Journal of Materials Chemistry A, Год журнала: 2024, Номер 12(30), С. 18968 - 18976
Опубликована: Янв. 1, 2024
A scandium acetate electrolyte additive enables the improved stability of Zn metal anodes in an aqueous ZnSO 4 with suppressed side reactions and dendrite formation due to buffered pH value homogenized 2+ distribution.
Язык: Английский
Journal of Colloid and Interface Science, Год журнала: 2025, Номер 686, С. 878 - 887
Опубликована: Фев. 4, 2025
Язык: Английский
Процитировано
1
Energy & Environmental Science, Год журнала: 2024, Номер unknown
Опубликована: Янв. 1, 2024
A superelastic, high ionic conductivity and environment-friendly hydrogel electrolyte is developed based on the unique advantages of α-helical proteins.
Язык: Английский
Процитировано
6
Journal of Energy Storage, Год журнала: 2024, Номер 101, С. 113686 - 113686
Опубликована: Сен. 14, 2024
Язык: Английский
Процитировано
6
ACS Energy Letters, Год журнала: 2024, Номер 9(6), С. 2816 - 2825
Опубликована: Май 20, 2024
Zinc (Zn) powder-based anodes have garnered considerable attention as viable alternatives to their conventional Zn foil-based counterparts. However, challenges arising from undesirable interfacial side reactions and dendritic growth hinder practical implementation. Here, we present a class of liquid metal-skinned (LSZ) powder enabled by capillary suspension. The suspension strategy can overcome the miscibility metal with other components, resulting in self-standing uniform LSZ anode. nanothick eutectic gallium–indium (EGaIn) skin layer on powders facilitated horizontal along (002) plane mitigated corrosion hydrogen evolution reaction. Consequently, full cell (V2O5 cathode ∥ anode) exhibited stable capacity retention per cycle 99.99% over 2000 cycles at fast current rate 1 A g–1, outperforming those previously reported aqueous cells.
Язык: Английский
Процитировано
5
Batteries & Supercaps, Год журнала: 2024, Номер 7(6)
Опубликована: Март 11, 2024
Abstract The pursuit of alternative anode materials featuring inexpensive, efficient, and adaptable is shaping the future rechargeable zinc‐ion batteries. Zn powder anodes stand out among contenders due to their cost‐effectiveness, exceptional processability, adjustability. However, widespread use hampered by significant challenges, including volume expansion dendrite growth. To counter these issues, a gamut optimization strategies for has been explored developed. This review systematically encapsulates research findings, offering comprehensive understanding various enhancement methods, such as three‐dimensional printing, in‐situ surface engineering, scalable electrostatic self‐assembly, epoxy oligomer binding. These methodologies are discussed in detail context unique synthesis methods underlying mechanisms. paper concludes outlining prospective trajectories aimed at further optimizing aqueous batteries, thereby illuminating potential avenues exploration development.
Язык: Английский
Процитировано
4
Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 159895 - 159895
Опубликована: Янв. 1, 2025
Язык: Английский
Процитировано
0
Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 162372 - 162372
Опубликована: Апрель 1, 2025
Язык: Английский
Процитировано
0
Advanced Energy Materials, Год журнала: 2025, Номер unknown
Опубликована: Апрель 21, 2025
Abstract Aggressive side reactions and dendrite growth, associated with the unstable Zn anode/electrolyte interface, have impeded practical application of metal‐based batteries. Here, a donor‐acceptor (D‐A) polymer is employed to reconstruct robust supramolecular (SP) protective layer achieve highly stable anodes. The D‐A possessing abundant electron donor acceptor sites can dynamically co‐crosslink water molecules 2 ⁺ through multivalent dipole interactions (MDIs), resulting in formation network. MDIs disrupt original strong hydrogen‐bonding network within polymer, leading reconfiguration chain conformations an increase intermolecular free volume exposing more widely distributed dipoles, thereby regulating 2+ desolvation behavior facilitating rapid uniform plating. Meanwhile, resultant endows SP ultra‐high mechanical modulus 10.4 GPa, which homogenize stress distribution during plating process for effective suppression. Consequently, SP‐assisted asymmetric cell achieves nearly 99.94% Coulombic efficiency over 9000 cycles, enabling Zn/Zn cycle 540 h under ultrahigh 92% utilization. Outstanding cycling stability also successfully demonstrated high mass‐loading (≈12.8 mg cm −2 ) pouch cells, further demonstrating its prospects applications.
Язык: Английский
Процитировано
0
International Journal of Hydrogen Energy, Год журнала: 2024, Номер 71, С. 1351 - 1362
Опубликована: Май 26, 2024
Язык: Английский
Процитировано
3
Advanced Materials, Год журнала: 2024, Номер unknown
Опубликована: Авг. 27, 2024
Abstract The challenge of inadequate mechano‐electrochemical stability in rechargeable fibrous Zn‐ion batteries (FZIBs) has emerged as a critical for their broad applications. Traditional rigid Zn wires struggle to maintain stable electrochemical interface when subjected external mechanical stress. To address this issue, wet‐spinning technique been developed fabricate powder based anode, while carbon nanotubes (CNTs) introduced enhance the spinnability dispersion. followed annealing treatment conducted reengineer crystalline texture with CNTs assisted surface tension regulation redirect (002) crystallographic textural formation. thus‐derived annealed Zn@CNTs fiber demonstrates great after long‐term bending and process. fabricated FZIB remarkable durability, surpassing 800 h at 1 mA cm −2 mAh , marginal voltage hysteresis increase 21.7 mV even 100 twisting cycles under 180 degree angle. assembled full cell displays an 88.6% capacity retention long cycle series bending, knotting, straightening deformation. It also woven into 200 2 size textile demonstrate its capability integrate smart textiles.
Язык: Английский
Процитировано
3