Organic Chemistry Frontiers,
Год журнала:
2024,
Номер
unknown
Опубликована: Дек. 5, 2024
A
TBADT-photocatalyzed
cascade
hydrogen
atom
transfer
procedure
was
established
for
the
synthesis
of
α-CF
3
-1,4-diketones
from
aldehydes
and
2-bromo-3,3,3-trifluoro-1-propenes.
Journal of the Chinese Chemical Society,
Год журнала:
2025,
Номер
unknown
Опубликована: Март 26, 2025
Abstract
WO
3
has
successfully
been
deposited
on
indium
tin
oxide
(ITO)
substrate
via
physical
vapor
deposition
(PVD)
technique,
and
X‐rays
diffraction
(XRD)
confirmed
the
of
a
thin
layer
that
is
orthorhombic.
The
XRD
linear
sweep
voltammetry
(LSV)
study
film
type
semiconductor
observed
it
to
be
an
n‐type
semiconductor.
scanning
electron
microscopy
(SEM)
revealed
uniform
porous
morphology
film,
particle
size
was
measured
34
nm
without
annealing.
Fourier
transform
infrared
(FTIR)
functional
group
vibration
(stretching,
compression)
broad
band
stretching
monoclinic
in
range
3200–3500
cm
−1
.
W‐O‐W
peak
noted
400–500
,
while
W‐O
recorded
700–900
furthermore,
minor
peaks
were
also
1400–1700
UV
spectroscopy
provided
absorbance
solar
spectrum
visible
beyond
400‐nm
wavelength.
maximum
(320
nm)
gradually
decreases
with
percentage
transmittance
at
wavelength
500‐nm
range,
which
88.67%.
gap
Tauc
plot
3.26
eV.
Electrochemical
impedance
(EIS)
small
curve
evidence
low
large
photocurrent.
photocurrent
from
LSV
measurement
0.51%
0.8
V,
quite
good
for
water‐splitting
applications.
hydrogen
generation
through
photoelectrochemical
(PEC)
water
splitting
found
have
average
rate
1743.09
mol
g
6
h.
Chinese Journal of Chemistry,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 16, 2025
Comprehensive
Summary
The
N–H
methylsulfoxidation
of
sulfoximines
using
DMSO
as
a
methylsulfinyl
source,
induced
by
electrochemistry,
has
been
developed.
This
method
is
the
first
example
an
electrochemical
reaction
in
which
serves
source.
Unlike
previous
reactions
involving
substrate,
exclusively
proceed
via
radical
mechanisms,
this
follows
S‐cation
pathway.
A
wide
range
N
‐methylsulfinyl
were
successfully
obtained.
Organic Letters,
Год журнала:
2025,
Номер
27(10), С. 2492 - 2497
Опубликована: Март 5, 2025
A
controlled
cleavage
of
double
C-F
bonds
in
sterically
hindered
tetrasubstituted
CF3-alkenes
using
formate
salt
has
been
achieved
through
a
photoinduced
electron
transfer
approach.
Diverse
γ-branched
multifunctionalized
gem-difluoroalkenes
and
α-fluoroacrylic
acids
are
obtained
sequentially
via
hydrodefluorination
bond
carboxylation
with
good-to-high
yields.
Precisely
controlling
the
quantity
reaction
time
is
crucial
for
obtaining
divergent
defluorinative
products.
Formate
serves
as
C1
source,
hydrogen
donor,
reducing
agent.