Rigid Additives Enabling Inorganic‐Rich Interphase via Steric Effects and Van der Waals Force for Stable Lithium Metal Batteries DOI Open Access

Shu-Hao Yao,

Chi Guo, Yu-Xi Yang

и другие.

Advanced Functional Materials, Год журнала: 2024, Номер unknown

Опубликована: Дек. 11, 2024

Abstract Electrolyte additives (EAs) are cost‐effective for stabilization of lithium metal batteries (LMBs). Nevertheless, most EAs gradually consumed during the deposition process, rendering them inadequate long‐term cyclability. Herein, a novel hybrid metal–organic framework (MOF)‐based non‐expendable additive is prepared through polymerization pentaerythritol tetraacrylate (PETEA) on zeolitic imidazolate (ZIF‐67). Owing to partial coating by PETEA‐based polymer, exposed unsaturated sites ZIF‐67 still attenuate interaction between ions (Li + ) and anions, enabling rapid electrochemical kinetics uniform Li deposition. Concurrently, polymerized PETEA partially enters solvation sheath expels some organic solvents Van der Waals interactions, which promotes derivation an inorganic‐rich SEI inhibits dendrite formation. Accordingly, this additive‐contained Li||Li symmetric cell exhibits stability over 1200 h with small overpotential 75 mV. Additionally, assembled Li||LiFePO 4 full cells negative/positive ratio 1.76 delivers stable cyclability 400 cycles at 0.5 C. Moreover, Li||LiNi 0.8 Mn 0.1 Co O 2 high‐voltage displays impressive capacity retention 80% 311 This study provides valuable guidance design multifunctional advancing high‐performance LMBs.

Язык: Английский

Recent advances in potassium metal batteries: electrodes, interfaces and electrolytes DOI Creative Commons
Jianlu Sun, Yichen Du, Yijiang Liu

и другие.

Chemical Society Reviews, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

This review explores the latest advancements in potassium metal batteries, including electrode design, interface engineering, and electrolyte optimization to suppress dendrite formation enhance cycling stability.

Язык: Английский

Процитировано

5
A Thermally Robust Biopolymeric Separator Conveys K+ Transport and Interfacial Chemistry for Longevous Potassium Metal Batteries DOI

Yuyuan Wang,

Liang Xu, Xiaopeng Chen

и другие.

ACS Nano, Год журнала: 2025, Номер unknown

Опубликована: Янв. 15, 2025

Potassium metal batteries (KMBs) hold promise for stationary energy storage with certain cost and resource merits. Nevertheless, their practicability is greatly handicapped by dendrite-related anodes, the target design of specialized separators to boost anode safety in its nascent stage. Here, we develop a thermally robust biopolymeric separator customized via solvent-exchange amino-siloxane decoration strategy render durable safe KMBs. Through experimental investigation theoretical computation, reveal that optimized porosity surface functionalization could manage ion transport interfacial chemistry, thereby enabling efficient K+ diffusion favorable solid electrolyte interphase achieve prolonged cycling stability (over 3000 h). The thus-assembled full cell retains 80% initial capacity after 400 cycles at 0.5 A g–1. heat-proof property designed further demonstrated. Our separator, affording multifunctional features, provides an appealing solution circumvent instability issues associated potassium batteries.

Язык: Английский

Процитировано

1
Recent progress in nonaqueous electrolytes and interfaces for potassium-ion batteries DOI

Haobo Xia,

Hao Lou,

Luanjie Nie

и другие.

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 159970 - 159970

Опубликована: Янв. 1, 2025

Язык: Английский

Процитировано

1
Strategies to boost the electrochemical performance of bismuth anodes for potassium-ion batteries DOI Creative Commons

Xunzhu Zhou,

Xiaohong Chen,

Wenxi Kuang

и другие.

Chemical Science, Год журнала: 2024, Номер 15(31), С. 12189 - 12199

Опубликована: Янв. 1, 2024

Potassium-ion batteries (PIBs) are considered potential candidates for large-scale energy storage systems due to the abundant resources of potassium. Among various reported anode materials, bismuth anodes with advantages high theoretical specific capacity, low cost, and nontoxicity have attracted widespread attention. However, experience significant volume changes during charge/discharge process, leading unsatisfactory cycling stability rate performance. In this review, we focus on summarizing research progress in PIBs. We discuss detail modification strategies PIBs, including electrolyte optimization, morphology design, hybridization carbon materials. addition, attempt propose possible future directions development aiming expedite their practical application. It is believed that review can assist researchers more efficiently designing high-performance materials

Язык: Английский

Процитировано

4
The Ether’s Chain Length Effect in Electrolyte for Hard carbon towards Efficient Sodium Storage at Low Temperature DOI
Jiabao Li,

Jingjing Hao,

Quan Yuan

и другие.

