Visible-light-induced cascade chromone cyclization/chalcogenation to access 3-chalcogenyl-chromones using elemental sulfur/selenium DOI
Tao Guo,

Chang Gao,

Zhonghui Li

и другие.

Chemical Communications, Год журнала: 2024, Номер 60(99), С. 14866 - 14869

Опубликована: Янв. 1, 2024

An unprecedented photoredox-induced radical cascade for the synthesis of 3-chalcogenyl-chromones has been developed, which featured by wide substrate scope and good functional group tolerance.

Язык: Английский

Chromium‐Catalyzed Reductive Cross‐Coupling to Construct C−SS Bonds from Unactivated Alkyl Electrophiles DOI

Chao‐Peng Zhang,

Tian‐Zhang Wang,

Kang Wu

и другие.

ChemCatChem, Год журнала: 2024, Номер 16(15)

Опубликована: Март 15, 2024

Abstract Low‐valent chromium catalysts are cheap and less toxic compared to other transition metal catalysts. Here in, we reported a ligand‐free chromium(III)‐catalyzed manganese reductive cross‐coupling of unactivated alkyl electrophiles, such as sulfonates chlorides, with trisulfide dioxides thiolation agents form carbon−sulfur bonds. The powerful method featured ample substrate scope wide functional group tolerance, constructing large number unsymmetrical disulfides under simple conditions.

Язык: Английский

Процитировано

7
Nickel-free cross-electrophile coupling of unactivated alkyl bromides with thiosulfonates and sulfinyl sulfones DOI

Qiujin Fan,

Yanchuang Zhao,

Jintao Liang

и другие.

Organic Chemistry Frontiers, Год журнала: 2024, Номер 11(9), С. 2518 - 2527

Опубликована: Янв. 1, 2024

An unusual zinc-promoted reductive coupling between alkyl bromides and thiosulfonates under nickel-free conditions is described.

Язык: Английский

Процитировано

5
Semiconductor clusters enable high-efficiency extraction of hot electrons from gold nanorods for photocatalytic organic conversions DOI
Jiaxing Liu,

Hao Ma,

Shang‐Fu Yuan

и другие.

Science China Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Фев. 6, 2025

Язык: Английский

Процитировано

0
One-Pot Stepwise Dechalcogenization of Trisulfides to Unsymmetrical Dialkyl Thioethers DOI

Jiuwen Xu,

Ying Chen, Weidong Rao

и другие.

Organic Letters, Год журнала: 2025, Номер unknown

Опубликована: Апрель 17, 2025

The construction of C-S bonds has garnered significant interest due to the ubiquitous presence organosulfur compounds in natural products and bioactive molecules. Herein, we report a one-pot, stepwise desulfuration strategy employing trisulfides as precursors for synthesis unsymmetrical dialkylthioethers. Our study demonstrates that copper powder facilitates conversion into disulfides, which subsequently undergo nickel-catalyzed reductive coupling afford desired products. This approach provides practical, odorless, broadly applicable method

Язык: Английский

Процитировано

0
Manganese-promoted reductive cross-coupling of disulfides with dialkyl carbonates DOI

Chao‐Peng Zhang,

Tian‐Zhang Wang,

Yu‐Feng Liang

и другие.

Chemical Communications, Год журнала: 2023, Номер 59(97), С. 14439 - 14442

Опубликована: Янв. 1, 2023

Manganese is a cheap and environmentally friendly metal on Earth. Herein, we report manganese-promoted reductive cross-coupling using easily available odorless disulfides as thiolating agents in an excellent 100% sulfur atom economy. The protocol featured broad substrate scope, including various alkyl functional group compatibility, constructing diverse thioethers under simple conditions. Ultimately, can be prepared gram-scale reactions further transformed into structurally complex molecules.

Язык: Английский

Процитировано

8
Recent advances in electrochemical difunctionalization of alkenes and alkynes for the synthesis of organohalides DOI
Yu Zheng, Wenguang Lu,

Chunxi Chen

и другие.

Organic Chemistry Frontiers, Год журнала: 2024, Номер 11(18), С. 5306 - 5324

Опубликована: Янв. 1, 2024

This review summarizes recent achievements in electrosynthesis of organohalides through difunctionalization alkenes and alkynes provides insights into future directions for the development field.

Язык: Английский

Процитировано

2
Bioinspired zinc-mediated umpolung thiolation of alkyl electrophiles: reaction development, scope and mechanism DOI

Yuenian Xu,

Yan Zhang, Yong Liu

и другие.

Science China Chemistry, Год журнала: 2023, Номер 67(3), С. 898 - 907

Опубликована: Дек. 4, 2023

Язык: Английский

Процитировано

6
Iron-Catalyzed Markovnikov-Selective Radical Hydrochalcogenation of Unactivated Alkenes DOI
Jiayi Li, Xia Liu, Zhaohui Liu

и другие.

ACS Catalysis, Год журнала: 2024, Номер 15(1), С. 14 - 22

Опубликована: Дек. 12, 2024

A Markovnikov-selective radical hydrochalcogenation reaction of unactivated alkenes via iron-catalyzed hydrogen atom transfer was reported. Using N-(arylsulfenyl)arenesulfonamide, PhSO2SCD3, S-alkyl thiosulfonate, dithiosulfonate and Ebselen derivatives as versatile radicalophiles, a wide range unsymmetrical alkyl-aryl, dialkyl SCD3 (D > 99%) containing sulfides, disulfides, well organoselenides have been collectively synthesized under mild conditions. As powerful alternative to the classical thiol–ene reaction, this protocol features exclusive Markovnikov selectivity, good functional group tolerance broad substrate scope. number probe experiments suggest proceeds through pathway. The synthetic utility transformation also demonstrated late-stage modifications diverse natural products bioactive molecules.

Язык: Английский

Процитировано

1
Visible-light-induced cascade chromone cyclization/chalcogenation to access 3-chalcogenyl-chromones using elemental sulfur/selenium DOI
Tao Guo,

Chang Gao,

Zhonghui Li

и другие.

Chemical Communications, Год журнала: 2024, Номер 60(99), С. 14866 - 14869

Опубликована: Янв. 1, 2024

An unprecedented photoredox-induced radical cascade for the synthesis of 3-chalcogenyl-chromones has been developed, which featured by wide substrate scope and good functional group tolerance.

Язык: Английский

Процитировано

0