Sustainable Energy & Fuels,
Год журнала:
2024,
Номер
8(16), С. 3617 - 3629
Опубликована: Янв. 1, 2024
The
discovery
of
graphdiyne
(GDY)
represents
a
significant
advancement
in
the
field
carbon
allotropes,
and
has
garnered
widespread
attention
for
its
potential
applications
hydrogen
production.
Photothermal
catalysis
represents
a
clean,
efficient,
and
sustainable
approach
to
harnessing
solar
energy
drive
chemical
reactions.
However,
the
inherent
trade-off
between
mass
heat
transport
efficiencies
poses
significant
challenges
its
applicability.
Herein,
nature-inspired
hollow
silica
nanocone
array
catalyst
(HSNCA/Co)
is
developed
address
this
limitation
by
enhancing
management
sunlight-absorptive
ability,
while
maintaining
exposure
of
active
sites.
The
structure
creates
dual-flow-rate
regions
that
enable
multidimensional
optimization
thermal
simultaneous
mitigation
all
three
primary
dissipation
pathways.
Moreover,
dense
enhances
light
trapping
plasmon
coupling
efficacy,
achieving
nearly
99%
broadband
absorption.
In
CO2
hydrogenation
model
reaction,
system
achieved
conversion
rate
4427.2
mmol
gCo-1
h-1
under
intense
illumination,
one
highest
reported
performances
among
cobalt-based
catalysts.
This
study
emphasizes
role
light-to-heat
in
photothermal
offers
potential
strategy
for
design
catalytic
materials.
Sustainable Energy & Fuels,
Год журнала:
2024,
Номер
8(16), С. 3617 - 3629
Опубликована: Янв. 1, 2024
The
discovery
of
graphdiyne
(GDY)
represents
a
significant
advancement
in
the
field
carbon
allotropes,
and
has
garnered
widespread
attention
for
its
potential
applications
hydrogen
production.