Chemical Engineering Journal, Год журнала: 2024, Номер 497, С. 154812 - 154812
Опубликована: Авг. 13, 2024
Язык: Английский
Energy & Environmental Science, Год журнала: 2024, Номер 17(14), С. 4819 - 4846
Опубликована: Янв. 1, 2024
This review provides a comprehensive overview detailing the advancements in desolvation strategies pertaining to aqueous zinc-ion batteries (AZIBs) performances, addressing applications and working mechanisms of AZIBs.
Язык: Английский
Процитировано
70
National Science Review, Год журнала: 2024, Номер 11(7)
Опубликована: Июнь 13, 2024
ABSTRACT Irreversible interfacial reactions at the anodes pose a significant challenge to long-term stability and lifespan of zinc (Zn) metal batteries, impeding their practical application as energy storage devices. The plating stripping behavior Zn ions on polycrystalline surfaces is inherently influenced by microscopic structure anodes, comprehensive understanding which crucial but often overlooked. Herein, commercial foils were remodeled through incorporation cerium (Ce) elements via ‘pinning effect’ during electrodeposition process. By leveraging electron-donating effect Ce atoms segregated grain boundaries (GBs), electronic configuration restructured increase active sites for nucleation. This facilitates continuous nucleation throughout growth stage, leading high-rate instantaneous-progressive composite model that achieves spatially uniform distribution nuclei induces spontaneous refinement. Moreover, elevates site GBs, mitigating detrimental parasitic enhancing GB stability. Consequently, ZnCe electrode exhibits highly reversible plating/stripping with an accumulated capacity up 4.0 Ah cm−2 in symmetric cell over 4000 h without short-circuit behavior. Notably, ∼0.4 Zn||NH4V4O10 pouch runs 110 cycles 83% retention high-areal-loading cathode (≈20 mg cm−2). refining-grains strategy offers new insights into designing dendrite-free rechargeable batteries.
Язык: Английский
Процитировано
44
ACS Energy Letters, Год журнала: 2024, Номер 9(7), С. 3292 - 3307
Опубликована: Июнь 11, 2024
Aqueous zinc metal batteries (ZMBs) have attracted much attention in the field of grid-scale energy storage due to their high safety, low cost, and abundant resources. Zn powders exhibit unique advantages specific surface area, mature scaled-up manufacturing ability, structural tunability, which can meet large-scale devices, even special-shaped devices. However, powder-based anodes are at an early stage far from practical industrial application. With pursuit comprehensive electrochemical performances anodes, this review focus on advances, issues, optimized strategies, discussed systematically previous reports anodes. Meanwhile, we also added many supplementary discussions some important strategies relevant content but not yet reported. Finally, future prospects toward performance practicability proposed, will provide scientific guidance for application ZMBs.
Язык: Английский
Процитировано
24
Chemical Science, Год журнала: 2024, Номер 15(29), С. 11229 - 11266
Опубликована: Янв. 1, 2024
This paper reviews advancements in flexible carbon-based and polymer gel materials for various types of energy storage systems, providing guidance future development next-generation wearable electronics.
Язык: Английский
Процитировано
24
ACS Applied Energy Materials, Год журнала: 2024, Номер 7(11), С. 4745 - 4760
Опубликована: Май 31, 2024
The utilization of hydrogel (HG) electrolytes for aqueous zinc-ion batteries is a new emerging technology flexible and wearable electronics owing to their eco-friendliness, low cost, high safety, ease operation. In comparison with solid electrolytes, the electrolyte (HGE) carries an annexation individualities both liquid in terms mechanical strength ionic conductivity. However, it still technical hitch achieve that comply all necessities developing high-performance battery. Herein, newer type polymer-inorganic-based hybrid (HHGE) polyacrylamide (PAM)/Ti-MXene developed address aforementioned concerns. Among different wt % values Ti-MXene-incorporated PAM, PAM/Ti-MXene (0.1 %) HHGE shows higher conductivity 25.27 mS cm–1 electrochemical stability window (ESW) ∼2.7 V. Additionally, as-fabricated Zn//V2O5–CNT battery initial capacity 192 mAh g–1 at 0.05 Ag–1 Coulombic efficiency 100%.
Язык: Английский
Процитировано
16
Nano Letters, Год журнала: 2024, Номер 24(14), С. 4055 - 4063
Опубликована: Март 30, 2024
Aqueous rechargeable zinc-based batteries hold great promise for energy storage applications, with most research utilizing zinc foils as the anode. Conversely, high tunability of powder (Zn-P) makes it an ideal choice batteries, seamlessly integrating current battery production technologies. However, challenges such contact loss, dendrite formation, and a tendency corrosion significantly hamper performance enhancement Zn-P anodes. This review provides overview strategies adopted from various perspectives, including optimization, electrode engineering, electrolyte modification, to address these issues. Additionally, explores limitations existing offers valuable insights into potential future directions further advancements in
Язык: Английский
Процитировано
15
Advanced Energy Materials, Год журнала: 2024, Номер 14(32)
Опубликована: Июнь 5, 2024
Abstract Aqueous zinc metal batteries (AZMBs) have emerged as a focal point of interest in academic research and industrial strategic planning. Zinc powder (ZP) is poised to assume prominent position both future practical applications due its high Zn utilization rate processability. However, critical challenges need be addressed before realizing substantial progress. Notably, severe voltage polarization gas production ZP electrodes stand out the primary causes battery failure, differing with foil where short circuits caused by dendrites contribute failure. While numerous comprehensive reviews offered effective strategies for foil, systematic summary still lacking. For ZP, electrode preparation dictates performance. This review summarizes criteria optimal electrodes, covering components, methods, technique parameters. It emphatically introduces underlying water‐related side reactions briefly analyzes stripping/plating behaviors electrodes. The status quo ZP‐based then discussed categories current collector, conductive scaffold, binder, electrolytes. Finally, potential avenues are proposed from three aspects enhance focus on facilitate application AZMBs.
Язык: Английский
Процитировано
13
Rare Metals, Год журнала: 2024, Номер 43(10), С. 5005 - 5016
Опубликована: Июль 16, 2024
Язык: Английский
Процитировано
12
Science Bulletin, Год журнала: 2024, Номер unknown
Опубликована: Сен. 1, 2024
Язык: Английский
Процитировано
11
Angewandte Chemie International Edition, Год журнала: 2024, Номер 63(41)
Опубликована: Июль 22, 2024
Abstract The practical application of aqueous zinc‐ion batteries (ZIBs) indeed faces challenges primarily attributed to the inherent side reactions and dendrite growth associated with Zn anode. In present work, N‐Methylmethanesulfonamide (NMS) is introduced optimize transfer, desolvation, reduction 2+ , achieving highly stable reversible plating/stripping. NMS molecule can substitute one H 2 O in solvation structure hydrated be preferentially chemisorbed on surface protect anode against corrosion hydrogen evolution reaction (HER), thereby suppressing byproducts formation. Additionally, a robust N‐rich organic inorganic (ZnS ZnCO 3 ) hybrid solid electrolyte interphase situ generated due decomposition NMS, resulting enhanced transport kinetics uniform deposition. Consequently, cells achieve long lifespan 2300 h at 1 mA cm −2 mAh high cumulative plated capacity 3.25 Ah excellent reversibility an average coulombic efficiency (CE) 99.7 % over 800 cycles.
Язык: Английский
Процитировано
10