Modeling the Liquid-Phase Adsorption of Cephalexin onto Coated Iron Nanoparticles Using Response Surface and Molecular Modeling DOI Creative Commons
Shahin Ahmadi, Soumya Ghosh, Alhadji Malloum

и другие.

Adsorption Science & Technology, Год журнала: 2022, Номер 2022

Опубликована: Янв. 1, 2022

In order to assess the interactions between process factors, experiments involving liquid-phase adsorption of cephalexin (CEX) onto silicon-coated iron nanoparticles (Fe 3 O 4 @SIO 2 ) were designed using Box-Behnken Design-Response surface methodology (BBD-RSM). Optimal circumstances used investigate synergistic influence on process’s efficiency. addition, data was test and fit an artificial neural network (ANN) model. Molecular-level DFT calculations CEX molecule carried out. The PW6B95D3/Def2-TZVP level theory build DFT-based descriptors for molecule. At 25°C, pH 5.83, 37.67 min, a dosage 0.8 g Fe 118.01 mg/L CEX, removal efficiency achieved maximum 99.01 percent. For example, we found that OH --- O, NH CH hydrogen bonds, π, π as well dipole-dipole could all be connect nanoparticles. There is strong correlation output target values acquired by BBD-RSM ANN fits. proved excellent tool eliminating CEX.

Язык: Английский

Recent advances in hydrochar application for the adsorptive removal of wastewater pollutants DOI
Joshua O. Ighalo,

Rangabhashiyam Selvasembian,

Kanika Dulta

и другие.

Process Safety and Environmental Protection, Год журнала: 2022, Номер 184, С. 419 - 456

Опубликована: Июнь 20, 2022

Язык: Английский

Процитировано

122

A review of emerging micro-pollutants in hospital wastewater: Environmental fate and remediation options DOI Creative Commons
Oluwaseun J. Ajala, Jimoh Oladejo Tijani,

Rasaq Bolakale Salau

и другие.

Results in Engineering, Год журнала: 2022, Номер 16, С. 100671 - 100671

Опубликована: Сен. 28, 2022

Hospitals played vital role in the maintenance and sustenance of human health. However, hospital activities generate high volume toxic solid liquid containing diverse inorganic, organic microbial wastes released untreated into ecosystem. The management wastewater particular has been a major source concern due to presence unregulated emerging micro-pollutants at concentrations range ng/L μg/L. These pollutants low concentration exert different potential health effects on aquatic species. In this review, formation, composition, properties ecotoxicology selected (Norfloxacin, Ofloxacin, Ciprofloxacin, Clofibric acid Carbamazepine) were reviewed. review also elucidates detection quantification micropollutants by Spectrophotometry techniques, Gas Chromatography, Ion Chromatography-Mass spectrometry, High-Performance Liquid Chromatography. Furthermore, treatment through physical, biological, chemical, adsorption advanced oxidation processes such as photocatalysis photo-Fenton including their operational mechanism provided. chemistry degradation several intermediates It was found that conventional methods are not designed for effective removal these because they exist mixtures very exerts toxicological effects. reveals no single technology can effectively detoxify wastewater, instead combination (phototcatalytic/adsorption or photo-fenton/adsorption) most appropriate treatment. Finally, regular monitoring determination physicochemical ecotoxicological parameters recommended.

Язык: Английский

Процитировано

103

A critical review on graphene oxide nanostructured material: Properties, Synthesis, characterization and application in water and wastewater treatment DOI
Oluwaseun J. Ajala, Jimoh Oladejo Tijani, M.T. Bankole

и другие.

Environmental Nanotechnology Monitoring & Management, Год журнала: 2022, Номер 18, С. 100673 - 100673

Опубликована: Март 4, 2022

Язык: Английский

Процитировано

70

Biomass Hydrochar: A Critical Review of Process Chemistry, Synthesis Methodology, and Applications DOI Open Access
Joshua O. Ighalo,

Florence Chidinma Akaeme,

Jordana Georgin

и другие.

Sustainability, Год журнала: 2025, Номер 17(4), С. 1660 - 1660

Опубликована: Фев. 17, 2025

Hydrothermal carbonization (HTC) is a novel thermochemical process that turns biomass into hydrochar, substance rich in carbon has potential uses advanced material synthesis, energy production, and environmental remediation. With an emphasis on important chemical pathways, such as dehydration, decarboxylation, polymerization, control the conversion of lignocellulosic useful this review critically investigates fundamental chemistry HTC. A detailed analysis conducted effects variables physicochemical characteristics including temperature, pressure, composition, water ratio, residence time. Particular focus placed new developments HTC technology improve sustainability efficiency, like recirculating microwave-assisted co-hydrothermal carbonization. Furthermore, improvement adsorption capacity for organic contaminants heavy metals explored relation to functionalization activation namely through surface modification KOH treatment. The performance hydrochar biochar adsorption, catalysis, storage compared, emphasizing unique benefits difficulties each substance. Although comparatively high higher heating value (HHV) can be good substitute coal, issues with reactor design, scalability, secondary waste management continue limit its widespread use. In order maximize sustainable profitable avenue valorization, study addresses critical research gaps future initiatives.

