Chemical Science, Год журнала: 2024, Номер 15(27), С. 10281 - 10307
Опубликована: Янв. 1, 2024
Delving into the tools empowering polymer chemists to design polymers for roles as solid electrolytes, multifunctional binders and active electrode materials in cutting-edge solid-state batteries wearable devices.
Язык: Английский
Energy storage materials, Год журнала: 2023, Номер 64, С. 103088 - 103088
Опубликована: Ноя. 25, 2023
Язык: Английский
Процитировано
32
Advanced Science, Год журнала: 2024, Номер 11(31)
Опубликована: Июнь 18, 2024
Abstract Raising the charging voltage and employing high‐capacity cathodes like lithium cobalt oxide (LCO) are efficient strategies to expand battery capacity. High voltage, however, will reveal major issues such as electrolyte's low interface stability weak electrochemical stability. Designing high‐performance solid electrolytes from standpoint of substance genetic engineering design is consequently vital. In this instance, stable SEI CEI layers constructed, a 4.7 V high‐voltage copolymer electrolyte (PAFP) with fluoro‐cyanogen group generated by polymer molecular engineering. As result, PAFP has an exceptionally broad window (5.5 V), high Li + transference number (0.71), ultrahigh ionic conductivity (1.2 mS cm −2 ) at 25 °C. Furthermore, Li||Li symmetric cell possesses excellent 2000 cycles 1 mA . The LCO|PAFP|Li batteries have 73.7% retention capacity after 1200 cycles. Moreover, it still cycling V. These characteristics above also allow run stably loading, showing proposed provides new insights into resistant electrolytes.
Язык: Английский
Процитировано
16
Nano-Micro Letters, Год журнала: 2024, Номер 16(1)
Опубликована: Фев. 19, 2024
The pursuit of safer and high-performance lithium-ion batteries (LIBs) has triggered extensive research activities on solid-state batteries, while challenges related to the unstable electrode-electrolyte interface hinder their practical implementation. Polymer been used extensively improve cathode-electrolyte in garnet-based all-solid-state LIBs (ASSLBs), it introduces new concerns about thermal stability. In this study, we propose incorporation a multi-functional flame-retardant triphenyl phosphate additive into poly(ethylene oxide), acting as thin buffer layer between LiNi
Язык: Английский
Процитировано
14
Journal of Energy Storage, Год журнала: 2024, Номер 90, С. 111919 - 111919
Опубликована: Май 4, 2024
The search for sustainable and high-performance materials lithium-ion batteries is leading to significant advances in solid polymer electrolyte (SPE) technology. However, the current drawbacks of this approach prove need further research development field. Herein, novel ternary electrolytes have been developed using varying loads MOF-808 metal-organic framework [BMIM][SCN] ionic liquid (IL) incorporated a poly(vinylidene fluoride-co-hexafluoropropylene) matrix. were evaluated at morphological, structural, thermal, mechanical electrochemical levels, their performance cycling battery testing was assessed. results showed homogeneous structure throughout all samples good dispersion distinct components. polar phase degree crystallinity are increased with increasing IL content, thermal properties appropriate application. conductivity reaches maximum values 4.68 × 10−5 S‧cm−1 room temperature, lithium transference numbers up 0.65, high stability, making them well-suited applications. assembled stability after 50 cycles C/10 discharge capacity value 150 mAh‧g−1 temperature tested/derived. obtained show potential system electrolytes.
Язык: Английский
Процитировано
11
Chemical Science, Год журнала: 2024, Номер 15(27), С. 10281 - 10307
Опубликована: Янв. 1, 2024
Delving into the tools empowering polymer chemists to design polymers for roles as solid electrolytes, multifunctional binders and active electrode materials in cutting-edge solid-state batteries wearable devices.
Язык: Английский
Процитировано
11