Perovskite solar cells with high-efficiency exceeding 25%: A review

Energy Materials and Devices, Год журнала: 2024, Номер 2(1), С. 9370018 - 9370018

Опубликована: Фев. 2, 2024

Metal halide perovskite solar cells (PSCs) are one of the most promising photovoltaic devices. Over time, many strategies have been adopted to improve PSC efficiency, and certified efficiency has reached 26.1%. However, only a few research groups fabricated PSCs with an >25%, indicating that achieving this remains uncommon. To develop industry, outstanding talent must be reserved latest technologies. Herein, we summarize recent developments in high-efficiency (>25%) highlight their effective crystal regulation, interface passivation, component layer structural design. Finally, propose perspectives based on current further enhance promote commercialization process PSCs.

Язык: Английский

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Enhancing Performance of NiO_x‐Based Inverted Perovskite Solar Cells: Advances in Buried Interface Material Modification Strategy

Small, Год журнала: 2025, Номер unknown

Опубликована: Фев. 13, 2025

Abstract Inverted perovskite solar cells (PSCs) have become a current research hotspot due to their advantages such as low‐temperature preparation, low hysteresis, and compatibility with stacked other cells. NiO x , metal oxide hole transport layer material, is widely used in inverted PSCs. However, challenges high defect density, intrinsic conductivity, unfavorable valence band mismatch at the /perovskite interface hinder further improvement of device performance. Therefore, enhancing buried between layers crucial for optimizing This review systematically categorizes materials based on types, including organic small molecules, self‐assembled monolayers (SAMs), polymers, salts. Additionally, it incorporates strategies, introduction low‐dimensional materials, doping, advancements deposition technology. By reviewing technologies past 2 years, this article aims provide insights achieve more efficient stable ‐based Finally, we also discuss future directions challenges.

Язык: Английский

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Key Roles of Interfaces in Inverted Metal-Halide Perovskite Solar Cells

ACS Nano, Год журнала: 2024, Номер 18(16), С. 10688 - 10725

Опубликована: Апрель 11, 2024

Metal-halide perovskite solar cells (PSCs), an emerging technology for transforming energy into a clean source of electricity, have reached efficiency levels comparable to those commercial silicon cells. Compared with other types PSCs, inverted (IPSCs) shown promise regard commercialization due their facile fabrication and excellent optoelectronic properties. The interlayer interfaces play important role in the performance cells, not only affecting charge transfer transport, but also acting as barrier against oxygen moisture permeation. Herein, we describe summarize last three years studies that advantages interface engineering-based advances IPSCs. This review includes brief introduction structure working principle IPSCs, analyzes how affect IPSC devices from perspective photovoltaic device lifetime. In addition, comprehensive summary various engineering approaches solving these problems challenges including use interlayers, modification, defect passivation, others, is summarized. Moreover, based upon current developments breakthroughs, fundamental perspectives on future pathways are provided innovation design next-generation

Язык: Английский

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Eliminating Hole Extraction Barrier in 1D/3D Perovskite Heterojunction for Efficient and Stable Carbon‐Based CsPbI₃ Solar Cells with a Record Efficiency

Advanced Materials, Год журнала: 2024, Номер 36(33)

Опубликована: Июнь 17, 2024

Carbon-based perovskite solar cells (C-PSCs) have the advantages of low-cost and high-stability, but their photovoltaic performance is limited by severe defect-induced recombination low hole extraction efficiency. 1D proven to effectively passivate defects on surface, therefore reducing non-radiative loss. However, unsuitable energy level most renders an undesired downward band bending for 3D perovskite, resulting in a high barrier reduced Therefore, rational design selection perovskites as modifiers are essential balancing defect passivation extraction. In this work, based simulation calculations, thiocholine iodide (TchI) selected prepare with work function then constructs TchPbI

Язык: Английский

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Integration of One-Dimensional (1D) Lead-Free Perovskite Microbelts onto Silicon for Ultraviolet–Visible–Near-Infrared (UV-vis-NIR) Heterojunction Photodetectors

The Journal of Physical Chemistry Letters, Год журнала: 2024, Номер 15(9), С. 2359 - 2368

Опубликована: Фев. 23, 2024

Lead-free perovskites are considered to be candidates for next-generation photodetectors, because of their excellent charge carrier transport properties and low toxicity. However, application in integrated circuits is hindered by inadequate performance size restrictions. To aim at the development lead-free perovskite-integrated optoelectronic devices, a CsAg2I3/silicon (CAI/Si) heterojunction presented this work using spatial confinement growth method, where in-plane CAI microbelts with high-quality single-crystal characteristics primarily dependent on concentration surrounding precursor solution. The fabricated photodetectors based CAI/Si heterojunctions exhibit broad-spectrum detection capability ultraviolet–visible–near-infrared (UV-vis-NIR) range. In addition, show good photoelectric performance, including maximum responsivity 48.5 mA/W detectivity 1.13 × 1011 Jones, respectively. Besides, have rapid response 6.5/224 μs air stability over 2 months. This contributes new idea design devices high integration density.

