comes
at
cost
increased
computational
preventing
employment
these
real-time
applications
for
parametric
design.
Machine
learning
have
emerged
as
powerful
tools
that
are
increasingly
being
used
battery
studies.
Hybrid
be
developed
integrating
machine
algorithms
well
efficiency.
Therefore,
this
paper
presents
comprehensive
review
current
trends
integration
to
accelerate
batteries.
Firstly,
direction
explicit
modeling
methods
research
reviewed.
Then
thorough
investigation
contemporary
hybrid
is
presented
addressing
both
monitoring
control.
The
objective
work
provide
details
including
various
applications,
type
employed
algorithms,
architecture
models,
outcome
proposed
models.
challenges
gaps
discussed
aiming
inspiration
future
works
field.
Nano-Micro Letters,
Год журнала:
2024,
Номер
16(1)
Опубликована: Янв. 25, 2024
Abstract
The
practical
application
of
aqueous
zinc-ion
batteries
for
large-grid
scale
systems
is
still
hindered
by
uncontrolled
zinc
dendrite
and
side
reactions.
Regulating
the
electrical
double
layer
via
electrode/electrolyte
interface
an
effective
strategy
to
improve
stability
Zn
anodes.
Herein,
we
report
ultrathin
zincophilic
ZnS
as
a
model
regulator.
At
given
cycling
current,
cell
with
Zn@ZnS
electrode
displays
lower
potential
drop
over
Helmholtz
(stern
layer)
suppressed
diffuse
layer,
indicating
regulated
charge
distribution
decreased
electric
repulsion
force.
Boosted
adsorption
sites
are
also
expected
proved
enhanced
double-layer
capacitance.
Consequently,
symmetric
protection
can
stably
cycle
around
3,000
h
at
1
mA
cm
−2
overpotential
25
mV.
When
coupled
I
2
/AC
cathode,
demonstrates
high
rate
performance
160
mAh
g
−1
0.1
A
long
10,000
cycles
10
.
Zn||MnO
sustains
both
capacity
130
after
1,200
0.5
Single-layered
MoS2
is
a
promising
anode
material
for
lithium-ion
batteries
(LIBs),
sodium-ion
(SIBs),
and
potassium-ion
(PIBs)
due
to
its
high
capacity
isotropic
ion
transport
paths.
However,
the
low
intrinsic
conductivity
easy-agglomerated
feature
hamper
applications.
Here,
charge-driven
interlayer
expansion
strategy
that
Co2+
replaces
Mo4+
in
doping
form
endow
layers
with
negative
charges,
thus
inducing
electrostatic
repulsion,
together
insertion
of
gaseous
groups,
drive
which
once
breaks
confinement
van
der
Waals
force,
single-layered
obtained
uniformly
dispersed
into
carbon
matrix
arising
from
transformation
carbonaceous
groups
under
vapor
pressure,
proposed.
Co
atom
helps
enhance
.
Carbon
effectively
prevents
agglomeration
The
doped
atoms
can
be
fully
transformed
ultrasmall
nanoparticles
during
conversion
reaction,
enables
strong
spin-polarized
surface
capacitance
significantly
boosts
storage.
Consequently,
prepared
delivers
superb
Li/Na/K-ion
storage
performances,
are
best
reported
-based
anodes.
proposed
provides
novel
perspective
preparing
MoS2,
shows
huge
potential
energy
Advanced Functional Materials,
Год журнала:
2024,
Номер
34(24)
Опубликована: Янв. 23, 2024
Abstract
Lithium
(Li)
metal
has
emerged
as
a
viable
alternative
anode
material
to
address
the
current
energy
density
shortfalls
in
Li
batteries.
However,
its
integration
into
widespread
implementation
remains
somewhat
constrained
due
substandard
reversibility
issues
and
safety
concerns
arising
from
erratic
deposition.
To
effectively
tackle
these
obstacles,
considerable
endeavors
have
been
exerted
modulate
morphology
of
Nevertheless,
it
is
exceedingly
challenging
for
nuclei
that
tend
dendritic
growth
thermodynamically
transform
dense
morphologies
during
their
process.
