Efficient Consecutive Synthesis of Fluorinated Isoflavone Analogs, X-Ray Structures, Hirshfeld Analysis, and Anticancer Activity Assessment DOI Creative Commons
Mohammed Salah Ayoup,

Malak Daqa,

Yousef Salama

и другие.

Molecules, Год журнала: 2025, Номер 30(4), С. 795 - 795

Опубликована: Фев. 9, 2025

The synthesis of 7-O-carboxymethyl-4'-fluoroisoflavone 4 and 7-O-carboxymethyl-4'-fluoro-2-trifluormethylisoflavone 7 involved the cyclization 2,4-dihydroxy-4'-fluorodeoxybenzoin 1, followed by 7-O-alkylation with methyl bromoacetate subsequent acid-catalyzed hydrolysis. structures novel compounds were validated using a range techniques, including XRD crystallography (1H, 19F, 13C)-NMR, IR. Only interhalogen contacts detected in 5, while they completely lacking 2 4, owing to presence crystalline ethanol crystal structure. %F…F 5 was 12.2% based on Hirshfeld calculations. aromatic π-π stacking interactions important only but not observed 5. Isoflavones displayed anticancer activity against MCF-7 cancer cells, IC50 values 13.66, 15.43, 11.73 µM, respectively.

Язык: Английский

Botanical Flavonoids: Efficacy, Absorption, Metabolism and Advanced Pharmaceutical Technology for Improving Bioavailability DOI Creative Commons
Lei Hu, Yongming Luo, Jiaxin Yang

и другие.

Molecules, Год журнала: 2025, Номер 30(5), С. 1184 - 1184

Опубликована: Март 6, 2025

Flavonoids represent a class of natural plant secondary metabolites with multiple activities including antioxidant, antitumor, anti-inflammatory, and antimicrobial properties. However, due to their structural characteristics, they often exhibit low bioavailability in vivo. In this review, we focus on the vivo study flavonoids, particularly effects gut microbiome common modifications such as methylation, acetylation, dehydroxylation, etc. These aim change characteristics original substances enhance absorption bioavailability. order improve discuss two feasible methods, namely dosage form modification chemical modification, hope that these approaches will offer new insights into application flavonoids for human health. article, also introduce types, sources, efficacy flavonoids. conclusion, is comprehensive review how

Язык: Английский

Процитировано

5

Phytosomes as a New Frontier and Emerging Nanotechnology Platform for Phytopharmaceuticals: Therapeutic and Clinical Applications DOI Open Access
Suresh Koppula, Bajee Shaik, Srinivas Maddi

и другие.

Phytotherapy Research, Год журнала: 2025, Номер unknown

Опубликована: Март 20, 2025

ABSTRACT A complete investigation into phytosome‐based formulations and innovative nanotechnology is presented in this review. This aims to improve the bioavailability therapeutic effectiveness of herbal components. Phytosomes can significantly increase solubility, absorption, stability compared standard by encapsulating active phytoconstituents phospholipid complexes. unique ability phytosomes overcome limits traditional a potential game changer medicine. study highlights different uses across various health disorders, such as neurodegenerative illnesses, inflammatory conditions, diabetes, cardiovascular diseases, wound healing. The review also discusses treating infectious diseases improving delivery bioactive compounds that have improved anticancer efficacy antibacterial properties. Despite emergence numerous groundbreaking discoveries, substantial barriers remain hinder their widespread application. Challenges must be addressed include stability, large‐scale manufacture, regulatory hurdles, limited clinical translation. examines limitations present practice, mainly focusing on variability bioavailability. crucial need for future research phytosomes, engaging researchers emphasizing continuous evolution promising area

Язык: Английский

Процитировано

1

Efficient Consecutive Synthesis of Fluorinated Isoflavone Analogs, X-Ray Structures, Hirshfeld Analysis, and Anticancer Activity Assessment DOI Creative Commons
Mohammed Salah Ayoup,

Malak Daqa,

Yousef Salama

и другие.

Molecules, Год журнала: 2025, Номер 30(4), С. 795 - 795

Опубликована: Фев. 9, 2025

The synthesis of 7-O-carboxymethyl-4'-fluoroisoflavone 4 and 7-O-carboxymethyl-4'-fluoro-2-trifluormethylisoflavone 7 involved the cyclization 2,4-dihydroxy-4'-fluorodeoxybenzoin 1, followed by 7-O-alkylation with methyl bromoacetate subsequent acid-catalyzed hydrolysis. structures novel compounds were validated using a range techniques, including XRD crystallography (1H, 19F, 13C)-NMR, IR. Only interhalogen contacts detected in 5, while they completely lacking 2 4, owing to presence crystalline ethanol crystal structure. %F…F 5 was 12.2% based on Hirshfeld calculations. aromatic π-π stacking interactions important only but not observed 5. Isoflavones displayed anticancer activity against MCF-7 cancer cells, IC50 values 13.66, 15.43, 11.73 µM, respectively.

Язык: Английский

Процитировано

0