Proceedings of the National Academy of Sciences, Год журнала: 2025, Номер 122(22)

Опубликована: Май 30, 2025

Tessellation, as an ancient and fascinating mathematical pursuit, has not only captivated mathematicians but also attracted chemists’ increasing attention at the molecular level in recent years. Exploring tessellation scale is pivotal for gaining profound insights into effects of on materials elucidating essential design principles supramolecular tessellation. In this study, we develop a dynamic fullerene host ( 1 ) with three consecutive heptagons, which promotes diverse via hierarchical assembly. solid state, molecule arranges itself layered square-shaped crystal superstructure. Interestingly, co-crystal structures C 60 70 exhibit highly ordered triangular rhombic patterns, respectively, due to adaptive regulation heptagons different curved guests, demonstrating first series tessellated framework chemistry. This work enriches development in-solution facilitates rational 2D

Язык: Английский