Zinc-ion batteries: Drawbacks, opportunities, and optimization performance for sustainable energy storage
Mohammed Jameel Alawi,
Hadeer Gamal,
M. Rashad
и другие.
Journal of Alloys and Compounds,
Год журнала:
2025,
Номер
1012, С. 178455 - 178455
Опубликована: Янв. 1, 2025
Язык: Английский
Electronic-ionic dual-conductive framework/channel stabilized Zn anodes for high-performance aqueous Zn-ion batteries
Chemical Engineering Journal,
Год журнала:
2025,
Номер
unknown, С. 161884 - 161884
Опубликована: Март 1, 2025
Язык: Английский
Mitigating crosstalk through water deactivation to achieve advanced Zn-ion batteries with superior temperature adaptability
Journal of Colloid and Interface Science,
Год журнала:
2025,
Номер
693, С. 137591 - 137591
Опубликована: Апрель 12, 2025
Язык: Английский
Weak Dipole Effect Customized Zinc Ion‐Rich Protective Layer for Lean‐Electrolyte Zinc Metal Batteries
Advanced Materials,
Год журнала:
2025,
Номер
unknown
Опубликована: Апрель 25, 2025
Abstract
The
industrial
development
of
Zn‐ion
batteries
requires
high
performance
even
with
lean‐electrolyte.
Nevertheless,
lean‐electrolyte
can
exacerbate
concentration
polarization
at
the
interface
electrode/electrolyte,
leading
to
significant
Zn
corrosion
and
battery
failure.
Here,
a
stable
ion‐rich
protective
layer
(TMAO‐Zn)
is
constructed
by
unique
zwitterion
structure
trimethylamine
N‐oxide
(TMAO).
TMAO
characterized
direct
connection
between
positive
negative
charges
(N
+
‐O
−
)
minimal
dipole
moment,
which
renders
weak
interactions
form
TMAO‐Zn
2+
,
thereby
reducing
promoting
rapid
uniform
deposition
.
Furthermore,
O
exhibits
higher
electrophilic
index,
indicating
stronger
propensity
for
hydrogen
bond
active
free
water
in
inner
Helmholtz
(IHL),
mitigating
under
extreme
conditions
low
electrolyte‐to‐capacity
ratio
(E/C
ratio).
Consequently,
symmetrical
enables
cycling
over
250
h
15
µL
mA
−1
Additionally,
Zn/I₂
pouch
E/C
21.2
provides
ultra‐high
specific
capacity
96
cycles
(capacity
retention
rate
98.3%).
This
study
offers
new
concept
propel
practical
application
Язык: Английский
Nanoreactor‐Driven Uniform Nano ZnS Deposition in Tunable Porous Carbon Spheres for High‐Performance Zn‐S Batteries
Advanced Science,
Год журнала:
2025,
Номер
unknown
Опубликована: Май 8, 2025
Abstract
Zn‐S
batteries
have
garnered
widespread
attention
in
recent
years
due
to
their
higher
safety
and
low
cost.
However,
challenges
such
as
incomplete
sulfur
redox
reactions
the
tendency
of
ZnS
agglomerate
impeded
continued
advancement
high‐performance
batteries.
Hollow
hierarchical
porous
carbon
spheres
(HCs)
are
designed
efficient
hosts
for
The
tailored
HCs,
featuring
optimized
shell
thickness,
porosity,
facilitate
uniform
nano‐ZnS
deposition,
improve
ion/electron
transport,
which
revealed
by
situ
impedance
technology.
This
nano
reactor
design
ensures
highly
reversible
S‐ZnS
conversion,
reducing
internal
polarization
mitigating
structural
degradation.
Electrochemical
tests
demonstrate
outstanding
cycling
stability,
with
minimal
capacity
decay
(0.068%)
over
500
cycles,
463
mAh
g
−1
at
5
A
.
Finite
element
simulations
further
confirm
effective
stress
dispersion
preserving
electrode
integrity.
work
provides
a
promising
strategy
developing
Язык: Английский
Spin State Modulation via Magnetic Fields in Fe Single Atom Catalysts for High-Performance Aqueous Zinc–Sulfur Batteries
ACS Nano,
Год журнала:
2025,
Номер
unknown
Опубликована: Май 29, 2025
Aqueous
zinc-sulfur
battery
has
garnered
significant
attention
as
a
high-energy,
low-cost,
and
safe
energy
storage
system.
However,
the
multielectron
transfer
kinetics
of
sulfur
cathodes
are
relatively
slow,
presenting
challenges
such
limited
utilization
lower
discharge
voltage,
which
significantly
hinder
their
practical
applications.
In
this
study,
we
explored
comprehensive
design
approach
for
high-performance,
long-cycle
aqueous
batteries.
The
simultaneous
introduction
ZnI2
Fe
single
atoms
(Fe-SAs)
catalytically
active
agents
decouples
redox
reactions,
effectively
facilitating
ZnS
oxidation
S
reduction
separately.
application
an
external
magnetic
field
regulates
spin
state
Fe-SAs,
further
enhancing
catalytic
activity
electron
capability.
Electrochemical
tests
demonstrate
that
S@Fe-NC
HS/ZnI2
cathode
assembled
under
exhibits
excellent
rate
performance,
achieving
impressive
specific
capacity
1399
mAh
g-1
at
high
current
density
5
A
good
cycling
stability
over
300
cycles,
representing
highest
reported
high-current
to
date.
This
study
provides
framework
optimizing
(Zn-S)
performance
elucidates
influence
field-induced
modulation
on
behavior.
Язык: Английский
Aqueous Zinc‐Sulfur Batteries: From Challenges to Strategies
Advanced Materials,
Год журнала:
2025,
Номер
unknown
Опубликована: Июнь 1, 2025
Abstract
Aqueous
Zn‐S
batteries
(AZSBs),
including
conventional
and
decoupled
AZSBs,
are
suitable
options
for
advanced
electrochemical
energy
storage
systems.
They
cost‐effective
with
safety,
high
theoretical
capacity,
power
density.
Nevertheless,
many
inherent
hurdles
need
to
be
overcome
make
AZSBs
practically
feasible,
irreversible
transformation
of
the
sulfur
cathode,
instability
Zn
anode,
incompatibility
electrolyte.
This
review
presents
a
comprehensive
evaluation
emphasizing
configurations
electrode
reactions,
challenges,
strategies,
prospects
future.
First,
electrochemistry
behavior
is
reviewed,
encompassing
both
battery
configurations,
along
their
respective
reactions.
Second,
various
sources,
hosts,
additives
identified
that
can
effectively
enhance
reversibility
cathode.
Third,
approaches
constructing
solid
electrolyte
interphase
on
anode
facilitating
alloying
discussed
as
key
strategies
protection.
Fourth,
selection
zinc
salts
employment
organic
co‐solvents
explored
regulate
electrolytes.
Finally,
thoughts
future
research
development
in
presented
build
better
aqueous
batteries.
Язык: Английский