Hydrophilic and Insulative Interface Strategy Against Side Reactions for Dendrite‐Free Zinc Metal Anodes DOI Creative Commons
Kunlun Liu, Yifan Li, Tian Zhang

и другие.

Advanced Functional Materials, Год журнала: 2024, Номер 34(49)

Опубликована: Авг. 28, 2024

Abstract The zinc dendrite growth and the parasitic hydrogen evolution reactions (HER) hinder commercialization of batteries. To address this, a hydroxyl‐rich Boehmite coating (HR‐BC) strategy is developed that combines excellent electrical insulation high ion conductivity. hydrophilic hydroxyl groups facilitate bond formation with hydrated ions, accelerating de‐solvation process suppressing HER. Additionally, electrically insulative nature prevents reduction ions within HR‐BC results in preferential Zn deposition underneath it, leading to dendrite‐free “sandwich structure” HR‐BC//Zn deposition//Zn foil. Symmetric cells using HR‐BC‐Zn electrodes obtain an ultralong stable cycling lifetime 1700 h at 5 mA cm −2 , along cumulative plating capacity 4250 mAh . When paired V 2 O cathode, anode demonstrates capacitance retention 90% average Coulombic efficiency (CE) 99.8% after 4000 cycles. Furthermore, when combined heteroatoms‐doped carbon (HDC) HR–BC–Zn//HDC pouch‐type cell exhibits superior performance nearly 100% CE 15000 cycles 3.0 A g −1 This work highlights effectiveness strategies fostering progression long‐lasting zinc‐based energy storage systems.

Язык: Английский

Inhibition of Vanadium Cathodes Dissolution in Aqueous Zn‐Ion Batteries DOI Creative Commons
Yuhang Dai, Chengyi Zhang, Jianwei Li

и другие.

Advanced Materials, Год журнала: 2024, Номер 36(14)

Опубликована: Янв. 16, 2024

Aqueous zinc-ion batteries (AZIBs) have experienced a rapid surge in popularity, as evident from the extensive research with over 30 000 articles published past 5 years. Previous studies on AZIBs showcased impressive long-cycle stability at high current densities, achieving thousands or tens of cycles. However, practical low densities (<1C) is restricted to merely 50-100 cycles due intensified cathode dissolution. This genuine limitation poses considerable challenge their transition laboratory industry. In this study, leveraging density functional theory (DFT) calculations, an artificial interphase that achieves both hydrophobicity and restriction outward penetration dissolved vanadium cations, thereby shifting reaction equilibrium suppressing dissolution following Le Chatelier's principle, described. The approach has resulted one best cycling stabilities date, no noticeable capacity fading after more than 200 (≈720 h) mA g

Язык: Английский

Процитировано

133
Covalent Organic Framework with 3D Ordered Channel and Multi-Functional Groups Endows Zn Anode with Superior Stability DOI Creative Commons
Bin Li, Pengchao Ruan, Xieyu Xu

и другие.

Nano-Micro Letters, Год журнала: 2024, Номер 16(1)

Опубликована: Янв. 4, 2024

Abstract Achieving a highly robust zinc (Zn) metal anode is extremely important for improving the performance of aqueous Zn-ion batteries (AZIBs) advancing “carbon neutrality” society, which hampered by uncontrollable growth Zn dendrite and severe side reactions including hydrogen evolution reaction, corrosion, passivation, etc. Herein, an interlayer containing fluorinated zincophilic covalent organic framework with sulfonic acid groups (COF-S-F) developed on (Zn@COF-S-F) as artificial solid electrolyte interface (SEI). Sulfonic group (− SO 3 H) in COF-S-F can effectively ameliorate desolvation process hydrated ions, three-dimensional channel fluoride (-F) provide interconnected channels favorable transport ions ion-confinement effects, endowing Zn@COF-S-F dendrite-free morphology suppressed reactions. Consequently, symmetric cell stably cycle 1,000 h low average hysteresis voltage (50.5 mV) at current density 1.5 mA cm −2 . Zn@COF-S-F|MnO 2 delivers discharge specific capacity 206.8 mAh g −1 1.2 A after 800 cycles high-capacity retention (87.9%). Enlightening, building SEI metallic surface targeted design has been proved effective strategy to foster practical application high-performance AZIBs.

Язык: Английский

Процитировано

92
Universal F4‐Modified Strategy on Metal–Organic Framework to Chemical Stabilize PVDF‐HFP as Quasi‐Solid‐State Electrolyte DOI Open Access
Wenhuan Huang, Shun Wang,

Xingxing Zhang

и другие.

