ABSTRACT
Electrochemical
CO
2
reduction
reaction
(CO
RR)
has
received
great
attention
to
solve
‐
induced
global
warming
and
carbon
neutrality.
It
is
essential
enhance
the
electrochemical
RR
selectivity,
activity,
long‐term
stability
for
sustainable
manufacturing
of
specific
chemicals
via
RR.
To
produce
multi‐carbon
(C
2+
)
chemicals,
Cu‐based
heterogeneous
catalysts
have
been
developed
in
terms
defect
engineering,
morphological
design,
facet
control.
Despite
substantial
efforts
design
efficient
catalysts,
there
exist
inevitable
structural
changes
with
continuous
dissolution
redeposition
during
This
reconstruction
modifies
as‐synthesized
into
an
unpredictable
structure
leads
active
site.
Here,
we
review
RR,
which
occurs
process.
includes
fundamental
principles
effect
microenvironment
on
We
offer
research
progress
about
electrocatalysts,
analysis
methodologies
track
reconstruction,
insight
improve
provide
perspective
understand
harness
development
catalysts.
Advanced Energy Materials,
Год журнала:
2025,
Номер
unknown
Опубликована: Май 15, 2025
Abstract
Alkaline
water
electrolyzer
(AWE)
is
widely
considered
as
an
environmentally‐friendly
technique
for
green
H
2
production.
However,
it
still
a
great
bottleneck
that
the
AWE
technology
cannot
meet
fluctuating
renewable
energies,
due
to
instability
and
poor
resistant
counter‐current
property
of
electrocatalysts
in
AWE.
Herein,
high‐stable
robust
WMo‐CoP@NM
electrocatalyst
constructed
by
modulating
electronic
structure
CoP
catalysts.
The
catalyst
not
only
exhibits
excellent
hydrogen
evolution
reaction
(HER)
performance
at
ampere‐level
current
densities,
but
also
presents
outstanding
adaptability
multi‐cycle
start‐stop
tests
AWE,
which
offers
opportunity
use
energies
produce
.
Importantly,
(cathode)||NM
(anode)
holds
ultra‐long
stability
over
1500
h
30
wt.%
KOH
65
°C,
confirms
their
potential
practical
applications.
DFT
calculation
shows
synergistic
effect
Mo
W
doping
can
increase
adsorption
capability
optimize
species,
therefore
efficiently
promote
HER
performance.
In
short,
this
work
provides
first
example
via
designing
catalysts
realize
will
accelerate
coupling
with
Inorganic Chemistry Frontiers,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 1, 2025
This
review
summarizes
the
synthesis,
modification,
and
characterization
of
nonmetal-doped
HER
electrocatalysts.
Reported
catalysts
are
categorized
by
dopant
type,
future
prospects
for
non-metal
doping
strategies
discussed.
