Enhanced Electrochemical Nitrate Reduction to Ammonia with Nanostructured Mo2C on Carbon Nanotube-Reduced Graphene Oxide Hybrid Support DOI
So Eun Jang, Jae Young Kim, Duck Hyun Youn

и другие.

Dalton Transactions, Год журнала: 2024, Номер unknown

Опубликована: Янв. 1, 2024

Mo 2 C nanoparticles dispersed on CNT-RGO hybrid support (Mo C/CNT-RGO) serve as an effective electrocatalyst for NO 3 − RR, showing high performance due to the synergistic interaction between active sites and support.

Язык: Английский

Interface Engineering on Heterostructural Nanosheets for Efficient Electrocatalytic-Paired Upcycling of Waste Plastics and Nitrate DOI
Junhua Wu,

Xiaoxiao Cheng,

Yun Tong

и другие.

ACS Catalysis, Год журнала: 2024, Номер unknown, С. 18095 - 18106

Опубликована: Ноя. 22, 2024

Язык: Английский

Процитировано

18

Boosting Synergistic Catalysis C–N Coupling via Stabilizing Close Zn/Ti Bimetallic Sites for Electrocatalytic Urea Synthesis from CO2 and Nitrite DOI
Ruifeng Wang, Yuchang Liu,

Yafen Kong

и другие.

ACS Catalysis, Год журнала: 2025, Номер unknown, С. 2703 - 2714

Опубликована: Янв. 30, 2025

Electrocatalytic urea synthesis is significantly limited by the low efficiency of C–N bond coupling between CO2 and nitrite. Here, we designed a Zn Ti bimetallic active site catalyst anchoring TiO2 on surface ZnO developed new NF@CoMn2O4@ZnO-TiO2 electrocatalyst with high resistance to deactivation. The Co3+/Mn3+-Mn4+ solid oxide pairs in maintain their stability extracting accumulated electrons around Zn2+ Ti4+ through strong electronic interactions. sites can efficiently catalyze reduction *CO, while NO2– *NH2 intermediate product. proximity shortens distance *CO intermediates, facilitating efficient electrocatalytic urea. DFT calculations indicate that ΔG required for adsorbed short-range CoMn2O4@ZnO-TiO2 lower compared CoMn2O4@ZnO ZnO. This results remarkably Faradaic 61.18% at −0.6 V vs RHE NF@CoMn2O4@ZnO-TiO2. work provides pathway achieving synergistic catalysis reactions different metal catalytic sites.

Язык: Английский

Процитировано

1

Electroreduction of nitrate into ammonia on Co3O4: Mechanistic insights into Co2+-promoted NO3RR performance DOI
Yu Sun,

Yaxin Shi,

Yuhang Gao

и другие.

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 162506 - 162506

Опубликована: Апрель 1, 2025

Язык: Английский

Процитировано

1

Boosting Electroreduction of Nitrate and CO2 to Urea on a Tandem Fe1/MoS2 Catalyst DOI

Wenyu Du,

Zeyi Sun,

Shiyao Shang

и другие.

ACS Nano, Год журнала: 2024, Номер unknown

Опубликована: Сен. 23, 2024

Urea electrosynthesis by coelectrolysis of NO

Язык: Английский

Процитировано

6

Relay Catalysis of Isolated Rhodium-Alloyed Copper Boosts Urea Electrosynthesis from Nitrate and CO2 DOI

Jiaqi Xiang,

Chaofan Qiang,

Shiyao Shang

и другие.

ACS Nano, Год журнала: 2024, Номер 18(43), С. 29856 - 29863

Опубликована: Окт. 16, 2024

Urea electrosynthesis from the coelectrolysis of NO3– and CO2 (UENC) presents a fascinating approach for simultaneously migrating pollutants producing valuable urea. In this study, isolated Rh-alloyed copper (Rh1Cu) is explored as highly active selective catalyst toward UENC. Combined in situ spectroscopic analysis theoretical calculations reveal relay catalysis Rh1 site Cu to promote UENC energetics, which activates form *NH2 while *CO. The formed *CO then migrated substrate nearby site, promotes C–N coupling urea formation. Prominently, Rh1Cu achieves an exceptional performance flow cell, exhibiting highest urea-Faradaic efficiency 67.10% yield rate 50.36 mmol h–1 g–1 at −0.6 V versus RHE.

Язык: Английский

Процитировано

5

Nanoconfinement and tandem catalysis over yolk-shell catalysts towards electrochemical reduction of CO2 to multi-carbon products DOI
Lidan Sun, Xiaolin Zheng,

Yuanrui Li

и другие.

Journal of Colloid and Interface Science, Год журнала: 2025, Номер 687, С. 733 - 741

Опубликована: Фев. 15, 2025

Язык: Английский

Процитировано

0

Selective coreduction of CO2 and NO3− for urea synthesis via electrochemical pathway modulated by p-block metal-doped copper oxides DOI
Kailun Yu, Hui Wang, Wenchao Yu

и другие.

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 163048 - 163048

Опубликована: Апрель 1, 2025

Язык: Английский

Процитировано

0

Modeling of three-dimensional flow cell reactor with serpentine channel for nitrate electroreduction to ammonia DOI
Jianpeng Sun, Yang Lv,

He Chang

и другие.

Chemical Engineering Science, Год журнала: 2025, Номер unknown, С. 121845 - 121845

Опубликована: Май 1, 2025

Язык: Английский

Процитировано

0

Surface reconstruction induced Cu2O/FeO heterojunction towards efficient nitrate-containing wastewater remediation DOI

Le Ding,

Haosheng Lan,

Xin Li

и другие.

Journal of Colloid and Interface Science, Год журнала: 2025, Номер unknown, С. 137318 - 137318

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

0

Catalyst and gas diffusion electrode design toward C–N coupling for urea electrosynthesis DOI Creative Commons
Jiping Sun, Bichao Wu, Guangchao Li

и другие.

eScience, Год журнала: 2025, Номер unknown, С. 100425 - 100425

Опубликована: Апрель 1, 2025

Язык: Английский

Процитировано

0