Exploring the Differences in Self‐Assembly Behavior, Structure, and Properties of Two Novel Pentanuclear Zinc (II) Salamo‐Type Complexes Possessing Solvent Effect DOI Open Access

Yingru Zheng,

Na Tuo,

Haiwei Zhang

и другие.

Applied Organometallic Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 18, 2024

ABSTRACT A salamo‐type biscompartmental ligand was successfully prepared. On this basis, two novel pentanuclear zinc (II) complexes possessing solvent effect were self‐assembled with different salts: [Zn 5 (L) 2 ( μ ‐OAc) (CH 3 COCH )] 1 ) and CN)] ). Complex contains fully deprotonated 4− units, five Zn(II) atoms, coordinating acetate anions, one acetone molecule. The atoms are all in a slightly distorted triangular bipyramidal geometrical configurations. consists of anions acetonitrile structures the self‐assembling may be attributed to various effects applied self‐assembly. As result, involved bridging coordination, thereby expanding distance between secondary building units (SBUs). In addition, polar nonprotonic solvents, especially molecules, coordination process. Finally, reaction sites intermolecular interactions further discussed by MEP, IRI, Hirshfeld surfaces, their fluorescence properties explored.

Язык: Английский

Zn (II) Complexes Synthesized With Salamo‐Type Ligand as a Highly Efficient Sensor to Detect MnO4− in Aqueous Solution DOI

Na Tuo,

Lele Liu, Jun Ren

и другие.

Applied Organometallic Chemistry, Год журнала: 2025, Номер 39(5)

Опубликована: Апрель 1, 2025

ABSTRACT Herein, Three Salamo‐type Zn (II) complexes [Zn 2 (L)( μ ‐OAc)]·CH 3 OH ( 1 ), 4 (L) ]Cl ](NO ) is synthesized as the fluorescence probe for ultrasensitive detection of MnO − in aqueous solution. The structure analysis shows that complex a binuclear structure, while and symmetric tetranuclear structure. exhibited high stability intensity solvent. limit 8.8, 12.8 13.8 μM. anions involved coordination undergo structural changes due to their different modes compared with , resulting better performance than other two complexes. have good selectivity applicability determination solutions. At same time, sensing effect real water samples was also detected. In addition, recognition mechanisms three above analytes were explored detail.

Язык: Английский

Процитировано

0
Exploring the Differences in Self‐Assembly Behavior, Structure, and Properties of Two Novel Pentanuclear Zinc (II) Salamo‐Type Complexes Possessing Solvent Effect DOI Open Access

Yingru Zheng,

Na Tuo,

Haiwei Zhang

и другие.

Applied Organometallic Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 18, 2024

ABSTRACT A salamo‐type biscompartmental ligand was successfully prepared. On this basis, two novel pentanuclear zinc (II) complexes possessing solvent effect were self‐assembled with different salts: [Zn 5 (L) 2 ( μ ‐OAc) (CH 3 COCH )] 1 ) and CN)] ). Complex contains fully deprotonated 4− units, five Zn(II) atoms, coordinating acetate anions, one acetone molecule. The atoms are all in a slightly distorted triangular bipyramidal geometrical configurations. consists of anions acetonitrile structures the self‐assembling may be attributed to various effects applied self‐assembly. As result, involved bridging coordination, thereby expanding distance between secondary building units (SBUs). In addition, polar nonprotonic solvents, especially molecules, coordination process. Finally, reaction sites intermolecular interactions further discussed by MEP, IRI, Hirshfeld surfaces, their fluorescence properties explored.

Язык: Английский

Процитировано

2