Journal of Alloys and Compounds, Год журнала: 2024, Номер unknown, С. 178269 - 178269
Опубликована: Дек. 1, 2024
Small, Год журнала: 2025, Номер unknown
Опубликована: Март 4, 2025
Abstract In the past few years, aqueous zinc‐metal batteries (ZMBs) have gained much attention and can be regarded as a potential alternative to lithium‐metal owing their high safety, nature of abundance, environmental sustainability. However, several challenges persist, including dendrite formation, corrosion, unwanted side reactions, before ZMBs fully utilized in practical applications. To circumvent these issues, anode free (AFZMBs) emerged next‐generation energy storage system. This review provides comprehensive analysis recent developments AFZMBs, working mechanisms, advantages over conventional ZMBs, for implementation. It also highlights key strategies, current collector modification, electrolyte engineering, 3D printing techniques enhance zinc deposition uniformity cycling stability. The explores how technology revolutionize design advanced collectors zinc‐rich cathodes, optimizing material utilization enhancing battery performance. Finally, with future perspective AFZMBs is concluded, highlighting need further research address existing bottlenecks unlock storage.
Язык: Английский
Процитировано
1
Advanced Functional Materials, Год журнала: 2025, Номер unknown
Опубликована: Март 26, 2025
Abstract Zwitterionic hydrogels have attracted intensive attentions for their exceptional hydration and anti‐fouling properties, while the exploration rational structural designs to achieve multi‐function superior anti‐freezing capability remains an ongoing mission. Herein, a new multi‐functional zwitterionic monomer (ACHPES) is designed developed from which novel are fabricated. The pyridinium‐sulfonate motif endows hydrogel with discoloration in both visible light fluorescence response pH stimulus, enabling unique multi‐channel information encryption highly sensitive Cu 2+ detection threshold of 0.64 ppm. design carbamate group fulfils high bonding capacity water, leading capability. As such, exhibit extremely low water freezing point −47.3 °C breaking elongation ≈500% at −20 °C. outstanding enables sensors electrolytes excellent operational performance temperatures. This innovative strategy offers avenue functionalization application icy temperature.
Язык: Английский
Процитировано
1
ACS Nano, Год журнала: 2025, Номер unknown
Опубликована: Апрель 1, 2025
Aqueous batteries, renowned for their high capacity, safety, and low cost, have emerged as promising candidates next-generation, sustainable energy storage. However, large-scale application is hindered by challenges, such dendrite formation side reactions at the anode. Hydrogel electrolytes, which integrate advantages of liquid solid phases, exhibit superior ionic conductivity interfacial compatibility, giving them potential to suppress evolution. This Perspective first briefly introduces fundamentals underlying unique features hydrogels. It then identifies key role water polymer networks in inhibiting formation, highlighting regulation activity, ion transport, electrode kinetics. By elucidating principles hydrogels suppression, this work aims provide valuable insights advance implementation aqueous batteries incorporating
Язык: Английский
Процитировано
1
Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 162523 - 162523
Опубликована: Апрель 1, 2025
Язык: Английский
Процитировано
0
Small, Год журнала: 2025, Номер unknown
Опубликована: Апрель 28, 2025
Abstract Considering the merits and shortcomings of conventional hydrogels in terms low‐temperature adaptability, a new type hydrogel electrolyte, reinforced by hydrogen bonding containing just 6.8% water, is fabricated. This film exhibits high ionic conductivity 3.9 mS cm −1 at room temperature maintains its flexibility even −40 °C. The hydrogel‐based quasi‐solid‐state cell shows good cyclic stability performance, retaining 80.3% initial capacity after 800 cycles. Furthermore, it performs well sub‐zero conditions, 89.6% −30 °C (0.5C) releasing 56.4 mAh g (0.1C). Notably, LTE‐based flexible full under 180° bending 15% stretching. can be attributed to polymer network with hydrophilic groups, which disrupts hydrogen‐bond networks original water molecules forms abundant interactions between chains molecules. These are crucial for improving adaptability. Overall, this work offers promising approach creating adaptable that used develop wearable energy‐storage devices.
Язык: Английский
Процитировано
0
Energy storage materials, Год журнала: 2025, Номер unknown, С. 104373 - 104373
Опубликована: Июнь 1, 2025
Язык: Английский
Процитировано
0
Journal of Alloys and Compounds, Год журнала: 2024, Номер unknown, С. 178269 - 178269
Опубликована: Дек. 1, 2024
Процитировано
0