Advanced Materials, Год журнала: 2023, Номер 35(52)

Опубликована: Ноя. 21, 2023

Solid-state electrolytes (SSEs) based on metal organic framework (MOF) and polymer mixed matrix membranes (MMMs) have shown great promotions in both lithium-ion conduction interfacial resistance lithium batteries (LMBs). However, the unwanted structural evolution obscure electrochemical reaction mechanism among two phases limit their further optimization commercial application. Herein, fluorine-modified zirconium MOF with diverse F-quantities is synthesized, denoted as Zr-BDC-Fx (x = 0, 2, 4), to assemble high performance quais-solid-state (QSSEs) PVDF-HFP. The chemical complexation of F-sites Zr-BDC-F4 stabilized PVDF-HFP chains β-phase disordered oscillation enhanced charge transfer Li transmit property. Besides, porous confinement electronegativity F-groups capture dissociation TFSI- anions homogeneous deposition LiF solid electrolyte interphase (SEI), promoting high-efficient transport Li+ ions inhibiting growth dendrites. superb specific capacities high-loaded Li.

Язык: Английский

Процитировано

70
Gel polymer electrolytes for rechargeable batteries toward wide-temperature applications DOI Creative Commons
Xiaoyan Zhou,

Yifang Zhou,

Le Yu

и другие.

Chemical Society Reviews, Год журнала: 2024, Номер 53(10), С. 5291 - 5337

Опубликована: Янв. 1, 2024

Design principles, engineering strategies, challenges, and opportunities of gel polymer electrolytes for rechargeable batteries toward wide-temperature applications are thoroughly reviewed.

Язык: Английский

Процитировано

56
Glycine composed anode-electrolyte interphase induced Zn(002) deposition for highly reversible zinc anode DOI

Xincheng Liang,

Xingfa Chen,

Zhixiang Zhai

и другие.

Chemical Engineering Journal, Год журнала: 2023, Номер 480, С. 148040 - 148040

Опубликована: Дек. 14, 2023

Язык: Английский

Процитировано

46
Designing single-ion conductive electrolytes for aqueous zinc batteries DOI
Jin‐Lin Yang, Peihua Yang, Tao Xiao

и другие.

Matter, Год журнала: 2024, Номер 7(6), С. 1928 - 1949

Опубликована: Апрель 18, 2024

Язык: Английский

Процитировано

29
In Situ Spontaneous Construction of Zinc Phosphate Coating Layer Toward Highly Reversible Zinc Metal Anodes DOI

Shu Xia,

Qiuyang Luo,

Junnan Liu

и другие.

Small, Год журнала: 2024, Номер 20(29)

Опубликована: Фев. 13, 2024

Aqueous zinc ion batteries have received widespread attention due to their merits of high safety, theoretical specific capacity, low cost, and environmental benignity. Nevertheless, the irreversible issues Zn anode deriving from side reactions dendrite growth hindered its commercialization in large-scale energy storage systems. Herein, a phosphate tetrahydrate (Zn

Язык: Английский

Процитировано

22
Electrolyte Additive Strategies for Safe and High-Performance Aqueous Zinc-Ion Batteries: A Mini-Review DOI
Da Zhang, Ling Miao, Ziyang Song

и другие.

Energy & Fuels, Год журнала: 2024, Номер 38(14), С. 12510 - 12527

Опубликована: Июль 4, 2024

With outstanding safety and economic benefits, aqueous zinc-ion batteries (ZIBs) represent a highly promising energy system. As the "blood" of ZIBs, solid (electrode)/liquid (electrolyte) interface reactions transport rate zinc ions in electrolyte are crucial fields for long-term ZIBs. However, parasitic dendrite growth at electrode/electrolyte hinder practical application Thus, adjusting composition is valuable to reduce active-H2O molecules solvation structure realize textured anode. In this mini-review, electrochemical reaction dilemmas interfaces modification mechanism additives first summarized. Furthermore, we compare charge transfer storage methods among various additives. Notably, effects plating/stripping textures ((100), (101) (002) crystal planes) on reversibility metal anodes highlighted, providing more intuitive strategy epitaxial metal. Finally, specific applications perspectives ZIBs with outlined guide next-generation efficient storage.

Язык: Английский

Процитировано

22
Hydrophobic Ion Barrier‐Enabled Ultradurable Zn (002) Plane Orientation towards Long‐Life Anode‐Less Zn Batteries DOI
Guigui Liu, Yongchao Tang,

Yue Wei

и другие.

Angewandte Chemie International Edition, Год журнала: 2024, Номер unknown

Опубликована: Июль 8, 2024

Gradual disability of Zn anode and high negative/positive electrode (N/P) ratio usually depreciate calendar life energy density aqueous batteries (AZBs). Herein, within original

Язык: Английский

Процитировано

22
Reconstruction of zinc-metal battery solvation structures operating from −50 ~ +100 °C DOI Creative Commons

Lingbo Yao,

Jiahe Liu, Feifan Zhang

и другие.

Nature Communications, Год журнала: 2024, Номер 15(1)

Опубликована: Июль 24, 2024

Serious solvation effect of zinc ions has been considered as the cause severe side reactions (hydrogen evolution, passivation, dendrites, and etc.) aqueous metal batteries. Even though regulation cationic structure widely studied, effects anionic structures on were rarely examined. Herein, co-reconstruction was realized through constructing a new multi-component electrolyte (Zn(BF

Язык: Английский

Процитировано

22