Synlett, Год журнала: 2025, Номер unknown
Опубликована: Фев. 18, 2025
Abstract Transition-metal-catalyzed functionalizations of C–H bonds to construct C–C represent an ideal route in the synthesis valuable organic molecules. In particular, rhodium(III)-catalyzed bond activation offers attractive strategy due its efficiency and step economy for direct functionalization synthesis. Consequently, recent developments this area have assured a high level regioselectivity reactions. Account, we summarized our achievements sp2- sp3-C–H using rhodium catalyst. The scope, limitation, mechanism these reactions been described briefly. 1 Introduction 2 Arylation 2.1 Aromatic C(sp2)–H 2.2 Benzylic C(sp3)–H 2.3 Olefinic 3 Alkenylation Alkylation 4 Heteroarylation 5 Conclusion
Язык: Английский