Synthesis of 2‐Pyrones by Base‐Induced [3+3] Annulation Reaction of Phenacyl Phosphonium Ylides with Cyclopropenones DOI
Yuanyuan Zhang, Xiaoyu Wang, Jiangwei Wen

и другие.

Asian Journal of Organic Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Окт. 18, 2024

Abstract The base‐induced [3+3] annulation reaction of phenacyl phosphonium ylides with cyclopropenones has been proposed. Various polysubstituted 2‐pyrones are achieved in moderate to good yields through C−P bond cleavage and C−O/C−C coupling under simple easy‐to‐operate conditions. synthetic application mechanism have also preliminarily explored gain a deeper understanding this strategy practicality details. This protocol offers an alternative approach for the synthesis useful 2‐pyrone derivatives.

Язык: Английский

Synthesis of 2‐Pyrones by Base‐Induced [3+3] Annulation Reaction of Phenacyl Phosphonium Ylides with Cyclopropenones DOI
Yuanyuan Zhang, Xiaoyu Wang, Jiangwei Wen

и другие.

Asian Journal of Organic Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Окт. 18, 2024

Abstract The base‐induced [3+3] annulation reaction of phenacyl phosphonium ylides with cyclopropenones has been proposed. Various polysubstituted 2‐pyrones are achieved in moderate to good yields through C−P bond cleavage and C−O/C−C coupling under simple easy‐to‐operate conditions. synthetic application mechanism have also preliminarily explored gain a deeper understanding this strategy practicality details. This protocol offers an alternative approach for the synthesis useful 2‐pyrone derivatives.

Язык: Английский

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