Язык: Английский

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Polyfluorinated Organic Diammonium Induced Lead Iodide Arrangement for Efficient Two‐Step‐Processed Perovskite Solar Cells

Angewandte Chemie International Edition, Год журнала: 2024, Номер 63(26)

Опубликована: Апрель 23, 2024

The inefficient conversion of lead iodide to perovskite has become one the major challenges in further improving performance solar cells fabricated by two-step method. Herein, discontinuous layer realized introduction a polyfluorinated organic diammonium salt, octafluoro-([1,1'-biphenyl]-4,4'-diyl)-dimethanaminium (OFPP) which does not form low-dimensional perovskites, can enable satisfactory into perovskite, leading meliorated crystallinity and enlarged grains OFPP modulated (OFPP-PVK) film. Combined with effective defect passivation, OFPP-PVK films show enhanced charge mobility suppressed recombination. Accordingly, OFPP-based exhibit champion efficiency 24.76 % better device stability. Moreover, superior 21.04 was achieved large-area module (100 cm

Язык: Английский

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Mixed‐Halide Perovskites with Suppressed Phase Segregation for Large Modulation Depth and High‐Stability Terahertz Modulators

Small Structures, Год журнала: 2025, Номер unknown

Опубликована: Янв. 28, 2025

Metal‐halide perovskites with tunable bandgaps are promising semiconductors in heterojunction engineering for high‐performance terahertz modulators. However, most traditional perovskite‐based modulators reported so far difficult to simultaneously achieve both large modulation depth and high environmental stability a simple structure. To overcome this bottleneck, herein, the Cs 0.25 MA 0.75 PbI 2 Br/MAPbI 3 /Si dual‐heterojunction modulator is fabricated using two‐step spin‐coating method. In device, Br film formed by substituting − at X‐site + A‐site from MAPbI can not only tailor but also suppress phase segregation, while promote accumulation of photon‐generated electrons Si substrate. Moreover, maximum THz 71% 0.42 THz. Compared Br/Si or samples, be increased almost 100%. After continuous operation an environment 70% humidity 10 h, device still operate stably. This study illuminates potential devices, as well offers new strategies improve perovskites.

Язык: Английский

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Critical role of post-treatment induced surface reconstruction for high performance inorganic tin-lead perovskite solar cells

Chemical Engineering Journal, Год журнала: 2023, Номер 479, С. 147554 - 147554

Опубликована: Ноя. 22, 2023

Язык: Английский

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From lab to luminescence: Perovskite-based dimensional integrations pushing LED boundaries

Materials Today Physics, Год журнала: 2024, Номер 46, С. 101490 - 101490

Опубликована: Июнь 22, 2024

Язык: Английский

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Promoting the formation of metal–carboxylate coordination to modulate the dimensionality of ultrastable lead halide hybrids

Chemical Science, Год журнала: 2024, Номер 15(8), С. 2848 - 2856

Опубликована: Янв. 1, 2024

Crystal engineering of metal halide hybrids is critical to investigate their structure-property relationship and advance photophysical applications, but there have been limited efforts employ coordination chemistry precisely control the dimensionality sublattices. Herein, we present a coordination-assembly synthetic strategy developed for rational modulation lead dimensionality, realizing transition from 2D 3D architectures. This manipulation achieved by utilizing three organocarboxylates featuring identical cyclohexane backbone unit. Specifically, 1,4-cyclohexanedicarboxylate 1,2,4,5-cyclohexanetetracarboxylate ligands facilitate formation quasi-2D layered structures, characterized weakly corrugated strongly layers, respectively. Importantly, introduction 1,2,3,4,5,6-cyclohexanehexacarboxylate ligand results in architectures chloride/bromide The templated affords extended wavelength coverage superior carrier transport properties compared analogues. both halide-based polymers exhibit high aqueous stability over wide pH range, outperforming conventional ionic-bound halides. Notably, chemically stable bromide exhibits efficient photocatalytic ethylbenzene oxidation with conversion rate 498 μmol g

Язык: Английский

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