Polymers,
Год журнала:
2024,
Номер
16(11), С. 1543 - 1543
Опубликована: Май 30, 2024
The
increasing
awareness
of
the
importance
a
clean
and
sustainable
environment,
coupled
with
rapid
growth
both
population
technology,
has
instilled
in
people
strong
inclination
to
address
issue
wastewater
treatment.
This
global
concern
prompted
individuals
prioritize
proper
management
purification
wastewater.
Organic
pollutants
are
very
persistent
due
their
destructive
effects,
it
is
necessary
remove
them
from
In
last
decade,
porous
organic
polymers
(POPs)
have
garnered
interest
among
researchers
effectiveness
removing
various
types
pollutants.
Porous
biopolymers
seem
be
suitable
candidates
POPs.
Sustainable
consumption
environmental
protection,
as
well
reducing
toxic
chemicals,
advantages
using
preparation
effective
composites
Composites
containing
biopolymers,
like
other
POPs,
can
through
absorption,
membrane
filtration,
or
oxidative
photocatalytic
effects.
Although
based
on
shown
relatively
good
performance
pollutants,
insufficient
strength
limits
performance.
On
hand,
comparison
including
covalent
frameworks,
they
weaker
Therefore,
generally
used
compounds.
seems
research
these
investigate
reasons
for
composite
components.
review
exhaustively
investigates
recent
progress
use
removal
form
adsorbents,
membranes,
catalysts,
etc.
Information
regarding
mechanism,
functionality,
each
component
construction
discussed.
following
provides
vision
future
opportunities
biopolymers.
Inorganic Chemistry,
Год журнала:
2023,
Номер
62(34), С. 14124 - 14133
Опубликована: Авг. 17, 2023
Nowadays,
coordination
polymers
(CPs)
are
promising
candidates
as
sensory
materials
for
their
high
sensitivity,
improved
selectivity,
fast
responsive
nature,
well
good
recyclability.
However,
poor
chemical
stability
often
makes
practical
usage
limited.
Herein,
employing
a
mixed
ligand
approach,
we
constructed
chemically
robust
CP,
{[Zn2L2(DPA)2]·3H2O}n
(IITKGP-70,
IITKGP
stands
the
Indian
Institute
of
Technology
Kharagpur),
which
exhibited
excellent
framework
robustness
not
only
in
water
but
also
over
broad
range
pH
solutions
(pH
=
3–11).
The
developed
displayed
selectivity
and
sensitivity
detection
trivalent
Al3+
ions
toxic
hexavalent
Cr(VI)-oxo
anions
an
aqueous
medium.
medium
turn-on
phenomenon
with
limit
(LOD)
value
1.29
μM,
whereas
turn-off
effect
was
observed
oxo-anions
(Cr2O72–
CrO42–)
having
LOD
values
0.27
0.71
respectively.
Both
mechanisms
speculated
via
spectroscopic
methods
coupled
several
ex
situ
studies.
Such
multiresponsive
nature
(both
turn-off)
targeted
cations
simultaneously
single
platform
robustness,
ease
scalability,
recyclability,
fast-responsive
IITKGP-70
highly
fascinating
material
real-world
applications.
Langmuir,
Год журнала:
2024,
Номер
40(10), С. 5060 - 5076
Опубликована: Фев. 28, 2024
Water
contamination
is
an
increasing
concern
to
mankind
because
of
the
amount
pollutants
in
aquatic
ecosystems.
To
purify
polluted
water,
various
techniques
have
been
used
remove
hazardous
components.
Unfortunately,
traditional
cleanup
with
a
low
uptake
capacity
are
unable
achieve
water
purification.
Metal–organic
frameworks
(MOFs)
recently
shown
potential
effective
pollutant
isolation
terms
selectivity
and
adsorption
over
porous
materials.
The
high
surface
area
versatile
functionality
MOFs
allow
for
development
new
adsorbents.
range
treatments
recent
five
years
will
be
highlighted
this
review,
along
assessments
performance
relevant
particular
task.
Moreover,
outlook
on
future
opportunities
purification
using
also
provided.
Scientific Reports,
Год журнала:
2024,
Номер
14(1)
Опубликована: Июнь 5, 2024
Abstract
This
study
reports
the
antibacterial
and
antibiofilm
activities
of
Magnesium
ferrite
nanoparticles
(MgFe
2
O
4
)
against
gram-positive
gram-negative
bacteria.
