ChemPlusChem, Год журнала: 2025, Номер unknown
Опубликована: Март 18, 2025
Abstract The open‐shell organic and carbon‐based systems, with either a doublet, triplet or higher spin‐states, play key role in contemporary research, opening potential applicability for several crucial fields. Among those derivatives, specific attention has been given to p ‐phenylene‐based systems derived from the original Thiele hydrocarbon. These stabilize an diradicaloid resonance structure thermally accessible state are quinone‐benzene (Clar's sextet) equilibrium. In our discussion, we very carefully choose examples which focus on fundamental derivatives that merge diatropic subunits, ready two unpaired electrons via dynamic modulation of geometry. This process provides additional factor energy aromatics, mostly responsible stabilization electrons.
Язык: Английский