Modulating the Aggregation States of a Pd6L4 Cage for Selectivity Flipping during the Stereo‐Divergent Semi‐Hydrogenation of Alkynes DOI Open Access
Wei Zhong, Jing Xu, Song Zhao

и другие.

Angewandte Chemie, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 6, 2024

Abstract An enzyme‐mimicking catalytic system has been established using a singular palladium‐based octahedral cage as the supramolecular reactor, deftly unlocking off‐on‐off selectivity in semi‐hydrogenation of alkynes. Water serves critical regulator, modulating catalyst states, reaction rates, and endpoints. The choice solvent influences activity host–guest binding types homogeneous heterogeneous catalysis, effectively modifying steps involved Z → E isomerization during Kinetic inhibition experiments indicate that mimics activation characteristics enzymes towards substrates, enabling selective transformations within confined environment. utility this switchable cage‐confined catalysis demonstrated synthesis modification complex biologically active molecules with controllable / selectivity. This work sheds light on design control artificial counterparts enzymes, offering fundamental insights into factors influencing biological macromolecules.

Язык: Английский

A novel Nitrogen-Doped Water-Soluble carbon dot for highly selective Recognition of Mg2+ by chelation conjugation enhancement effect (CCE) and its application in Synergistically enhanced photodynamic antibacterial DOI
Kezhen Zhang,

Xiaoyong Tian,

Peipei Xu

и другие.

Microchemical Journal, Год журнала: 2025, Номер unknown, С. 112842 - 112842

Опубликована: Янв. 1, 2025

Язык: Английский

Процитировано

0

Metallacycle-Cored Luminescent Ionic Liquid Crystals with Trigonal Symmetry DOI Creative Commons
Long Chen, Yu Cao,

Haohui Huo

и другие.

Chemical Science, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

The phase separation between blue tri(ethyl glycol) units and red alkyl chains regulated the metallacycle packing into p 3 m 1 hexagonal phase, generating first macrocycle-based liquid crystal with high luminescence good ionic conductivity.

Язык: Английский

Процитировано

0

Boron dipyrromethene fungicide for anti-microbial photodynamic therapeutics DOI
A Jia, Min Zheng, Zhigang Xie

и другие.

Journal of Photochemistry and Photobiology B Biology, Год журнала: 2025, Номер 265, С. 113137 - 113137

Опубликована: Фев. 28, 2025

Язык: Английский

Процитировано

0

Metallacage-crosslinked free-standing supramolecular networks via photo-induced copolymerization for photocatalytic water decontamination DOI Creative Commons
Rongrong Li, Haixin Zhang,

Yali Hou

и другие.

Nature Communications, Год журнала: 2025, Номер 16(1)

Опубликована: Март 19, 2025

The development of polymer materials for water decontamination makes a significant contribution to environmental protection and public health. Herein, we report the preparation metallacage-crosslinked free-standing supramolecular networks by photo-induced copolymerization acrylate metallacages butyl methacrylate decontamination. integration into endows good capability generating singlet oxygen via photosensitization, making them serve as type that can effectively eliminate diverse organic pollutants bacterial contaminants. This study not only provides mild effective strategy metallacage-cored but also explores their applications photocatalytic dye degradation killing, which will promote future metallacage-based applications. is important authors

Язык: Английский

Процитировано

0

Ultrasound-switchable piezoelectric BiVO4/fullerene heterostructure for on-demand ROS modulation in MRSA-infected diabetic wound healing DOI

Zini Huang,

Yihan Ma,

Xinyi Yang

и другие.

Biomaterials Advances, Год журнала: 2025, Номер unknown, С. 214307 - 214307

Опубликована: Апрель 1, 2025

Язык: Английский

Процитировано

0

Modulating the Aggregation States of a Pd6L4 Cage for Selectivity Flipping during the Stereo‐Divergent Semi‐Hydrogenation of Alkynes DOI
Wei Zhong,

Xu Jing,

Zhao Song

и другие.

Angewandte Chemie International Edition, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 6, 2024

Abstract An enzyme‐mimicking catalytic system has been established using a singular palladium‐based octahedral cage as the supramolecular reactor, deftly unlocking off‐on‐off selectivity in semi‐hydrogenation of alkynes. Water serves critical regulator, modulating catalyst states, reaction rates, and endpoints. The choice solvent influences activity host–guest binding types homogeneous heterogeneous catalysis, effectively modifying steps involved Z → E isomerization during Kinetic inhibition experiments indicate that mimics activation characteristics enzymes towards substrates, enabling selective transformations within confined environment. utility this switchable cage‐confined catalysis demonstrated synthesis modification complex biologically active molecules with controllable / selectivity. This work sheds light on design control artificial counterparts enzymes, offering fundamental insights into factors influencing biological macromolecules.

Язык: Английский

Процитировано

1

Metallacage-Crosslinked Free-Standing Supramolecular Networks via Photo-induced Copolymerization for Photocatalytic Water Decontamination DOI Creative Commons
Mingming Zhang, Rongrong Li, Haixin Zhang

и другие.

Research Square (Research Square), Год журнала: 2024, Номер unknown

Опубликована: Авг. 21, 2024

Abstract The development of polymer materials for water decontamination makes a significant contribution to environmental protection and public health. Herein, we report the preparation metallacage-crosslinked free-standing supramolecular networks by photo-induced copolymerization acrylate metallacages butyl methacrylate decontamination. integration into endows good capability generating singlet oxygen via photosensitization, making them serve as type that can effectively eliminate diverse organic pollutants bacterial contaminants. This study not only provides mild effective strategy metallacage-cored but also explores their applications photocatalytic dye degradation killing, which will promote future metallacage-based applications.

Язык: Английский

Процитировано

0

Modulating the Aggregation States of a Pd6L4 Cage for Selectivity Flipping during the Stereo‐Divergent Semi‐Hydrogenation of Alkynes DOI Open Access
Wei Zhong, Jing Xu, Song Zhao

и другие.

Angewandte Chemie, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 6, 2024

Abstract An enzyme‐mimicking catalytic system has been established using a singular palladium‐based octahedral cage as the supramolecular reactor, deftly unlocking off‐on‐off selectivity in semi‐hydrogenation of alkynes. Water serves critical regulator, modulating catalyst states, reaction rates, and endpoints. The choice solvent influences activity host–guest binding types homogeneous heterogeneous catalysis, effectively modifying steps involved Z → E isomerization during Kinetic inhibition experiments indicate that mimics activation characteristics enzymes towards substrates, enabling selective transformations within confined environment. utility this switchable cage‐confined catalysis demonstrated synthesis modification complex biologically active molecules with controllable / selectivity. This work sheds light on design control artificial counterparts enzymes, offering fundamental insights into factors influencing biological macromolecules.

Язык: Английский

Процитировано

0