High Interspace-Layer Manganese Selenide Nanorods as a High-Performance Cathode for Aqueous Zinc-Ion Batteries DOI
Ali Molaei Aghdam, Sajjad Habibzadeh, Mehran Javanbakht

и другие.

ACS Applied Energy Materials, Год журнала: 2023, Номер 6(6), С. 3225 - 3235

Опубликована: Март 8, 2023

This study presents a low-cost and straightforward α-MnSe-nanorod (NR) cathode active material (CAM) with superior function in rechargeable aqueous zinc-ion batteries (AZIBs). The facile two-dimensional Zn2+ transport channels, tunnel type, layered structure render such CAMs as the potential materials embedded AZIBs. However, their practical usage has been limited by either poor cycling stability or low capacity. We are first to develop an α-MnSe-NR synthesized hydrothermal method lengths up 100 nm diameters around 30 for ZIBs, featuring large diameter of 6.07 Å interlayer spacing 0.91 nm. During situ electrochemical activation process, is electrochemically oxidized MnSe (MnSe-EO). reflects higher storage capacity MnSe-EO cathodes. Besides, pseudocapacitive performance compared α-MnO2 gives rise much rate charge/discharge. developed high reversible (309 mA h g–1) durable cyclability 83.4% retention after 1000 cycles at 5 A g–1. In addition, detailed coinsertion process hydrated H+/Zn2+ was conducted, clarifying self-regulating mechanism electrolyte-involved production flake-like zinc hydrogen sulfate. preferential embedding adsorption energy ions were confirmed density functional theory analysis, which may further enhance migration abilities structure, primarily responsible corresponding performance. Electrochemical measurements favorable functions kinetics.

Язык: Английский

Proton‐Conductive Supramolecular Hydrogen‐Bonded Organic Superstructures for High‐Performance Zinc‐Organic Batteries DOI
Ziyang Song, Ling Miao, Laurent Ruhlmann

и другие.

Angewandte Chemie International Edition, Год журнала: 2023, Номер 62(13)

Опубликована: Янв. 25, 2023

Abstract With fast (de)coordination kinetics, the smallest and lightest proton stands out as most ideal charge carrier for aqueous Zn‐organic batteries (ZOBs). Hydrogen‐bonding networks with rapid Grotthuss conduction is particularly suitable organic cathodes, yet not reported. We report supramolecular self‐assembly of cyanuric acid 1,3,5‐triazine‐2,4,6‐triamine into superstructures through in‐plane H‐bonds out‐of‐plane π‐π interaction. The exhibit highly stable lock‐and‐key H‐bonding an ultralow activation energy protonation (0.09 eV vs. 0.25 zincification). Then, high‐kinetics H + coordination prior to Zn 2+ protophilic C=O sites via a two‐step nine‐electron reaction. assembled ZOBs show high‐rate capability (135 mAh g −1 at 150 A ), high density (267 Wh kg cathode ) ultra‐long life (50 000 cycles 10 becoming state‐of‐the‐art in comprehensive performances.

Язык: Английский

Процитировано

99
Metal-organic frameworks and beyond: The road toward zinc-based batteries DOI
Peng Zhi, Yuehua Li, Pengchao Ruan

и другие.

Coordination Chemistry Reviews, Год журнала: 2023, Номер 488, С. 215190 - 215190

Опубликована: Май 2, 2023

Язык: Английский

Процитировано

78
Advances in MOFs and their derivatives for non‑noble metal electrocatalysts in water splitting DOI

Guoliang Gao,

Xueli Chen, Lu Han

и другие.

Coordination Chemistry Reviews, Год журнала: 2024, Номер 503, С. 215639 - 215639

Опубликована: Янв. 8, 2024

Язык: Английский

Процитировано

77
All‐Round Ionic Liquids for Shuttle‐Free Zinc‐Iodine Battery DOI
Tao Xiao, Jin‐Lin Yang, Bao Zhang

и другие.

Angewandte Chemie International Edition, Год журнала: 2024, Номер 63(8)

Опубликована: Янв. 5, 2024

Abstract The practical implementation of aqueous zinc‐iodine batteries (ZIBs) is hindered by the rampant Zn dendrites growth, parasite corrosion, and polyiodide shuttling. In this work, ionic liquid EMIM[OAc] employed as an all‐round solution to mitigate challenges on both anode iodine cathode side. First, EMIM + embedded lean‐water inner Helmholtz plane (IHP) inert solvation sheath modulated OAc − effectively repels H 2 O molecules away from surface. preferential adsorption metal facilitates uniform nucleation via a steric hindrance effect. Second, can reduce shuttling hindering dissolution forming ‐I 3 dominated phase. These effects holistically enhance cycle life, which manifested || symmetric cells Zn‐I full cells. ZIBs with EAc deliver capacity decay rate merely 0.01 ‰ per after over 18,000 cycles at 4 A g −1 , lower self‐discharge better calendar life than without additive.

