The chemistry of heterocycles in the 21st century

Russian Chemical Reviews, Год журнала: 2024, Номер 93(7), С. RCR5125 - RCR5125

Опубликована: Июль 1, 2024

The chemistry of heterocyclic compounds has traditionally been and remains a bright area chemical science in Russia. This is due to the fact that many heterocycles find widest application. These are key structural fragments most drugs, plant protection agents. Many natural also derivatives heterocycles. At present, more than half hundreds millions known collective review devoted achievements Russian chemists this field over last 15–20 years. presents leading heterocyclists representing both RAS institutes university science. It worth noting wide scope review, terms geography author teams, covering whole our large country, diversity research areas. Practically all major types represented review. special attention focused on practical applications design new drugs biologically active compounds, high-energy molecules, materials for organic electronics photovoltaics, ligands coordination chemistry, other rapidly developing advances would not be possible without development fundamental transformations chemistry.<br> Bibliography — 2237 references.

Язык: Английский

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Base/DMSO‐Promoted Synthesis of Benzo[4,5]imidazo[2,1‐a]isoquinolines via C−C Bond Formation

Advanced Synthesis & Catalysis, Год журнала: 2024, Номер 366(5), С. 1182 - 1188

Опубликована: Янв. 13, 2024

Abstract In this study, a synthetic method to access benzo[4,5]imidazo[2,1‐ ]isoquinolines is developed by the reaction of 2‐(2‐bromoaryl)benzimidazoles with 1,3‐diketones under basic conditions. A pathway involving initial formation C−C coupled intermediate nucleophilic aromatic substitution and subsequent deacylative cyclocondensation proposed for process.

Язык: Английский

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Quantum Chemical Investigations of the Mechanisms of Carbo- and Heterocycles Assemblies Based on Acetylenes Reactions in Superbasic Media

Russian Journal of Organic Chemistry, Год журнала: 2023, Номер 59(10), С. 1660 - 1675

Опубликована: Окт. 1, 2023

Abstract The chemistry of acetylenes has gained significant development in the context using superbasic media organic synthesis. Studies reaction mechanisms require a combination chemical, physicochemical, and theoretical methods to be applied. review discusses results recent quantum chemical studies on assemblies complex highly functionalized molecular structures based reactions acetylene its derivatives performed at Favorsky Irkutsk Institute Chemistry (Siberian Branch, Russian Academy Sciences).

Язык: Английский

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Quantum chemical investigations of the mechanisms of carboand heterocycles assemblies based on acetylenes reactions in superbasic media

Журнал органической химии, Год журнала: 2023, Номер 59(10), С. 1301 - 1318

Опубликована: Дек. 15, 2023

Язык: Английский

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