Recent Advances in Pristine Iron Triad Metal–Organic Framework Cathodes for Alkali Metal‐Ion Batteries

Small, Год журнала: 2024, Номер 20(23)

Опубликована: Янв. 4, 2024

Abstract Pristine iron triad metal–organic frameworks (MOFs), i.e., Fe‐MOFs, Co‐MOFs, Ni‐MOFs, and heterometallic MOFs, are utilized as versatile promising cathodes for alkali metal‐ion batteries, owing to their distinctive structure characteristics, including modifiable designable composition, multi‐electron redox‐active sites, exceptional porosity, stable construction facilitating rapid ion diffusion. Notably, pristine MOFs have recently achieved significant milestones in electrochemical energy storage due properties. Here, the recent advances batteries summarized. The redox reaction mechanisms essential strategies boost behaviors associated devices also explored. Furthermore, insights into future prospects related lithium‐ion, sodium‐ion, potassium‐ion delivered.

Язык: Английский

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Deriving multi-metal nanomaterials on metal–organic framework platforms for oxygen electrocatalysis

Energy & Environmental Science, Год журнала: 2024, Номер 17(12), С. 4010 - 4035

Опубликована: Янв. 1, 2024

Synthetic strategies and oxygen electrocatalytic applications of high-entropy alloy multi-metal nanomaterials derived on metal–organic frameworks.

Язык: Английский

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Mesopore and macropore engineering in metal–organic frameworks for energy environment-related applications

Journal of Materials Chemistry A, Год журнала: 2024, Номер 12(9), С. 4931 - 4970

Опубликована: Янв. 1, 2024

The fabrication strategies of mesopores and macropores in metal–organic frameworks (MOFs) their emerging applications are summarized. In addition, the challenges future perspectives pore engineering MOF design also indicated.

Язык: Английский

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Highly dispersed platinum and phosphomolybdic acid (PMo) on the UiO-66 metal–organic framework (MOF) for highly efficient and selective hydrogenation of nitroaromatics

Journal of Materials Chemistry A, Год журнала: 2024, Номер 12(35), С. 23940 - 23947

Опубликована: Янв. 1, 2024

Pt-PMo@UiO-66 (0.32 wt% Pt) shows the highest catalytic activity and selectivity to one –NO 2 hydrogenation in nitroarene due its novel structure synergism.

Язык: Английский

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Progress of 0D Biomass-Derived porous carbon materials produced by hydrothermal assisted synthesis for Advanced supercapacitors

Journal of Colloid and Interface Science, Год журнала: 2025, Номер 685, С. 487 - 508

Опубликована: Янв. 21, 2025

Язык: Английский

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Porosity Tunable Metal-Organic Framework (MOF)-Based Composites for Energy Storage Applications: Recent Progress

Polymers, Год журнала: 2025, Номер 17(2), С. 130 - 130

Опубликована: Янв. 8, 2025

To solve the energy crisis and environmental issues, it is essential to create effective sustainable conversion storage technologies. Traditional materials for however have several drawbacks, such as poor density inadequate efficiency. The advantages of MOF-based materials, pristine MOFs, also known porous coordination polymers, MOF composites, their derivatives, over traditional been thoroughly investigated. These stem from high specific surface area, highly adjustable structure, multifunctional nature. MOFs are promising technologies, according research on many applications. Moreover, served sacrificial synthesis different nanostructures applications support substrates metals, metal oxides, semiconductors, complexes. One most intriguing characteristics porosity, which permits space micro- meso-scales, revealing limiting functions. main goals high-porosity develop more efficient activation techniques preserve access pore space. This paper examines porosity tunable mixed hybrid MOF, architecture, physical chemical properties conditions, market size latest development precursors potential uses.

Язык: Английский

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Advanced Cathode Designs for High‐Energy Lithium/Sodium–Selenium Battery

Advanced Functional Materials, Год журнала: 2025, Номер unknown

Опубликована: Янв. 28, 2025

Abstract Selenium, with its superior conductivity, serves as a promising cathode material in lithium–selenium (Li–Se) and sodium–selenium (Na–Se) batteries, exhibiting faster electron transfer processes volumetric capacity. Nonetheless, challenges such volume expansion, the shuttle effect, slow redox reaction kinetics, low conductivity of discharged products still hinder their commercial application. Extensive research has been conducted on design optimization materials to overcome these issues. This review summarizes latest advancements Se within Li/Na–Se systems, based electrochemical mechanisms batteries origins related challenges. The comprehensive principle advanced stable selenium cathodes is put forward, key role carbon structure analyzed, strategies improve affinity selenide kinetics are discussed. Additionally, it introduces representative polymer‐based metal–organic framework (MOF)‐based cathodes. Some potential modification for active also highlighted, including sulfide composite lithium cathodes, which can significantly enhance Se‐based batteries. Finally, existing research, insights directions future development proposed.

Язык: Английский

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Application of metal-organic framework materials in supercapacitors

Journal of Energy Storage, Год журнала: 2025, Номер 113, С. 115535 - 115535

Опубликована: Фев. 8, 2025

Язык: Английский

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MOF‐Derived Transition Metal Phosphides for Supercapacitors

Small, Год журнала: 2025, Номер unknown

Опубликована: Фев. 25, 2025

Abstract Transition metal phosphides (TMPs) in supercapacitors (SCs) applications are increasingly attracting attention because of their exceptional electrochemical performance. MOF‐derived TMPs, possess high specific surface areas, rich pore structure, and controllable chemical compositions, offering promising opportunities for supercapacitor applications. There is a wide variety they exhibit different properties SCs. This work mainly categorizes TMPs (Fe x P, Co Ni y Cu P), then outlines the latest research advancements regarding use as electrode materials SCs, including results synthesis methods structural modulation. Subsequently, SCs discussed. At end, perspectives future developments key challenges highlighted, with aim providing guidance research.

Язык: Английский

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Bifunctional carbon-based cathode catalysts for zinc-air battery: A review

Chinese Chemical Letters, Год журнала: 2021, Номер 33(2), С. 683 - 692

Опубликована: Июль 20, 2021

Язык: Английский

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