Rational Design of a Bi-Pd Based Intermetallic Alloy as a Promising Electrocatalyst for Oxidation of 5-Hydroxymethylfurfural (HMF) to 2,5-Furandicarboxylic Acid (FDCA) DOI
Dinesh Singh,

Sambhaji S. Ghadge,

Vrushali H. Jadhav

и другие.

ACS Sustainable Resource Management, Год журнала: 2025, Номер unknown

Опубликована: Май 16, 2025

Язык: Английский

Direct Electrosynthesis of an Amino Acid from a Biomass Derivative DOI Creative Commons
Zamaan Mukadam, Sihang Liu, Søren B. Scott

и другие.

ACS electrochemistry., Год журнала: 2025, Номер unknown

Опубликована: Март 14, 2025

The electrochemical synthesis of nitrogen-containing molecules from biomass-derived compounds under ambient conditions is demonstrated, relying only on green sources feedstock, renewable energy, and water. In this study, we report a two-step method electrochemically synthesizing 5-(aminomethyl)furan-2-carboxylic acid (AFCA) 5-hydroxymethylfurfural (HMF) using hydroxylamine (NH2OH) as the nitrogen source in an acidic electrolyte. first step, HMF was reductively aminated into (5-(aminomethyl)furan-2-yl)methanol (HMFA) NH2OH nitrogen. This followed by second involving oxidation HMFA to AFCA manganese oxide (MnOx) anode at same pH. MnOx able selectively oxidize alcohol group produce with 35% Faradaic efficiency without affecting amine group. As both these reactions are completed pH 1 electrolyte, it eliminates need separate before proceeding reaction. Among different metal electrodes (Ag, Au, Cu, Pb, Pt Sn) tested for reductive amination reaction, Ag displayed best performance aminate intermediate species, HMFA, up 69% mild potentials −0.50 VRHE. Density functional theory calculations were carried out explore possible reaction pathway Ag(111), which suggests thermodynamically feasible even 0 cathodic experimental parameters optimized reveal that electrolyte optimal Our work shapes future possibility any product separation between steps combining cathode sharing Since involve four electrons transferred, half single reactor can eliminate energy-wasting auxiliary counter such hydrogen evolution or water oxidation.

Язык: Английский

Процитировано

0
Transformative Strategies for Bimetallic Catalyst Screening in Biomass Conversion Through Active Learning and DFT DOI

Yuan Deng,

Pengxin Pu,

Zhaowei Tian

и другие.

Applied Catalysis B Environment and Energy, Год журнала: 2025, Номер unknown, С. 125267 - 125267

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

0
Aqueous Hydrogenation of Rosin Catalyzed by Amphiphilic Ni–Cu Nanocatalysts DOI
Fengli Yu,

Minghao Bao,

Jiahao Li

и другие.

ACS Applied Nano Materials, Год журнала: 2025, Номер unknown

Опубликована: Апрель 16, 2025

Язык: Английский

Процитировано

0
Effective electrocatalytic xylose oxidation coupling hydrogen production on hierarchical microcolumn NiMoO4 array DOI Creative Commons
Bin Liu, Hai‐Hu Wen,

B.W. DA

и другие.

Applied Catalysis B Environment and Energy, Год журнала: 2025, Номер unknown, С. 125443 - 125443

Опубликована: Май 1, 2025

Язык: Английский

Процитировано

0
Synergistic Catalysis for Recycling and Upcycling of Plastics DOI

Hongshun Ran,

Xinyang Sun, Mengying Zheng

и другие.

ACS Catalysis, Год журнала: 2025, Номер unknown, С. 8551 - 8585

Опубликована: Май 7, 2025

Язык: Английский

Процитировано

0
Rational Design of a Bi-Pd Based Intermetallic Alloy as a Promising Electrocatalyst for Oxidation of 5-Hydroxymethylfurfural (HMF) to 2,5-Furandicarboxylic Acid (FDCA) DOI
Dinesh Singh,

Sambhaji S. Ghadge,

Vrushali H. Jadhav

и другие.

ACS Sustainable Resource Management, Год журнала: 2025, Номер unknown

Опубликована: Май 16, 2025

Язык: Английский

Процитировано

0