Crystal Growth & Design,
Год журнала:
2024,
Номер
24(14), С. 6081 - 6094
Опубликована: Июль 1, 2024
Due
to
their
unique
structural
characteristics,
molecular
cages
have
become
pivotal
components
in
supramolecular
chemistry
and
materials
science.
These
possess
the
remarkable
ability
encapsulate
guest
molecules
metal
nanoparticles
within
cavities,
fostering
intriguing
host–guest
interactions
demonstrating
significant
potential
across
various
domains,
including
recognition,
drug
delivery,
catalysis,
material
synthesis.
Integrating
these
with
highly
porous
crystalline
covalent
organic
frameworks
(COFs)
constitutes
a
strategic
avenue
for
enhancing
both
porosity
functional
sites.
This
transition
from
COF
involves
precise
orchestration
of
individual
into
extended,
covalently
bonded
structures
well-defined
porosity.
unlocks
novel
pathways
design
applications,
significantly
enriching
landscape
review
comprehensively
summarizes
synthetic
strategies
employed
fabricating
cage-based
COFs,
explores
diverse
provides
insights
future
prospects
growth
this
rapidly
evolving
field.
Chemical Society Reviews,
Год журнала:
2023,
Номер
52(20), С. 6957 - 7035
Опубликована: Янв. 1, 2023
Reactive
oxygen,
nitrogen,
sulfur,
carbonyl,
chlorine,
bromine,
and
iodine
species
(RXS,
X
=
O,
N,
S,
C,
Cl,
Br,
I)
play
important
roles
in
normal
physiological
processes
through
governing
cell
signaling,
immune
balance,
tissue
homeostasis.
Chemical Science,
Год журнала:
2023,
Номер
14(34), С. 9086 - 9094
Опубликована: Янв. 1, 2023
A
comprehensive
study
of
the
photophysical
behaviors
and
CO
2
reduction
electrocatalytic
properties
a
series
cofacial
porphyrin
organic
cages
reveals
metals
regulate
excitation
electron
transfer
properties.
Crystal Growth & Design,
Год журнала:
2024,
Номер
24(14), С. 6081 - 6094
Опубликована: Июль 1, 2024
Due
to
their
unique
structural
characteristics,
molecular
cages
have
become
pivotal
components
in
supramolecular
chemistry
and
materials
science.
These
possess
the
remarkable
ability
encapsulate
guest
molecules
metal
nanoparticles
within
cavities,
fostering
intriguing
host–guest
interactions
demonstrating
significant
potential
across
various
domains,
including
recognition,
drug
delivery,
catalysis,
material
synthesis.
Integrating
these
with
highly
porous
crystalline
covalent
organic
frameworks
(COFs)
constitutes
a
strategic
avenue
for
enhancing
both
porosity
functional
sites.
This
transition
from
COF
involves
precise
orchestration
of
individual
into
extended,
covalently
bonded
structures
well-defined
porosity.
unlocks
novel
pathways
design
applications,
significantly
enriching
landscape
review
comprehensively
summarizes
synthetic
strategies
employed
fabricating
cage-based
COFs,
explores
diverse
provides
insights
future
prospects
growth
this
rapidly
evolving
field.
