Industrial‐Level Modulation of Catalyst‐Electrolyte Microenvironment for Electrocatalytic CO2 Reduction: Challenges and Advancements DOI
Weiyi Liu,

Zunhang Lv,

Changli Wang

и другие.

Advanced Energy Materials, Год журнала: 2024, Номер unknown

Опубликована: Сен. 9, 2024

Abstract CO 2 reduction reaction (CO RR), as a promising strategy for storing renewable energy and promoting carbon resource recycling, is critical industrial development. Previous reports have extensively explored catalyst‐electrolyte microenvironmental modulation to elucidate coupling mechanisms enhance catalytic conversion multicarbon products. Currently, most reviews mainly focus on the impact of microenvironment in low‐current systems mechanism exploration performance optimization, yet few them can integrate macroscopic applications with microscopic investigations explore relevance between development optimization. To address gap, this review focuses summarizing challenges advancements high‐current devices. By introducing models different scales sequentially, connection device clarified. Then, various invalidation effective solutions are summarized intuitively expound stability. Meanwhile, an intuitive measure rationality modulation, evaluation methods should be refined, which also covered further detail below. Finally, more valuable challenging prospects discussed guiding transformation RR.

Язык: Английский

In-situ characterization technologies and theoretical calculations in carbon dioxide reduction: In-depth understanding of reaction mechanisms and rational design of electrocatalysts DOI
Rutao Wang, Xiaokun Yang, Jianpeng Zhang

и другие.

Coordination Chemistry Reviews, Год журнала: 2025, Номер 533, С. 216541 - 216541

Опубликована: Фев. 28, 2025

Язык: Английский

Процитировано

1
2024, A Landmark Year for Climate Change and Global Carbon Capture, Utilization, and Storage: Annual Progress Review DOI Creative Commons
Shangli Shi, Yun Hang Hu

Energy Science & Engineering, Год журнала: 2025, Номер unknown

Опубликована: Апрель 4, 2025

ABSTRACT This annual review outlines the progress of carbon capture, utilization, and storage (CCUS) technologies in 2024. As human‐induced CO 2 emissions continued to rise, year presented critical challenges. Notably, 2024 was hottest on record first which global temperatures exceeded preindustrial levels by more than 1.5°C, driving intensified efforts advance CCUS. Scientific interest CCUS grew significantly, with number related publications increasing 11.4% compared 2023, reaching 53,970. The total operational commercial facilities also expanded, rising 16.3% a 50. In political area, governments introduced targeted policies accelerate adoption, focusing economic investment specific implementation requirements.

Язык: Английский

Процитировано

0
Heterogeneous Electrocatalytic CO2 Reduction by Supported Molecular Catalysts Well Dispersed on Electrode Surface DOI Creative Commons
Ke Ma, Shiyu Zhang, Weixuan Nie

и другие.

ChemElectroChem, Год журнала: 2025, Номер unknown

Опубликована: Апрель 22, 2025

Electrochemical CO 2 reduction (CO R) to value‐added products using renewable electricity offers a promising approach toward achieving carbon neutrality. Among various electrocatalysts, molecular catalysts, particularly transition metal complexes, stand out due the high selectivity for single specific and desirable tunability, enabling rational optimization of catalytic performance. However, their practical application is hindered by low operating current densities challenges in catalyst recycling. To address these limitations, immobilizing catalysts on electrode surfaces has emerged as an effective strategy integrating selective into heterogeneous catalysis. This mini review focuses distinct category heterogenized catalysts—those molecularly dispersed supported substrates or surfaces‐which exhibit remarkable activity at single‐molecule level ability drive deep (beyond two electrons) under certain conditions. Recent progress this field comprehensively discussed, emphasizing critical impacts molecule‐level dispersion catalyst‐support interactions electronic properties, multi‐electron transfer kinetics, overall Moreover, overview potential applications beyond electrochemical R provided end. aims offer valuable insights future design efficient scalable electrocatalysts sustainable conversion.

Язык: Английский

Процитировано

0
Industrial‐Level Modulation of Catalyst‐Electrolyte Microenvironment for Electrocatalytic CO2 Reduction: Challenges and Advancements DOI
Weiyi Liu,

Zunhang Lv,

Changli Wang

и другие.

Advanced Energy Materials, Год журнала: 2024, Номер unknown

Опубликована: Сен. 9, 2024

Abstract CO 2 reduction reaction (CO RR), as a promising strategy for storing renewable energy and promoting carbon resource recycling, is critical industrial development. Previous reports have extensively explored catalyst‐electrolyte microenvironmental modulation to elucidate coupling mechanisms enhance catalytic conversion multicarbon products. Currently, most reviews mainly focus on the impact of microenvironment in low‐current systems mechanism exploration performance optimization, yet few them can integrate macroscopic applications with microscopic investigations explore relevance between development optimization. To address gap, this review focuses summarizing challenges advancements high‐current devices. By introducing models different scales sequentially, connection device clarified. Then, various invalidation effective solutions are summarized intuitively expound stability. Meanwhile, an intuitive measure rationality modulation, evaluation methods should be refined, which also covered further detail below. Finally, more valuable challenging prospects discussed guiding transformation RR.

Язык: Английский

Процитировано

3