Опубликована: Янв. 1, 2024
Язык: Английский
Advanced Materials, Год журнала: 2024, Номер unknown
Опубликована: Ноя. 27, 2024
Abstract Photocatalysis leverages solar energy to overcome the thermodynamic barrier, enabling efficient chemical reactions under mild conditions. It can greatly reduce reliance on traditional sources and has attracted significant research interest. Reticular materials, including metal‐organic frameworks (MOFs) covalent organic (COFs), represent a class of crystalline materials constructed from molecular building blocks linked by coordination bonds, respectively. function as heterogeneous catalysts, combining well‐defined structures high tailorability akin homogeneous catalysts. In this review, regulation light absorption, charge separation, surface in photocatalytic process through precise molecular‐level design based features reticular is elaborated. Notably, for MOFsmicroenvironment modulation around catalytic sites affects performance delved, with emphasis their unique dynamic flexible microenvironments. For COFs, inherent excitonic effects due fully nature discussed highlight strategies regulate charge‐ and/or energy‐transfer‐mediated photocatalysis. Finally, current challenges future directions field, aiming provide comprehensive understanding how be optimized enhanced photocatalysis discussed.
Язык: Английский
Процитировано
11
Coordination Chemistry Reviews, Год журнала: 2024, Номер 515, С. 215965 - 215965
Опубликована: Май 23, 2024
Язык: Английский
Процитировано
9
Chemistry - A European Journal, Год журнала: 2024, Номер 30(37)
Опубликована: Май 1, 2024
Abstract Recent interest has surged in using heterogeneous carriers to boost synergistic photocatalysis for organic transformations. Heterogeneous catalysts not only facilitate enhancement of distinct catalytic centers compared their homogeneous counterparts, but also allow the easy recovery and reuse catalysts. This mini‐review summarizes recent advancements developing carriers, including metal–organic frameworks, covalent–organic porous polymers, others, reactions. The advantages materials catalysis originate from ability provide a high surface area, enhanced mass transport, offer tunable chemical structure, ensure stability active species, enable Both photosensitizers can be intricately incorporated into suitable create dual photocatalysts Notably, experimental evidence reported cases shown that efficacy often surpasses analogues. performance is attributed proximity confinement effects provided by nature carriers. It expected will versatile platform integrating diverse catalysts, thus exhibiting superior across range transformations appealing prospect industrial applications.
Язык: Английский
Процитировано
6
Inorganic Chemistry, Год журнала: 2024, Номер 63(26), С. 12333 - 12341
Опубликована: Июнь 20, 2024
Metal-anchored covalent organic frameworks (COFs), as a class of significant derivatives COFs, are widely used heterogeneous catalysts in diverse chemical reactions. However, they typically synthesized via post-treatment strategies, which often lead to the decline COF crystallinity, decrease porous properties, instability catalytic performances, generation additional waste, and consumption excess time energy. In this work, we demonstrate an approach construct metal-functionalized one-pot method induced by γ-ray radiation. Specifically, copper-coordinated was situ irradiating mixture monomers copper salt under ambient conditions. Interestingly, initial Cu
Язык: Английский
Процитировано
3
Chemical Engineering Science, Год журнала: 2025, Номер unknown, С. 121509 - 121509
Опубликована: Март 1, 2025
Язык: Английский
Процитировано
0
Journal of Catalysis, Год журнала: 2025, Номер unknown, С. 116079 - 116079
Опубликована: Март 1, 2025
Язык: Английский
Процитировано
0
Biosensors and Bioelectronics, Год журнала: 2025, Номер unknown, С. 117461 - 117461
Опубликована: Апрель 1, 2025
Язык: Английский
Процитировано
0
Chem & Bio Engineering, Год журнала: 2025, Номер unknown
Опубликована: Апрель 16, 2025
Язык: Английский
Процитировано
0
Advanced Science, Год журнала: 2025, Номер unknown
Опубликована: Апрель 30, 2025
Enzymes have been recognized as highly efficient biocatalysts, whereas characteristics such poor stability and single reaction type greatly significantly limit their wide application. Hence, the exploitation of suitable carriers for immobilized enzymes enables provision a protective layer enzyme, with capability chemical biological cascade catalysis. Among various immobilization carriers, metal-organic frameworks (MOFs), covalent organic (COFs) hydrogen-bonded (HOFs) emerging promising strategy to surpass inherent instability other limitations free enzymes. Specifically, integration artificial porous materials improves reusability enzymes, while simultaneously affording platform multifunctional applications. Herein, this review systematically discusses preparation strategies advantages materials, elucidating effects different methods on enzyme activity. Furthermore, innovative applications in field fields photocatalysts, catalysts sensing are also comprehensively summarized here, thus demonstrating addressing complex biotransformation challenges.
Язык: Английский
Процитировано
0
Micro and Nano Systems Letters, Год журнала: 2025, Номер 13(1)
Опубликована: Май 12, 2025
Abstract Nanoparticles (NPs) are redefining enzyme immobilization, offering a paradigm shift in biocatalysis through precision engineering at the nanoscale. With their exceptional surface area, tunable porosity, and customizable functionalities, NPs provide unprecedented control over stability, activity, adaptability, bridging gap between molecular-scale interactions industrial-scale applications. In era of intelligent bioprocessing, how can NP-based immobilization strategies be optimized to drive next frontier sustainable high-performance technologies? A deep understanding NP structural diversity, interfacial chemistry, enzyme-matrix is crucial unlocking full potential. This review systematically explores emerging platforms, including cross-linked aggregates (CLEAs), covalent organic frameworks (COFs), nanoflowers, nanofibers, carbon nanotubes (CNTs), graphene oxide (GO), ionic liquids (ILs), layered double hydroxides (LDHs), each tailored advantages for catalytic enhancement process efficiency. The outlines current advancements such as 3D printing wearable biosensors, forecasts integration artificial intelligence smart nano-biocatalysts, envisions futuristic applications bio-intelligent nano/micro-robotic systems space biosensors. Challenges, upscaling limitations, nanotoxicity concerns, environmental risks, addressed ensure safe viable implementation. provides structured roadmap on (I) advances using next-generation NPs, (II) challenges scalability safety, (III) sustainability benefits enzyme-based industrial biocatalysis, (IV) emergence intelligence, nanoscale technologies AI-assisted design optimization. These visionary approaches mark toward dynamic, adaptive, highly specialized, multifunctional nano-enzyme systems. Graphical
Язык: Английский
Процитировано
0