Язык: Английский

Процитировано

2

Valorization of microwave-assisted H3PO4-activated plantain (Musa paradisiacal L) leaf biochar for malachite green sequestration: models and mechanism of adsorption DOI Creative Commons
Jamiu Mosebolatan Jabar, Matthew A. Adebayo, Yisau Adelaja Odusote

и другие.

Results in Engineering, Год журнала: 2023, Номер 18, С. 101129 - 101129

Опубликована: Апрель 28, 2023

Язык: Английский

Процитировано

38

Microbes as Resources to Remove PPCPs and Improve Water Quality DOI Creative Commons

Francesca Demaria,

Marcel Suleiman, Philippe F.-X. Corvini

и другие.

Microbial Biotechnology, Год журнала: 2025, Номер 18(1)

Опубликована: Янв. 1, 2025

ABSTRACT The inadequate removal of pharmaceuticals and personal care products (PPCPs) by traditional wastewater treatment plants (WWTPs) poses a significant environmental public health challenge. Residual PPCPs find their way into aquatic ecosystems, leading to bioaccumulation in biota, the dissemination antibiotic resistance genes (ARGs), contamination both water sources vegetables. These persistent pollutants can have negative effects on human health, ranging from development endocrine disruption. To mitigate these risks, there is growing interest exploiting microorganisms enzymes for bioremediation purposes. By harnessing metabolic capabilities microbial communities, be efficiently degraded, transformed, or sequestered systems. Additionally, communities exhibit remarkable adaptability resilience diverse PPCP contaminants, further underscoring potential as sustainable cost‐effective solutions treatment. This review explores promise an approach addressing complex challenges posed contamination, emphasising its safeguard integrity well‐being.

Язык: Английский

Процитировано

1

Utilisation of adsorption as a resource recovery technique for lithium in geothermal water DOI
Joshua O. Ighalo, James F. Amaku, Chijioke Olisah

и другие.

Journal of Molecular Liquids, Год журнала: 2022, Номер 365, С. 120107 - 120107

Опубликована: Авг. 17, 2022

Язык: Английский

Процитировано

33

Microbial degradation and transformation of PPCPs in aquatic environment: A review DOI Creative Commons
Mathiyazhagan Narayanan, Sabariswaran Kandasamy, Jintae Lee

и другие.

Heliyon, Год журнала: 2023, Номер 9(8), С. e18426 - e18426

Опубликована: Июль 19, 2023

The Pharmaceuticals and Personal Care Products (PPCPs) presence at harmful levels has been identified in aquatic ecosystems all over the world. Currently, PPCPs are more common regions have discovered to be extremely creatures. Waste-water treatment facilities primary cause of pollution systems due their limited as well following release PPCPs. degree elimination is primarily determined by method applied for remediation. It must addressed an eco-friendly manner order significantly improve environmental quality or, very least, prevent spread effects toxic pollutants. However, when compared other methods, environmentally friendly strategies (biological methods) less expensive require energy. Most biological methods under aerobic conditions shown degrade effectively. Furthermore, scientific literature indicates that with exception a few hydrophobic substances, degradation microbes process majority compounds. Hence, this review discusses about optimistic role microbe concerned or transformation into non/less form polluted environment. Accordingly, number microbial strains implicated biodegradation/transformation through termed bioremediation limitations.

Язык: Английский

Процитировано

17

Ipoma batatas (sweet potato) leaf and leaf-based biochar as potential adsorbents for procion orange MX-2R removal from aqueous solution DOI
Jamiu Mosebolatan Jabar, Matthew A. Adebayo,

Tella Adewale Akanni Taleat

и другие.

Journal of Analytical and Applied Pyrolysis, Год журнала: 2024, Номер unknown, С. 106876 - 106876

Опубликована: Ноя. 1, 2024

Язык: Английский

Процитировано

6

Aqueous phase adsorption of aromatic organoarsenic compounds: A review DOI
Kingsley O. Iwuozor,

Kovo G. Akpomie,

Jeanet Conradie

и другие.

Journal of Water Process Engineering, Год журнала: 2022, Номер 49, С. 103059 - 103059

Опубликована: Авг. 13, 2022

Язык: Английский

Процитировано

28