Therefore,
crucial
understand
what
influences
formation
process
how
improve
state
nuclei.
Herein,
nucleation
mechanisms
involving
mass
transport
across
solid
electrolyte
interface
electrode
interfacial
reactions
are
elucidated.
Inspired
by
understanding
nucleation,
corresponding
design
principles,
including
enhancing
homogenizing
transport,
stabilizing
film,
regulating
surface
interaction/selection,
summarized
optimizing
further
inducing
dendrite‐free
In
light
competition
among
perspective
on
existing
challenges
opportunities
promoting
application
batteries
proposed.
Angewandte Chemie International Edition,
Год журнала:
2021,
Номер
61(7)
Опубликована: Дек. 2, 2021
We
propose
self-expanding
lithium-ion
transport
channels
to
construct
a
fast-charging
anode
and
realize
high-performance
Li-ion
batteries.
The
self-expanded
can
be
enabled
by
self-reversible
conversion
of
chemical
bonds
with
different
bond
lengths
in
the
driven
interactions
Li
ions
during
cycling,
reduce
energy
barrier
allow
fast
solid-state
diffusion,
whereby
severe
voltage
polarization
metal
plating
are
effectively
eliminated.
Our
proof-of-concept
demonstration
on
surface
graphdiyne
successfully
verifies
channels,
self-accelerated
in-plane/out-of-plane
migration,
superior
capability
high
capacity
(342
mA
h
g-1
)
an
ultra-long
lifespan
(22
000
cycles)
under
extremely
conditions
(6
C
rate,
1
C=744
),
even
at
low
temperatures
(-10
°C).
Advanced Functional Materials,
Год журнала:
2022,
Номер
32(41)
Опубликована: Авг. 4, 2022
Abstract
Nonuniform
ion
flux
triggers
uneven
lithium
(Li)
deposition
and
continuous
dendrite
growth,
severely
restricting
the
lifetime
of
Li‐metal
batteries
(LMBs).
Herein,
an
electronegative
poly(pentafluorophenyl
acrylate)
(PPFPA)
polymer
brush‐grafted
Celgard
separator
signed
as
PPFPA‐g‐Celgard
is
designed
to
precisely
construct
one‐dimensionally
directed
Li
+
at
nanoscale
so
realize
faster
transport
ultra‐stable
deposition.
The
grafting
PPFPA
chains
enabled
by
simple
bio‐inspired
engineering
surface‐initiated
atom
transfer
radical
polymerization
chemistry.
Both
theoretical
experimental
analyses
demonstrate
obvious
increase
almost
two
times
in
affinity
kinetics
for
over
separator.
Reversible
stable
plating/stripping
can
be
realized
rapidly
switching
from
0.5
6
mA
cm
‐2
.
Besides,
|
LiFePO
4
full
cell
exhibits
universal
long‐term
cyclability
with
a
capacity
retention
83%
700
cycles
ether
electrolyte
92.9%
300
carbonate
well.
This
study
represents
new
direction
general
design
advanced
separators
typical
surface
topochemistry
self‐limited
channels
application
high‐performance
LMBs.
Nano-Micro Letters,
Год журнала:
2023,
Номер
15(1)
Опубликована: Март 31, 2023
High
theoretical
capacity
and
unique
layered
structures
make
MoS2
a
promising
lithium-ion
battery
anode
material.
However,
the
anisotropic
ion
transport
in
poor
intrinsic
conductivity
of
lead
to
unacceptable
capability.
Here,
we
propose
in-situ
construction
interlayer
electrostatic
repulsion
caused
by
Co2+
substituting
Mo4+
between
layers,
which
can
break
limitation
van
der
Waals
forces
fabricate
monolayer
MoS2,
thus
establishing
isotropic
paths.
Simultaneously,
doped
Co
atoms
change
electronic
structure
improving
its
conductivity.
Importantly,
be
converted
into
nanoparticles
create
space
charge
region
accelerate
transport.
Hence,
Co-doped
shows
ultrafast
lithium
capability
half/full
cells.
This
work
presents
novel
route
for
preparation
demonstrates
potential
application
fast-charging
batteries.