A Photocatalytic Approach to Radical 1-(Trifluoromethyl)cyclopropanation DOI Creative Commons

Sven Timmann,

Moritz T. H. Dilchert,

Jörg Dietzel

и другие.

ACS Catalysis, Год журнала: 2025, Номер unknown, С. 7232 - 7240

Опубликована: Апрель 17, 2025

Язык: Английский

Copper-Catalyzed Diastereoselective Addition of a [1,1,1]Propellane Dimer to N-tert-Butanesulfinyl Aldimines DOI
Yihui Li,

Yuan Han,

Jia-Xuan Luo

и другие.

Organic Letters, Год журнала: 2025, Номер unknown

Опубликована: Март 21, 2025

[1,1,1]Propellane is typically used as a building block for the construction of bicyclo[1,1,1]pentanes and cyclobutanes. In this work, diverse chiral bi(methylenecyclobutylidene) complexes were synthesized by diastereoselective addition [1,1,1]propellane dimer to N-tert-butanesulfinyl aldimines in presence copper bipyridine. Density functional theory calculations revealed that both step regeneration catalyst contributed generation favored (Ss,S,S)-diastereomer.

Язык: Английский

Процитировано

0
A Photocatalytic Approach to Radical 1-(Trifluoromethyl)cyclopropanation DOI Creative Commons

Sven Timmann,

Moritz T. H. Dilchert,

Jörg Dietzel

и другие.

ACS Catalysis, Год журнала: 2025, Номер unknown, С. 7232 - 7240

Опубликована: Апрель 17, 2025

Язык: Английский

Процитировано

0