Recent advances in hydrofunctionalisation of cyclopropenes via carbon–heteroatom bond formation

Organic Chemistry Frontiers, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

This review highlights recent advances in the hydrofunctionalisation of cyclopropenes through formation carbon–heteroatom bonds for synthesis polysubstituted cyclopropanes.

Язык: Английский

C−P Bond Formation by Nickel or Cobalt Catalyzed Coupling Reactions

Chemistry - An Asian Journal, Год журнала: 2025, Номер unknown

Опубликована: Март 12, 2025

Abstract This review discloses nickel‐ and cobalt‐catalyzed coupling reactions that allow C−P bond formation. Activation of C−halide bonds to form phosphonium, pentavalent phosphorus, or trivalent phosphorous compounds has been reported with both metals. However, the conversion C−O ((activated) ethers, carbonates, acetates) into ones only described Ni. Similarly, there are more examples C−Y (Y=C, S, N, B) activations catalyzed by Ni than Co. Nevertheless, cross‐dehydrogenative reaction between a P−H reagent C−H often cobalt nickel. In addition, for metals, electrolytic photocatalytic processes have shown produce variety containing molecules. aims provide an overview potential metals formation highlight remaining challenges.

Язык: Английский

Transition metal-catalyzed P(O)-H alkenylation, allenylation and alkynylation reactions: a recent trend

Tetrahedron, Год журнала: 2024, Номер unknown, С. 134388 - 134388

Опубликована: Ноя. 1, 2024

Язык: Английский