Tungsten-Catalyzed Stereodivergent Isomerization of Terminal Olefins DOI Creative Commons
Tanner C. Jankins, Camille Rubel, Hang Chi Ho

и другие.

Chemical Science, Год журнала: 2024, Номер unknown

Опубликована: Дек. 4, 2024

A stereodivergent, W-catalyzed alkene isomerization is reported, leading to either E - or Z -β,γ-unsaturated carbonyl compounds based on the ligand environment around metal.

Язык: Английский

(Z)-Selective Isomerization of 1,1-Disubstituted Alkenes by Scandium-Catalyzed Allylic C–H Activation DOI
Shao‐Jie Lou, Pan Wang, Xin Wen

и другие.

Journal of the American Chemical Society, Год журнала: 2024, Номер 146(39), С. 26766 - 26776

Опубликована: Сен. 20, 2024

The isomerization of 1,1-disubstituted alkenes through 1,3-hydrogen shift is an atom-efficient route for synthesizing trisubstituted alkenes, which are important moieties in many natural products, pharmaceuticals, and organic materials. However, this reaction often encounters regio- stereoselectivity challenges, typically yielding

Язык: Английский

Процитировано

8
Tungsten-catalyzed stereoselective isomerization of N‑allyl amides to access enamides with geometrically selectivity DOI

Yanduo Chen,

Haifei Yang,

Juanjuan Zhang

и другие.

Journal of Catalysis, Год журнала: 2025, Номер unknown, С. 115976 - 115976

Опубликована: Янв. 1, 2025

Язык: Английский

Процитировано

0
Tungsten-Catalyzed Stereodivergent Isomerization of Terminal Olefins DOI Creative Commons
Tanner C. Jankins, Camille Rubel, Hang Chi Ho

и другие.

Chemical Science, Год журнала: 2024, Номер unknown

Опубликована: Дек. 4, 2024

A stereodivergent, W-catalyzed alkene isomerization is reported, leading to either E - or Z -β,γ-unsaturated carbonyl compounds based on the ligand environment around metal.

Язык: Английский

Процитировано

0