Chemical Engineering Journal, Год журнала: 2024, Номер 498, С. 155370 - 155370
Опубликована: Сен. 3, 2024
Язык: Английский
Chemical Engineering Journal, Год журнала: 2024, Номер 498, С. 155370 - 155370
Опубликована: Сен. 3, 2024
Язык: Английский
ACS Nano, Год журнала: 2024, Номер 18(33), С. 21804 - 21835
Опубликована: Авг. 8, 2024
Covalent organic frameworks (COFs) are crystalline networks with extended backbones cross-linked by covalent bonds. Due to the semiconductive properties and variable metal coordinating sites, along rapid development in linkage chemistry, utilization of COFs photocatalytic CO2RR has attracted many scientists' interests. In this Review, we summarize latest research progress on for CO2 reduction. first part, present COF linkages that have been used CO2RR, discuss four mechanisms including as intrinsic photocatalysts, photosensitive motifs metalated semiconductors heterojunction photocatalysts. Then, principles structural designs functional building units stacking mode exchange. Finally, outlook challenges provided. This Review is intended give some guidance design synthesis diverse different linkages, various structures, divergent modes efficient photoreduction CO2.
Язык: Английский
Процитировано
32ACS Nano, Год журнала: 2025, Номер unknown
Опубликована: Фев. 27, 2025
Although Li-metal batteries have been widely used as high-capacity batteries, they are highly susceptible to electrolytes that lead dendritic or dead Li growth, which significantly reduces the stability of electrodes. Herein, we report an anionic covalent organic framework (sulfonate COF: Bd-COF) a Li+-solvate dissociator strips solvent molecules from encapsulated Li+ stabilize The homogeneous and dense ionic COF separator was prepared using template-assisted interface in-suit polymerization engineering. Notably, well-developed groups within channels could counter-charge ligands Li+, adsorb Li+-solvates induce their partial desolvation. Meanwhile, ordered on surface pores provide continuous ion for migration, facilitating removal Li+-solvated species. Combined with nanoporous feature, membrane found be effective in suppressing Li-dendrites parasitic reactions. Bd-COF/Celgard realizes uniform deposition electrodes, exhibiting excellent cycling performance Li-symmetric high-voltage LiNi0.6Mn0.2Co0.2O2 cathodes, showcasing application prospects ion-conductive frameworks lithium battery separators.
Язык: Английский
Процитировано
1Nano Energy, Год журнала: 2024, Номер unknown, С. 110534 - 110534
Опубликована: Дек. 1, 2024
Язык: Английский
Процитировано
4Progress in Materials Science, Год журнала: 2025, Номер unknown, С. 101455 - 101455
Опубликована: Фев. 1, 2025
Язык: Английский
Процитировано
0Journal of Colloid and Interface Science, Год журнала: 2025, Номер unknown, С. 137327 - 137327
Опубликована: Март 1, 2025
Язык: Английский
Процитировано
0Coordination Chemistry Reviews, Год журнала: 2025, Номер 535, С. 216604 - 216604
Опубликована: Март 20, 2025
Язык: Английский
Процитировано
0Advances in Colloid and Interface Science, Год журнала: 2025, Номер unknown, С. 103507 - 103507
Опубликована: Апрель 1, 2025
Язык: Английский
Процитировано
0Applied Materials Today, Год журнала: 2025, Номер 44, С. 102694 - 102694
Опубликована: Апрель 12, 2025
Язык: Английский
Процитировано
0Energy storage materials, Год журнала: 2024, Номер 73, С. 103849 - 103849
Опубликована: Окт. 18, 2024
Язык: Английский
Процитировано
1Chemical Engineering Journal, Год журнала: 2024, Номер 498, С. 155370 - 155370
Опубликована: Сен. 3, 2024
Язык: Английский
Процитировано
0