Ni‐Catalyzed Cross‐Electrophile Couplings of N‐Alkoxyphthalimides and Aryl Halides

European Journal of Organic Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Апрель 13, 2025

N ‐alkoxyphthalimides represent a versatile class of redox‐active alcohol derivatives for carbon–carbon bond formation following activation by single‐electron reduction. Herein, key precedents using the new bonds under photochemical reaction conditions are first presented. The merger these and other strategies with Ni catalysis in various cross‐electrophile couplings aryl halides is then highlighted. A particular focus made on mechanisms proposed Ni‐catalyzed reductive cross‐couplings. Concluding thoughts future design as C(sp 3 )O transition metal‐catalyzed cross‐couplings also

Язык: Английский

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Methyl chlorothioformate as a convenient reagent for thionoester synthesis

RSC Advances, Год журнала: 2025, Номер 15(19), С. 15116 - 15120

Опубликована: Янв. 1, 2025

A promising reagent for introducing the methyl thionoester function into organic molecules through a straightforward synthetic sequence based on common magnesium organics is proposed.

Язык: Английский

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Recent advances in asymmetric synthesis via cyclopropanol intermediates

Organic & Biomolecular Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Дек. 4, 2024

The review summarizes achievements in stereoselective and stereoretentive transformations of cyclopropanols suitable for asymmetric synthesis.

Язык: Английский

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Photocatalyzed O- to S- Rearrangement of Cyclopropanols

Synfacts, Год журнала: 2024, Номер 20(06), С. 0600 - 0600

Опубликована: Май 14, 2024

Key words iridium catalysis - rearrangement photocatalysis cyclopropanes

Язык: Английский

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