Abstract
The
development
of
catalysts
that
are
optically
transparent,
electrically
charge‐transferable,
and
capable
protecting
underlying
photoactive
semiconductors
is
crucial
for
efficient
photoelectrochemical
(PEC)
hydrogen
production.
However,
meeting
all
these
requirements
simultaneously
poses
significant
challenges.
In
this
study,
the
fabrication
a
wafer‐scale
transparent
bilayer
MoS
2
/WS
catalyst
presented
with
staggered
heterojunction,
optimized
photon
absorption,
extraction
photogenerated
charge
carriers,
surface
passivation
p
‐Si
photocathode.
WS
monolayers
grown
via
metal‐organic
chemical
vapor
deposition,
followed
by
sequential
transfer
stacking
onto
resulting
type‐II
heterojunction
film
establishes
strong
built‐in
electric
field
rapid
carrier
transport
effectively
protects
Si
from
oxidation
corrosion.
fabricated
/p‐Si
photocathode
demonstrates
outstanding
PEC
performance,
achieving
high
photocurrent
density
−25
mA
cm
−2
at
0
V
versus
reversible
electrode,
along
enhanced
stability
compared
to
monolayer
/p‐Si.
This
work
provides
promising
strategies
developing
active,
protective
practical
energy
conversion
systems.
ACS Catalysis,
Год журнала:
2024,
Номер
14(9), С. 6603 - 6622
Опубликована: Апрель 16, 2024
Photoelectrochemical
water
splitting
and
CO2
reduction
provide
an
attractive
route
to
produce
solar
fuels
while
reducing
the
level
of
emissions.
Metal
halide
perovskites
(MHPs)
have
been
extensively
studied
for
this
purpose
in
recent
years
due
their
suitable
optoelectronic
properties.
In
review,
we
survey
achievements
field.
After
a
brief
introduction
photoelectrochemical
(PEC)
processes,
discussed
properties,
synthesis,
application
MHPs
context.
We
also
state-of-the-art
findings
regarding
significant
performance,
developments
addressing
major
challenges
toxicity
instability
toward
water.
Efforts
made
replace
toxic
Pb
with
less
materials
like
Sn,
Ge,
Sb,
Bi.
The
stability
has
improved
by
using
various
methods
such
as
compositional
engineering,
2D/3D
perovskite
structures,
surface
passivation,
use
protective
layers,
encapsulation.
last
part,
considering
experience
gained
photovoltaic
applications,
provided
our
perspective
future
opportunities.
place
special
emphasis
on
improvement
challenge
potential
contribution
machine
learning
identify
most
formulation
desired
ACS Materials Letters,
Год журнала:
2024,
Номер
6(7), С. 2757 - 2786
Опубликована: Июнь 5, 2024
As
the
demand
for
sustainable
energy
sources
increases,
water
electrolysis
has
attracted
huge
attention
in
research
fields
due
to
its
cleanliness
and
high
purity
of
hydrogen
generation.
Electrolysis
technology
involves
splitting
molecules
into
oxygen
using
electricity.
The
combined
with
renewable
electricity
makes
it
a
key
method
producing
sustainably.
Herein,
we
present
comprehe1nsive
review
systems
efficient
production.
First,
representative
components
membrane
electrode
assembly
(MEA)
investigations
respect
configurations
MEAs,
which
are
categorized
as
catalyst-coated
substrates
(CCSs)
membranes
(CCMs),
will
be
discussed.
Then,
introduce
state-of-the-art
practices
on
electrolyzers
classified
alkaline
(AWEs),
proton
exchange
(PEMWEs),
anion
(AEMWEs).
Finally,
critical
outlooks
realize
full
potential
highlighted.
Molecules,
Год журнала:
2025,
Номер
30(3), С. 630 - 630
Опубликована: Янв. 31, 2025
As
an
energy
carrier
characterized
by
its
high
density
and
eco-friendliness,
hydrogen
holds
a
pivotal
position
in
transition.
This
paper
elaborates
on
the
scientific
foundations
recent
progress
of
photo-
electro-catalytic
water
splitting,
including
corresponding
mechanism,
material
design
optimization,
economy
production.
It
systematically
reviews
research
photo(electro)catalytic
materials,
oxides,
sulfides,
nitrides,
noble
metals,
non-noble
metal,
some
novel
photocatalysts
provides
in-depth
analysis
strategies
for
optimizing
these
materials
through
design,
component
adjustment,
surface
modification.
In
particular,
it
is
pointed
out
that
nanostructure
regulation,
dimensional
engineering,
defect
introduction,
doping,
alloying,
functionalization
can
remarkably
improve
catalyst
performance.
The
importance
adjusting
reaction
conditions,
such
as
pH
addition
sacrificial
agents,
to
boost
catalytic
efficiency
also
discussed,
along
with
comparison
cost-effectiveness
different
production
technologies.
Despite
significant
advancements
made
splitting
technology,
this
highlights
challenges
faced
field,
development
more
efficient
stable
photo(electro)catalysts,
improvement
system
conversion
efficiency,
cost
reduction,
promotion
technology
industrialization,
addressing
environmental
issues.
ACS Materials Letters,
Год журнала:
2024,
Номер
6(9), С. 4066 - 4089
Опубликована: Авг. 6, 2024
With
the
escalating
demand
for
clean
and
sustainable
energy
sources,
hydrogen
emerges
as
a
paramount
contender,
necessitating
efficient
innovative
production
methods
of
water
splitting.
This
review
ventures
into
burgeoning
field
yolk@shell
nanostructures
their
pivotal
role
in
advancing
splitting
technologies.
The
synthesis,
unique
properties,
multifaceted
applications
across
electrocatalytic
(EC),
photocatalytic
(PC),
photoelectrocatalytic
(PEC)
processes
are
evaluated.
We
start
with
brief
introduction
to
various
synthetic
strategies,
including
template-assisted
formation,
Kirkendall
effect,
galvanic
replacement,
Ostwald
ripening,
each
contributing
tailored
construction
enhanced
catalytic
efficiencies.
Highlights
put
on
significant
advancements
utilizing
these
optimize
EC
activities,
PC
rates,
PEC
efficiency.
Furthermore,
we
address
challenges
integrating
generation
valuable
compound
production,
near-infrared
photoactivity,
seawater
splitting,
underscoring
necessity
innovation
potential
diversifying
conversion
systems.
Through
comprehensive
analysis,
this
not
only
showcases
current
developments
but
also
outlines
prospects,
emphasizing
critical
importance
landscape.
Nature Communications,
Год журнала:
2025,
Номер
16(1)
Опубликована: Июнь 2, 2025
Photoelectrochemical
(PEC)
synthesis
offers
a
sustainable
route
for
fine
chemicals
production,
yet
comprehending
and
modulating
the
reaction
processes
at
atomic
level
remains
challenge.
Herein,
we
develop
single-atom
Ir
decorated
Ti-doped
α-Fe2O3
photoanode
selective
PEC
of
adipic
acid
from
cyclohexanone
using
water
as
oxygen
source.
The
system
achieves
6.0
μmol
cm-2
h-1
production
with
~60%
Faradaic
efficiency
~88%
selectivity.
promotes
photogenerated
carrier
separation
transfer,
while
regulating
electronic
structure
to
optimize
its
adsorption
strength
OH-
cyclohexanone.
Mechanistic
studies
reveal
non-free-radical
pathway
level,
driven
by
holes
through
an
adsorbed
hydroxyl
transfer.
Notably,
integrating
amorphous
silicon-based
photocathode
leads
bias-free
device
that
enables
stable
over
80
hours,
underscoring
potential
light-driven
synthesis.