The
photocatalytic
degradation
Carbol
Fuchsin
(CF)
dye
(a
class
dyestuffs
that
are
resistant
to
biodegradation)
under
influence
UV-light
irradiation
is
also
studied.
crystalline
magnesium
were
synthesized
using
co-precipitation
method.
morphology
resulting
nanocomposite
was
examined
scanning
electron
microscopy
(SEM),
while
transmission
(TEM)
employed
for
further
characterization
particle
size.
Fourier
transform
infrared
(FTIR)
spectroscopy
X-ray
diffraction
(XRD)
utilized
analyze
structure,
chemical
composition,
surface
area,
respectively.
Optical
properties
evaluated
UV–Vis
spectroscopy.
UV-assisted
performance
MgFe
assessed
by
studying
decolorization
fuchsin
azo
dye.
crystallite
size
at
(311)
plane,
most
prominent
peak,
determined
be
28.5
nm.
10
ppm
CF
15
mg
resulted
in
a
significant
96%
reduction
after
135
min
ambient
temperature
(25
°C)
pH
value
9.
Additionally,
exhibited
potent
activity
E.
coli
S.
aureus
dose
dependent
manner
with
maximum
concentration
30
µg/ml.
Specifically,
demonstrated
substantial
via
disk
diffusion
microbroth
dilution
tests
zones
inhibition
minimum
inhibitory
concentrations
(MIC)
(26.0
mm,
1.25
µg/ml)
(23.0
2.5
µg/ml),
Moreover,
10.0
µg/ml
elicited
marked
percent
biofilm
formation
(89%)
followed
(78.5%)
treatment.
In
conclusion,
efficient
removal
capabilities
along
antimicrobial
bacterial
strains
suggesting
their
potential
as
promising
detoxifying
agents.
Membranes,
Год журнала:
2023,
Номер
13(8), С. 696 - 696
Опубликована: Июль 27, 2023
Connecting
organic
building
blocks
by
covalent
bonds
to
design
porous
crystalline
networks
has
led
frameworks
(COFs),
consequently
transferring
the
flexibility
of
dynamic
linkages
from
discrete
architectures
extended
structures.
By
virtue
library
and
diversity
topologies,
COFs
have
emerged
as
a
novel
field
materials
that
propose
platform
for
tailor-made
complex
structural
design.
Progress
over
past
two
decades
in
design,
synthesis,
functional
exploration
diverse
applications
successively
established
these
chemistry.
The
large-scale
synthesis
with
uniform
structures
properties
is
profound
importance
commercialization
industrial
applications;
however,
this
its
infancy
at
present.
An
innovative
designing
synthetic
approaches
paved
ways
address
future
hurdles.
This
review
article
highlights
fundamental
COFs,
including
principles,
coupling
reactions,
diversity,
strategies,
characterization,
growth
mechanism,
activation
aspects
COFs.
Finally,
major
challenges
trends
COF
fabrication
are
outlined.
Chemistry of Materials,
Год журнала:
2024,
Номер
36(9), С. 4468 - 4480
Опубликована: Апрель 17, 2024
Nitrogen-rich
porous
carbons
prepared
from
zeolitic
imidazolate
frameworks
(ZIFs)
offer
a
promising
platform
for
the
effective
confinement
of
small
guest
molecules.
However,
key
challenge
within
domain
liquid-phase
adsorption
lies
in
prevailing
microporosity
ZIF-derived
carbons,
which
impedes
diffusion
larger
molecules
and
hinders
efficiency.
In
order
to
maximize
carbon
availability,
methods
reshaping
particle
morphology
generating
mesoporosity
are
being
dynamically
developed.
Herein,
we
present
strategy
that
addresses
limitations
conventional
ZIF-8
endeavors
increase
capacities
toward
organic
pollutants
via
generation
dual-pore
system
along
with
obtaining
diverse
morphologies.
We
envisioned
developing
two
strategies
synthesize
unique
ZIF
precursors.
The
first
method
focused
on
preparation
zinc
oxides
form
nanoparticles
or
flowers.
second
approach,
crystalline
phase
was
transformed
into
pseudopolymorphic
(ZIF-CO3-1)
two-dimensional
structure.
study
unveils
unexplored
application
ZIF-CO3-1
preparing
functional
carbons.
Owing
architecture
ZnO@ZIF-8
precursors,
their
high-temperature
carbonization
generated
hierarchical
porosity
(micro/mesopores).
Compared
microporous
adsorbents
exhibited
superior
performance
removing
Auramine-O
Brilliant
Green
dyes,
sorption
257–544
247–395
mg/g,
respectively.
Their
efficiency
is
attributed
elevated
textural
parameters,
rich
surface
chemistry,
morphology,
improved
pore
accessibility.
