Transient transition from stable to dissipative assemblies in response to the spatiotemporal availability of a chemical fuel DOI Creative Commons
Haridas Kar, Rui Chen, Krishnendu Das

и другие.

Angewandte Chemie, Год журнала: 2024, Номер unknown

Опубликована: Окт. 15, 2024

Abstract The transition from inactive to active matter implies a thermodynamically stable energy‐dissipating structures. Here, we show how the spatiotemporal availability of chemical fuel causes self‐assembled structure transiently pass an state. system relies on local injection weak affinity phosphodiester substrate into agarose hydrogel containing surfactant‐based structures templated by ATP. Injection leads inclusion additional surfactant molecules in assemblies leading formation catalytic hotspots for conversion. After disappearance as result conversion and diffusion spontaneously return state, which can be reactivated upon new batch fuel. study illustrates dissipating cope with intermittent energy without compromising long‐term structural stability.

Язык: Английский

Transient transition from stable to dissipative assemblies in response to the spatiotemporal availability of a chemical fuel DOI Creative Commons
Haridas Kar, Rui Chen, Krishnendu Das

и другие.

Angewandte Chemie International Edition, Год журнала: 2024, Номер unknown

Опубликована: Окт. 15, 2024

The transition from inactive to active matter implies a thermodynamically stable energy-dissipating structures. Here, we show how the spatiotemporal availability of chemical fuel causes self-assembled structure transiently pass an state. system relies on local injection weak affinity phosphodiester substrate into agarose hydrogel containing surfactant-based structures templated by ATP. Injection leads inclusion additional surfactant molecules in assemblies leading formation catalytic hotspots for conversion. After disappearance as result conversion and diffusion spontaneously return state, which can be reactivated upon new batch fuel. study illustrates dissipating cope with intermittent energy without compromising long-term structural stability.

Язык: Английский

Процитировано

1
Transient transition from stable to dissipative assemblies in response to the spatiotemporal availability of a chemical fuel DOI Creative Commons
Haridas Kar, Rui Chen, Krishnendu Das

и другие.

Angewandte Chemie, Год журнала: 2024, Номер unknown

Опубликована: Окт. 15, 2024

Abstract The transition from inactive to active matter implies a thermodynamically stable energy‐dissipating structures. Here, we show how the spatiotemporal availability of chemical fuel causes self‐assembled structure transiently pass an state. system relies on local injection weak affinity phosphodiester substrate into agarose hydrogel containing surfactant‐based structures templated by ATP. Injection leads inclusion additional surfactant molecules in assemblies leading formation catalytic hotspots for conversion. After disappearance as result conversion and diffusion spontaneously return state, which can be reactivated upon new batch fuel. study illustrates dissipating cope with intermittent energy without compromising long‐term structural stability.

Язык: Английский

Процитировано

0