
npj Computational Materials, Год журнала: 2025, Номер 11(1)
Опубликована: Май 17, 2025
Язык: Английский
npj Computational Materials, Год журнала: 2025, Номер 11(1)
Опубликована: Май 17, 2025
Язык: Английский
Chemical Society Reviews, Год журнала: 2025, Номер unknown
Опубликована: Янв. 1, 2025
This review systematically discusses water-related and proton-assisted equilibria reactions in zinc-ion batteries. Water-related dissolution, deposition, amorphization phenomena are covered.
Язык: Английский
Процитировано
1Energy storage materials, Год журнала: 2025, Номер unknown, С. 104204 - 104204
Опубликована: Март 1, 2025
Язык: Английский
Процитировано
1ACS Nano, Год журнала: 2025, Номер unknown
Опубликована: Апрель 15, 2025
Sodium metal, regarded as an ideal anode material for high-energy-density rechargeable sodium metal batteries (SMBs), faces critical challenges, such sluggish Na+ transport kinetics and uncontrolled dendritic growth, which severely hinder its cycling stability practical applications. Herein, the well-designed, multifunctional separator, UFS2@GF, constructed using metal-organic frameworks functionalized with fluorinated (-F) sulfonic acid (-SO3H) groups, synergistically provides more nucleation sites deposition, thereby reducing overpotential achieving uniform deposition. The inorganic-rich solid electrolyte interphase induced by UFS2 facilitates a flux enhances charge transfer efficiency. Structural characterization density functional theory calculations further demonstrate that introduction of abundant sodiophilic provided -F -SO3H significantly energy barriers migration within framework, leading to higher transference number, superior ionic conductivity, accelerated ion transport. Because these synergistic effects, symmetric cell UFS2@GF achieves stable performance, enabling over 2500 h at 0.25 mA cm-2 while delivering excellent specific capacity 87.3 g-1 10C in Na∥Na3V2(PO4)3 cells. These results highlight role group strategies addressing limitations SMBs.
Язык: Английский
Процитировано
1Applied Surface Science, Год журнала: 2025, Номер 694, С. 162859 - 162859
Опубликована: Март 2, 2025
Язык: Английский
Процитировано
0Advanced Energy Materials, Год журнала: 2025, Номер unknown
Опубликована: Апрель 22, 2025
Abstract Aqueous zinc‐ion batteries (AZIBs) have become critical in driving the advancement of large‐scale energy storage systems due to their high specific capacity, safety, environmental friendliness, and low cost. However, fundamental challenges associated with Zn anodes, including dendrite growth, hydrogen evolution reaction, corrosion, zinc utilization, significantly hinder improvement cyclic stability density AZIBs. In light these challenges, considerable efforts been devoted exploring stable while a significant gap persists between current research advancements practical working conditions. Therefore, this review first reveals detailed mechanisms formation, as well influence utilization on AZIB systems. addition, recent various modification strategies for improving anodes are summarized, corresponding investigated. Finally, key factors advancing development application AZIBs clarified, goal bridging status future demands.
Язык: Английский
Процитировано
0Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 163617 - 163617
Опубликована: Май 1, 2025
Язык: Английский
Процитировано
0npj Computational Materials, Год журнала: 2025, Номер 11(1)
Опубликована: Май 17, 2025
Язык: Английский
Процитировано
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