Heterostructure of Hydrogen‐Bonded Organic Frameworks for White Light Emission and Information Encryption DOI
He Zhao,

Siwen Hu,

Liang Meng

и другие.

Advanced Optical Materials, Год журнала: 2024, Номер unknown

Опубликована: Окт. 25, 2024

Abstract Two dumbbell‐shaped building blocks (TMB and TMBT), featuring methyl benzoate groups as hydrogen bond units, are selected to construct heterostructures of HOFs, aiming achieve multiple functions including white luminescence, stimulus‐response behavior, well application in information encryption. TMB molecules self‐assembled form a flexible HOF (X‐HOF‐8) p‐xylene, containing solvent channels blue fluorescence. Upon removal guests, it can transform into nonporous crystal with gray In contrast, TMBT forms guest‐free (X‐HOF‐9) displaying orange They could bulk heterojunction (BHJ) HOFs energy transfer from TMBT, exhibiting composition‐dependent fluorescent color. Notably, emission be achieved BHJ converted fluorescence upon guest removal; subsequently, is restored re‐capturing guests. Furthermore, rod‐like triblock (THJ) also constructed, which exhibit regulatory behavior response gaining or losing The unique luminescent characteristics stimulus responsiveness these make them an excellent platform for applications anticounterfeit. This represents the pioneering achievement light HOF, groundbreaking realization THJ remarkable exciting characteristics.

Язык: Английский

Influence of π–π interactions on organic photocatalytic materials and their performance DOI Creative Commons
Liquan Jing, Pandeng Li, Zheng Li

и другие.

Chemical Society Reviews, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

A comprehensive review is provided on the impact, construction strategies and applications of π–π interactions in field photocatalysis.

Язык: Английский

Процитировано

2
Hydrogen-bonded organic frameworks for photocatalytic synthesis of hydrogen peroxide DOI Creative Commons
Jihong Zhang,

Zhao‐Ming Ge,

J. M. Wang

и другие.

Nature Communications, Год журнала: 2025, Номер 16(1)

Опубликована: Март 11, 2025

Photocatalysis provides a sustainable and environment-friendly strategy to produce H2O2, yet the catalytic efficiency of H2O2 overall photosynthesis (O2 + 2H2O → 2H2O2) needs be further improved, especially in absence additional cocatalysts, photosensitizers sacrificial agents. Here we find that hydrogen-bonded organic frameworks can serve as photocatalysts for under above-mentioned conditions. Specifically, constructed donor–acceptor framework exhibits high photocatalytic activity photosynthesis, with production rate 681.2 μmol g-1 h-1. The control experiments theoretical calculation revealed structures not only accelerate charge separation transfer but also optimize reaction pathways, which significantly boosts photosynthesis. This work insights into design development efficient A series were developed production. These materials are shown facilitate pathway toward H2O2.

Язык: Английский

Процитировано

0
Anti-interference Detection of Antibiotic Resistance Genes via Tetrahedral DNA Framework–Velcro Capturing Py-HOF@Ti3C2 MXene DOI
Liqi Liu,

Xujing Feng,

Yi Zou

и другие.

Journal of Hazardous Materials, Год журнала: 2025, Номер unknown, С. 138146 - 138146

Опубликована: Апрель 1, 2025

Язык: Английский

Процитировано

0
Heterostructure of Hydrogen‐Bonded Organic Frameworks for White Light Emission and Information Encryption DOI
He Zhao,

Siwen Hu,

Liang Meng

и другие.

Advanced Optical Materials, Год журнала: 2024, Номер unknown

Опубликована: Окт. 25, 2024

Abstract Two dumbbell‐shaped building blocks (TMB and TMBT), featuring methyl benzoate groups as hydrogen bond units, are selected to construct heterostructures of HOFs, aiming achieve multiple functions including white luminescence, stimulus‐response behavior, well application in information encryption. TMB molecules self‐assembled form a flexible HOF (X‐HOF‐8) p‐xylene, containing solvent channels blue fluorescence. Upon removal guests, it can transform into nonporous crystal with gray In contrast, TMBT forms guest‐free (X‐HOF‐9) displaying orange They could bulk heterojunction (BHJ) HOFs energy transfer from TMBT, exhibiting composition‐dependent fluorescent color. Notably, emission be achieved BHJ converted fluorescence upon guest removal; subsequently, is restored re‐capturing guests. Furthermore, rod‐like triblock (THJ) also constructed, which exhibit regulatory behavior response gaining or losing The unique luminescent characteristics stimulus responsiveness these make them an excellent platform for applications anticounterfeit. This represents the pioneering achievement light HOF, groundbreaking realization THJ remarkable exciting characteristics.

Язык: Английский

Процитировано

2