Язык: Английский

Процитировано

67
NH4+ Charge Carrier Coordinated H‐Bonded Organic Small Molecule for Fast and Superstable Rechargeable Zinc Batteries DOI
Ziyang Song, Ling Miao, Yaokang Lv

и другие.

Angewandte Chemie International Edition, Год журнала: 2023, Номер 62(38)

Опубликована: Июль 29, 2023

Organic small molecules as high-capacity cathodes for Zn-organic batteries have inspired numerous interests, but are trapped by their easy-dissolution in electrolytes. Here we knit ultrastable lock-and-key hydrogen-bonding networks between 2, 7-dinitropyrene-4, 5, 9, 10-tetraone (DNPT) and NH4+ charge carrier. DNPT with octuple-active carbonyl/nitro centers (H-bond acceptor) redox-exclusively accessible flexible tetrahedral ions donator) exclude larger rigid Zn2+ , due to a lower activation energy (0.14 vs. 0.31 eV). coordinated H-bonding chemistry conquers the stability barrier of electrolyte, gives fast diffusion kinetics non-metallic A stable two-step 4e- coordination cathode harvests high capacity (320 mAh g-1 ), high-rate capability (50 ) an ultralong life (60,000 cycles). This finding points new paradigm H-bond stabilized organic design advanced zinc batteries.

Язык: Английский

Процитировано

62
Tunnel‐Oriented VO2 (B) Cathode for High‐Rate Aqueous Zinc‐Ion Batteries DOI
Qian He, Tao Hu, Qiang Wu

и другие.

Advanced Materials, Год журнала: 2024, Номер 36(25)

Опубликована: Март 16, 2024

Tunnel-type vanadium oxides are promising cathodes for aqueous zinc ion batteries. However, unlike layer-type with adjustable layer distances, enhancing ion-transport kinetics in tunnels characterized by fixed sizes poses a considerable challenge. This study highlights that the macroscopic arrangement of electrode crucially determines tunnel orientation, thereby influencing transport. By changing material morphology, orientation can be optimized to facilitate rapid diffusion. In proof-of-concept demonstration, it is revealed (00l) facets-dominated VO

Язык: Английский

Процитировано

59
Non‐Metallic NH4+/H+ Co‐Storage in Organic Superstructures for Ultra‐Fast and Long‐Life Zinc‐Organic Batteries DOI
Yehui Zhang, Ziyang Song, Ling Miao

и другие.

Angewandte Chemie International Edition, Год журнала: 2023, Номер 63(3)

Опубликована: Ноя. 28, 2023

Compared with Zn

Язык: Английский

Процитировано

49
Interfacial synthesis of strongly-coupled δ-MnO2/MXene heteronanosheets for stable zinc ion batteries with Zn2+-exclusive storage mechanism DOI
Lisha Wu,

Yingying Mei,

Yuanhao Liu

и другие.

Chemical Engineering Journal, Год журнала: 2023, Номер 459, С. 141662 - 141662

Опубликована: Фев. 1, 2023

Язык: Английский

Процитировано

46
Multielectron Redox‐Bipolar Tetranitroporphyrin Macrocycle Cathode for High‐Performance Zinc‐Organic Batteries DOI
Ziyang Song, Ling Miao, Hui Duan

и другие.

Angewandte Chemie International Edition, Год журнала: 2024, Номер 63(16)

Опубликована: Фев. 19, 2024

Bipolar organics fuse the merits of n/p-type redox reactions for better Zn-organic batteries (ZOBs), but face capacity plafond due to low density active units and single-electron reactions. Here we report multielectron redox-bipolar tetranitroporphyrin (TNP) with quadruple two-electron-accepting n-type nitro motifs dual-electron-donating p-type amine moieties towards high-capacity-voltage ZOBs. TNP cathode initiates high-kinetics, hybrid anion-cation 10e

Язык: Английский

Процитировано

37
MXene‐mediated Interfacial Growth of 2D‐2D Heterostructured Nanomaterials as Cathodes for Zn‐based Aqueous Batteries DOI
Guangxun Zhang, Hui Yang,

Huijie Zhou

и другие.

Angewandte Chemie International Edition, Год журнала: 2024, Номер 63(18)

Опубликована: Фев. 21, 2024

In this study, we introduce a novel approach for synthesizing two-dimensional (2D) MXene heterostructures featuring sandwiched and cross-linked network structure. This method addresses the common issue of activity degradation in 2D nanomaterials caused by inevitable aggregation. By utilizing distinct surface characteristics MXene, successfully induced growth various on substrates. strategy effectively mitigates self-stacking defects augments exposure areas. particular, obtained 2D-2D MXene@NiCo-layered double hydroxide (MH-NiCo) exhibit enhanced structural stability, improved chemical reversibility, heightened charge transfer efficiency, outperforming pure NiCo LDH. The aqueous MH-Ni

Язык: Английский

Процитировано

37