Angewandte Chemie, Год журнала: 2024, Номер 137(1)
Опубликована: Ноя. 12, 2024
Abstract We recently reported the gold‐catalyzed Heck and chain‐walking reactions, which utilize migratory insertion, β ‐hydride elimination steps in a catalytic fashion. Budzelaar et al. their correspondence state that these reactions proceed through alkene heteroarylation followed by acid‐mediated cyclization sequence. In response to this correspondence, we have conducted some experiments convinced us product formation solely can not be rationalized based on hetero‐arylation of alkenes under ligand‐enabled Au(I)/Au(III) catalysis.
Язык: Английский