Journal of Power Sources, Год журнала: 2025, Номер 647, С. 237355 - 237355
Опубликована: Май 17, 2025
Язык: Английский
Journal of Power Sources, Год журнала: 2025, Номер 647, С. 237355 - 237355
Опубликована: Май 17, 2025
Язык: Английский
Advanced Functional Materials, Год журнала: 2025, Номер unknown
Опубликована: Фев. 5, 2025
Abstract The side reactions and dendritic growth largely impede the utilization of Zn anode in aqueous zinc ion batteries (AZIBs). Herein, a novel strong acidic electrolyte additive itaconic acid (IA) is introduced to achieve highly stable via dual functions. First, use trace amounts IA can provide steady low pH environment for electrolyte, which beneficial eliminate alkaline by‐products by neutralizing OH − that accumulated near anode. Second, an interfacial protective layer be situ formed cross‐linking reduction reaction between anode, helping inhibit continuous corrosion on promote formation uniform deposition. Consequently, achieves ultra‐long cycle‐life (5390 h at 1 mA cm −2 , mAh ) enhanced coulombic efficiency (99.86% upon 2100 cycles 5 −1 ). Besides, full cell assembled with sodium vanadate delivers high reversible capacity 179.6 g over 2000 2 A . This work offers new solution related insights design electrolytes additives toward AZIBs.
Язык: Английский
Процитировано
1Advanced Sustainable Systems, Год журнала: 2025, Номер unknown
Опубликована: Апрель 27, 2025
Abstract Aqueous zinc‐ion batteries (AZIBs) with inherent safety, cost‐effectiveness and environmental compatibility have garnered significant attention for large‐scale energy storage. However, AZIBs still suffer from the hydrogen evolution reaction, Zn dendrite corrosion, which are closely correlated 2+ solvation structure. Therefore, designing an optimized structure reduced water molecules in shell is expected to achieve stable reversible plating/stripping. In this study, water‐soluble Tartaric Acid containing abundant ─COOH groups as electrolyte additive employed. The dissociated can replace around 2 ⁺, leading a restructured shell, not only inhibits side reactions, but also enhances kinetics of de‐solvation process, promoting formation flat dense zinc deposition layer. as‐prepared electrode exhibits impressive areal capacity 28.21 mAh cm −2 after resting 6 h excellent long‐term stability (800 cycles retention 81.76%). addition, situ microscope electrochemical impedance spectroscopy (EIS) synergistically identify outstanding structural enhanced kinetics, respectively. This work sheds light on constructing highly anode seawater‐based AZIBs.
Язык: Английский
Процитировано
0Energy storage materials, Год журнала: 2025, Номер unknown, С. 104299 - 104299
Опубликована: Май 1, 2025
Язык: Английский
Процитировано
0Electrochimica Acta, Год журнала: 2025, Номер 530, С. 146409 - 146409
Опубликована: Май 6, 2025
Язык: Английский
Процитировано
0Advanced Energy Materials, Год журнала: 2025, Номер unknown
Опубликована: Май 13, 2025
Abstract Aqueous zinc‐ion hybrid capacitors (ZIHCs) have emerged as a sustainable energy storage technology. However, the slow diffusion of large solvated Zn 2+ within nanopores and restriction on electric double layer (EDL) thickness limit spatial charge density in carbon electrodes. Herein, multi‐channel porous nanofibers (MC‐PCNFs) are designed with customized porosity high‐charge‐density interfaces to facilitate rapid [Zn(H 2 O) 6 ] desolvation compact EDL formation. The hierarchical hollow structure maximizes ion accessibility, while precisely tuned 1.07 nm pores enable direct adsorption onto catalytic sites, significantly reducing barrier. resulting ZIHCs achieve high reversible capacity 221 mAh g −1 , battery‐level 170.2 Wh kg (based cathode materials), outstanding long‐term cycling stability (>90,000 cycles, 98.7% retention), practically areal capacities. Through in/ex situ spectroscopy, theoretical calculations, kinetic analysis, electrochemical quartz crystal microbalance (EQCM) interfacial mechanisms comprehensively elucidated. This study provides scalable effective strategy for engineering, paving way next‐generation high‐energy, long‐cycle‐life ZIHCs.
Язык: Английский
Процитировано
0Journal of Power Sources, Год журнала: 2025, Номер 647, С. 237355 - 237355
Опубликована: Май 17, 2025
Язык: Английский
Процитировано
0