Electrochemical C–N coupling of CO₂and nitrogenous small molecules for the electrosynthesis of organonitrogen compounds

Chemical Society Reviews, Год журнала: 2023, Номер 52(6), С. 2193 - 2237

Опубликована: Янв. 1, 2023

Electrochemical C–N coupling reaction by renewable electricity for the electrosynthesis of organonitrogen compounds with abundant CO 2 and nitrogenous small molecules as carbon nitrogen sources, respectively, is a promising sustainable synthetic strategy.

Язык: Английский

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Review on Electrocatalytic Coreduction of Carbon Dioxide and Nitrogenous Species for Urea Synthesis

ACS Nano, Год журнала: 2023, Номер 17(4), С. 3209 - 3224

Опубликована: Фев. 14, 2023

The electrochemical coreduction of carbon dioxide (CO2) and nitrogenous species (such as NO3–, NO2–, N2, NO) for urea synthesis under ambient conditions provides a promising solution to realize carbon/nitrogen neutrality mitigate environmental pollution. Although an increasing number studies have made some breakthroughs in synthesis, the unsatisfactory Faradaic efficiency, low yield rate, ambiguous C–N coupling reaction mechanisms remain major obstacles its large-scale applications. In this review, we present recent progress on based CO2 aqueous solutions conditions, providing useful guidance discussion rational design metal nanocatalyst, understanding mechanism, existing challenges prospects synthesis. We hope that review can stimulate more insights inspiration toward development electrocatalytic technology.

Язык: Английский

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Size Effects of Highly Dispersed Bismuth Nanoparticles on Electrocatalytic Reduction of Carbon Dioxide to Formic Acid

Journal of the American Chemical Society, Год журнала: 2023, Номер 145(25), С. 14133 - 14142

Опубликована: Июнь 15, 2023

Electrocatalytic reduction of carbon dioxide into value-added chemical fuels is a promising way to achieve neutrality. Bismuth-based materials have been considered as favorable electrocatalysts for converting formic acid. Moreover, size-dependent catalysis offers significant advantages in catalyzed heterogeneous processes. However, the size effects bismuth nanoparticles on acid production not fully explored. Here, we prepared Bi uniformly supported porous TiO2 substrate electrocatalytic by situ segregation element from Bi4Ti3O12. The Bi-TiO2 electrocatalyst with 2.83 nm displays Faradaic efficiency greater than 90% over wide potential range 400 mV. Theoretical calculations also demonstrated subtle electronic structural evolutions induced variations nanoparticles, where display most active p-band and d-band centers guarantee high electroactivity toward CO2RR.

Язык: Английский

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Dual Atom Catalysts for Energy and Environmental Applications

Angewandte Chemie International Edition, Год журнала: 2023, Номер 62(40)

Опубликована: Июнь 7, 2023

The pursuit of high metal utilization in heterogeneous catalysis has triggered the burgeoning interest various atomically dispersed catalysts. Our aim this review is to assess key recent findings synthesis, characterization, structure-property relationship and computational studies dual-atom catalysts (DACs), which cover full spectrum applications thermocatalysis, electrocatalysis photocatalysis. In particular, combination qualitative quantitative characterization with cooperation DFT insights, synergies superiorities DACs compare counterparts, high-throughput catalyst exploration screening machine-learning algorithms are highlighted. Undoubtably, it would be wise expect more fascinating developments field as tunable

Язык: Английский

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Review on strategies for improving the added value and expanding the scope of CO₂ electroreduction products

Chemical Society Reviews, Год журнала: 2024, Номер 53(10), С. 5149 - 5189

Опубликована: Янв. 1, 2024

This review summarizes promising strategies including the design of catalysts and construction coupled electrocatalytic reaction systems, aimed at achieving selective production various products from CO 2 electroreduction.

Язык: Английский

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Dual‐Atomic‐Site Catalysts for Molecular Oxygen Activation in Heterogeneous Thermo‐/Electro‐catalysis

Angewandte Chemie International Edition, Год журнала: 2023, Номер 62(22)

Опубликована: Март 9, 2023

Efficient molecular oxygen activation (MOA) is the key to environmentally friendly catalytic oxidation reactions. In last decade, single-atomic-site catalysts (SASCs) with nearly 100 % atomic utilization and unique electronic structure have been widely investigated for MOA. However, single active site makes effect unsatisfactory difficult deal complex Recently, dual-atomic-site (DASCs) provided a new idea effective of (O2 ) due more diverse sites synergetic interactions among adjacent atoms. this review, we systematically summarized recent research progress DASCs MOA in heterogeneous thermo- electrocatalysis. Finally, look forward challenges application prospects construction

Язык: Английский

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Inter‐Metal Interaction of Dual‐Atom Catalysts in Heterogeneous Catalysis

Angewandte Chemie International Edition, Год журнала: 2023, Номер 62(42)

Опубликована: Июнь 14, 2023

Dual-atom catalysts (DACs) have been a new frontier in heterogeneous catalysis due to their unique intrinsic properties. The synergy between dual atoms provides flexible active sites, promising enhance performance and even catalyze more complex reactions. However, precisely regulating site structure uncovering dual-atom metal interaction remain grand challenges. In this review, we clarify the significance of inter-metal DACs based on understanding center structures. Three diatomic configurations are elaborated, including isolated single-atom, N/O-bridged dual-atom, direct dual-metal bonding interaction. Subsequently, up-to-date progress oxidation reactions, hydrogenation/dehydrogenation electrocatalytic photocatalytic reactions summarized. structure-activity relationship catalytic is then discussed at an atomic level. Finally, challenges future directions engineer discussed. This review will offer prospects for rational design efficient toward catalysis.

Язык: Английский

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Homonuclear dual-atom catalysts embedded on N-doped graphene for highly efficient nitrate reduction to ammonia: From theoretical prediction to experimental validation

Applied Catalysis B Environment and Energy, Год журнала: 2023, Номер 339, С. 123156 - 123156

Опубликована: Авг. 7, 2023

Язык: Английский

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Palladium-Copper bimetallic catalysts for electroreduction of CO2 and nitrogenous species

Coordination Chemistry Reviews, Год журнала: 2024, Номер 509, С. 215802 - 215802

Опубликована: Март 26, 2024

Язык: Английский

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Enhancing Local CO₂ Adsorption by L‐histidine Incorporation for Selective Formate Production Over the Wide Potential Window

Angewandte Chemie International Edition, Год журнала: 2023, Номер 62(49)

Опубликована: Окт. 19, 2023

Electrochemical carbon dioxide reduction reaction (CO2 RR) to produce valuable chemicals is a promising pathway alleviate the energy crisis and global warming issues. However, simultaneously achieving high Faradaic efficiency (FE) current densities of CO2 RR in wide potential range remains as huge challenge for practical implements. Herein, we demonstrate that incorporating bismuth-based (BH) catalysts with L-histidine, common amino acid molecule proteins, an effective strategy overcome inherent trade-off between activity selectivity. Benefiting from significantly enhanced adsorption capability promoted electron-rich nature by L-histidine integrity, BH catalyst exhibits excellent FEformate unprecedented windows (>90 % within -0.1--1.8 V >95 -0.2--1.6 versus reversible hydrogen electrode, RHE). Excellent performance can still be achieved under low-concentration feeding (e.g., 20 vol.%). Besides, extremely low onset -0.05 VRHE (close theoretical thermodynamic -0.02 ) was detected situ ultraviolet-visible (UV-Vis) measurements, together stable operation over 50 h preserved ≈95 partial density 326.2 mA cm-2 at -1.0 .

Язык: Английский

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