Conjugated Cobalt Porphyrin Polymer for Highly Active and Selective Electrocatalytic Nitrite Reduction to Ammonia DOI
Lisi Xie,

Benxing Mei,

Yabo Wang

и другие.

Advanced Functional Materials, Год журнала: 2025, Номер unknown

Опубликована: Апрель 15, 2025

Abstract Electrocatalytic nitrite (NO 2 − ) reduction RR) to ammonia (NH 3 is a promising green technology for producing NH with high efficiency. Cobalt macrocyclic complexes have attracted great interest because of their ability selectively convert NO , but suffer from low yields. Herein, cobalt porphyrin conjugated polymer on carbon nanotubes (CoPCOP@CNT) reported display exceptional RR performance large yield 133.39 mg h −1 CoP at −1.0 V and Faradaic efficiency (FE) 98.0% −0.8 V. Utilizing CoPCOP@CNT as the catalyst cathode, Zn‐NO battery exhibits remarkable power density (5.34 mW cm −2 ), open‐circuit voltage (≈1.45 V), FE (94.6%), (29.15 ). The active intermediates reaction pathways CoPCOP in process are revealed by differential electrochemical mass spectroscopy theory calculations. This work highlights potential electrocatalysts based metal porphyrins conversion nitrogenous pollutant into .

Язык: Английский

Electron Traction Effect of CuPt-Sensitized Photocathode for Enhanced Ammonia Synthesis and Efficient Zn-Nitrate Battery DOI
Jiaxin Tong, Haiyan Wu, Pengfei Tan

и другие.

Nano Energy, Год журнала: 2025, Номер unknown, С. 111133 - 111133

Опубликована: Май 1, 2025

Язык: Английский

Процитировано

0
Conjugated Cobalt Porphyrin Polymer for Highly Active and Selective Electrocatalytic Nitrite Reduction to Ammonia DOI
Lisi Xie,

Benxing Mei,

Yabo Wang

и другие.

Advanced Functional Materials, Год журнала: 2025, Номер unknown

Опубликована: Апрель 15, 2025

Abstract Electrocatalytic nitrite (NO 2 − ) reduction RR) to ammonia (NH 3 is a promising green technology for producing NH with high efficiency. Cobalt macrocyclic complexes have attracted great interest because of their ability selectively convert NO , but suffer from low yields. Herein, cobalt porphyrin conjugated polymer on carbon nanotubes (CoPCOP@CNT) reported display exceptional RR performance large yield 133.39 mg h −1 CoP at −1.0 V and Faradaic efficiency (FE) 98.0% −0.8 V. Utilizing CoPCOP@CNT as the catalyst cathode, Zn‐NO battery exhibits remarkable power density (5.34 mW cm −2 ), open‐circuit voltage (≈1.45 V), FE (94.6%), (29.15 ). The active intermediates reaction pathways CoPCOP in process are revealed by differential electrochemical mass spectroscopy theory calculations. This work highlights potential electrocatalysts based metal porphyrins conversion nitrogenous pollutant into .

Язык: Английский

Процитировано

0