Electrochemical Cell Designs for Efficient Carbon Dioxide Reduction and Water Electrolysis: Status and Perspectives DOI Creative Commons
Zhangsen Chen, Lei Zhang, Shuhui Sun

и другие.

Advanced Materials, Год журнала: 2025, Номер unknown

Опубликована: Май 30, 2025

Abstract Integrating renewable electricity and concentrated CO 2 from direct air capture, electrochemical reduction reactions (eCO RR) offer a promising pathway for converting into fuel chemicals, enabling the closure of carbon loop in sustainable manner. The clean H produced via hydrogen evolution reaction (HER) during water electrolysis can replace traditional fossil fuels without additional emissions. Achieving large‐scale high‐efficiency eCO RR HER requires development rational electrolyzer designs, which are crucial industrial implementation. This review examines recent innovations system designs RR, HER, latest advances situ cell operando characterization reactions. It focuses on improvements flow patterns, membrane electrode assemblies, electrolyte engineering to maximize catalytic activities at level. Besides, discusses optimizing counter‐anodic improve energy efficiency electrolysis, offering insights design systems with efficient utilization. Furthermore, it explores integration other (e.g., cells), highlighting their potential role decarbonization future processes. Finally, summary, challenge, outlook industrial‐scale concluded.

Язык: Английский

Electron Shuttling of Iron‐Oxygen‐Cobalt Bridging in Cobalt Assembled Iron Oxyhydroxide Catalyst Boosts the Urea Oxidation Stability and Activity DOI Open Access

Guizeng Liang,

Rongrong Zhang, C. S. Ji

и другие.

Advanced Functional Materials, Год журнала: 2025, Номер unknown

Опубликована: Март 21, 2025

Abstract Iron (Fe)‐based materials hold great potential as urea oxidation reaction (UOR) catalysts, however, the deactivation of active Fe‐oxyhydroxide (FeOOH) species induced by its dissolution during catalytic process under high current densities is still significant challenge. Herein, cobalt (Co) assembled FeOOH constructed, and formation Iron‐Oxygen‐Cobalt (Fe‐O‐Co) bridging triggers electron transfer from Co to Fe sites. This shuttling induces low valence state sites in FeOOH. Co‐FeOOH catalyst achieves a density 1000 mA cm −2 at voltage merely 1.59 V, showing substantial improvement compared pure (1.97 V). Meanwhile, urea‐assisted anion exchange membrane electrolyzer, after 24 h continuous operation , fluctuation 12.4%, significantly lower than that (49.9%). The situ experiments theoretical calculations demonstrate Fe‐O‐Co endows suppressive Fe‐segregation, fast charge Fe(Co)OOH phase negative‐shifted d‐band center metal sites, boosting UOR stability activity.

Язык: Английский

Процитировано

0
Hydrogen production from water electrolysis coupled with ethanol oxidation by membrane electrolyzer combined flow-through and fed-batch operation DOI
Jiaojiao Chen, Yu Chen,

Ke Bai

и другие.

Fuel, Год журнала: 2025, Номер 397, С. 135380 - 135380

Опубликована: Апрель 17, 2025

Язык: Английский

Процитировано

0
Interfacial lattice strain and electronic transfer induced by lignin-derived carbon coupled with Ni-Mn2Mo3O8 heterojunction for improving industrial-level urea electrolysis DOI
Liancen Li, Lei Ge, Guangfu Qian

и другие.

Applied Catalysis B Environment and Energy, Год журнала: 2025, Номер unknown, С. 125465 - 125465

Опубликована: Май 1, 2025

Язык: Английский

Процитировано

0
Electrochemical Cell Designs for Efficient Carbon Dioxide Reduction and Water Electrolysis: Status and Perspectives DOI Creative Commons
Zhangsen Chen, Lei Zhang, Shuhui Sun

и другие.

Advanced Materials, Год журнала: 2025, Номер unknown

Опубликована: Май 30, 2025

Abstract Integrating renewable electricity and concentrated CO 2 from direct air capture, electrochemical reduction reactions (eCO RR) offer a promising pathway for converting into fuel chemicals, enabling the closure of carbon loop in sustainable manner. The clean H produced via hydrogen evolution reaction (HER) during water electrolysis can replace traditional fossil fuels without additional emissions. Achieving large‐scale high‐efficiency eCO RR HER requires development rational electrolyzer designs, which are crucial industrial implementation. This review examines recent innovations system designs RR, HER, latest advances situ cell operando characterization reactions. It focuses on improvements flow patterns, membrane electrode assemblies, electrolyte engineering to maximize catalytic activities at level. Besides, discusses optimizing counter‐anodic improve energy efficiency electrolysis, offering insights design systems with efficient utilization. Furthermore, it explores integration other (e.g., cells), highlighting their potential role decarbonization future processes. Finally, summary, challenge, outlook industrial‐scale concluded.

Язык: Английский

Процитировано

0