Bridge‐Oxygen Bond: An Active Group for Energy Electrocatalysis
Advanced Functional Materials,
Год журнала:
2025,
Номер
unknown
Опубликована: Март 20, 2025
Abstract
Energy
electrocatalytic
reactions
such
as
hydrogen
evolution
reaction,
oxygen
reduction
nitrogen
carbon
etc.,
are
important
to
solve
the
current
energy
shortage
and
increasing
environmental
problems.
Developing
novel
efficient
catalyts
for
these
has
become
an
essential
urgent
issue.
Catalysts
incorporating
bridge‐oxygen
bond
have
received
attention
due
their
superior
conductivity
stability,
which
favorable
optimizing
reaction
mechanism
improving
kinetics.
This
paper
provides
a
comprehensive
review
encompassing
concept
of
bond,
means
characterization,
activity
in
electrocatalysis
effect
on
catalytic
performance.
Through
this
review,
it
is
expected
furnish
valuable
reference
rational
design
catalysts
featuring
structure
across
diverse
reactions.
Язык: Английский
Controlled Synthesis of Copper Sulfide-associated Catalysts for Electrochemical Reduction of CO2 to Formic Acid and Beyond: A Review
Energy Advances,
Год журнала:
2024,
Номер
unknown
Опубликована: Янв. 1, 2024
This
review
provides
a
comprehensive
overview
of
various
advanced
engineering
strategies
and
controlled
synthesis
copper–sulfide
compounds
for
enhanced
electrochemical
CO
2
reduction
to
valuable
products.
Язык: Английский
Engineering interfacial molecular interactions on Ag Hollow fibre gas diffusion electrodes for high efficiency in CO2 conversion to CO
Chemistry - A European Journal,
Год журнала:
2024,
Номер
unknown
Опубликована: Окт. 9, 2024
The
electrochemical
CO
Язык: Английский
Microenvironment Regulation, Promoting CO2 Conversion to Mono- and Multicarbon Products over Cu-Based Catalysts
Industrial & Engineering Chemistry Research,
Год журнала:
2024,
Номер
unknown
Опубликована: Ноя. 16, 2024
This
Review
summarizes
recent
advancements
in
regulating
microenvironments
for
enhancing
CO2
conversion,
particularly
focusing
on
copper-based
catalysts,
which
are
crucial
transforming
to
valuable
chemicals
and
fuels.
We
discuss
strategies
microenvironment
regulation,
including
single-atom
catalyst
design,
particle
size/facets/morphology
control,
confinement
effects,
interfacial
engineering.
These
approaches
influence
the
efficiency
selectivity
of
conversion
by
optimizing
active
site
density,
controlling
reactant/intermediate
concentrations,
promoting
charge-transfer
processes.
highlight
importance
mass
transfer,
electrolyte
properties,
modifying
electrode
structures
improving
conversion.
Despite
significant
progress,
challenges
remain
electrocatalytically
achieving
high
current
densities
multicarbon
products,
developing
effective
quantify
contribution
catalytic
performance.
Future
research
will
focus
advanced
characterization
techniques,
exploring
novel
materials
synthesis
methods,
utilizing
machine
learning
theoretical
modeling
design
optimization.
Язык: Английский