Nano Energy, Год журнала: 2024, Номер 132, С. 110362 - 110362

Опубликована: Окт. 12, 2024

Язык: Английский

Процитировано

4
Recent Progress on Organic Liquid Electrolyte for High‐Temperature Sodium Batteries DOI
S.-M. Zhou, Xiaohong Chen, Xiao-Sa Zhang

и другие.

Advanced Functional Materials, Год журнала: 2025, Номер unknown

Опубликована: Фев. 26, 2025

Abstract Sodium batteries are considered promising candidates for large‐scale energy storage systems due to abundant sodium resources and low costs. However, suffer from serious transition metal dissolution, undesirable side reactions, increased thermal runaway risk at elevated operation temperatures. Electrolyte, as a key component of batteries, is closely related temperature tolerance. Herein, we focus on recent achievements in organic liquid electrolyte high‐temperature batteries. First, the failure mechanisms discussed Subsequently, introduce components summarize effective optimization strategies including salt selection, concentration regulation, solvents optimization, additives. Finally, further directions proposed. It believed that this review can provide whole picture insight into design

Язык: Английский

Процитировано

0
Achieving Superior Critical Current Density and Rate Performance in Solid-State Lithium Batteries via Vertically Aligned LATP Arrays DOI
Yongbiao Mu, Lin Yang,

Yitian Feng

и другие.

Nano Energy, Год журнала: 2025, Номер unknown, С. 110885 - 110885

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

0
Bulky steric hindrance effect-mediated weakly solvating electrolytes for highly reversible potassium-metal batteries DOI
Yuqing Cao, H. Zhou, Zhaoxuan Li

и другие.

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 161933 - 161933

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

0
Fast Li+ De‐Solvation Kinetics with PDDA Intercalated‐Montmorillonite Hybrid Artificial Interface Layer on Cu Substrate for Lithium Metal Batteries in a Wide Climate Temperature DOI Open Access
Yuxi Shen, Jianan Gu,

Zengquan Zhu

и другие.

Advanced Functional Materials, Год журнала: 2024, Номер unknown

Опубликована: Окт. 10, 2024

Abstract The tolerance requirement of lithium metal batteries in harsh environments presents great challenges to electrode materials and electrolytes because temperature plays a significant effect electrochemical processes. In this study, new artificial layer on copper current collector that boosts the de‐solvation kinetics provides electrostatic shielding effects is presented enhance performance batteries. This constructed with poly(diallyl dimethyl ammonium chloride) (PDDA) exfoliated montmorillonite (MMT) nanosheets, which combine advantages both inorganic clay organic polymer. Within protective hybrid layer, PDDA cations increase interlayer spacing MMT, broadening diffusion pathways Li + accelerating their fast diffusion. Moreover, PDDA‐MMT facilitates at interface anode electrolyte, enabling rapid reversible plating/stripping metal. As result, as‐prepared PDDA‐MMT@Cu exhibits excellent stability, good rate achieved commercial electrolyte range −20–60 °C. By combining enhanced as an clay‐polymer composite synergistic interaction offers inspiration for development

Язык: Английский

Процитировано

0
Rigid Additives Enabling Inorganic‐Rich Interphase via Steric Effects and Van der Waals Force for Stable Lithium Metal Batteries DOI Open Access

Shu-Hao Yao,

Chi Guo, Yu-Xi Yang

и другие.

Advanced Functional Materials, Год журнала: 2024, Номер unknown

Опубликована: Дек. 11, 2024

Abstract Electrolyte additives (EAs) are cost‐effective for stabilization of lithium metal batteries (LMBs). Nevertheless, most EAs gradually consumed during the deposition process, rendering them inadequate long‐term cyclability. Herein, a novel hybrid metal–organic framework (MOF)‐based non‐expendable additive is prepared through polymerization pentaerythritol tetraacrylate (PETEA) on zeolitic imidazolate (ZIF‐67). Owing to partial coating by PETEA‐based polymer, exposed unsaturated sites ZIF‐67 still attenuate interaction between ions (Li + ) and anions, enabling rapid electrochemical kinetics uniform Li deposition. Concurrently, polymerized PETEA partially enters solvation sheath expels some organic solvents Van der Waals interactions, which promotes derivation an inorganic‐rich SEI inhibits dendrite formation. Accordingly, this additive‐contained Li||Li symmetric cell exhibits stability over 1200 h with small overpotential 75 mV. Additionally, assembled Li||LiFePO 4 full cells negative/positive ratio 1.76 delivers stable cyclability 400 cycles at 0.5 C. Moreover, Li||LiNi 0.8 Mn 0.1 Co O 2 high‐voltage displays impressive capacity retention 80% 311 This study provides valuable guidance design multifunctional advancing high‐performance LMBs.

Язык: Английский

Процитировано

0