Energy, Год журнала: 2024, Номер 313, С. 133772 - 133772
Опубликована: Ноя. 13, 2024
Язык: Английский
EcoEnergy, Год журнала: 2025, Номер unknown
Опубликована: Фев. 12, 2025
Abstract Over the past few decades, significant advancements have been made in development of low‐temperature liquid electrolytes for lithium batteries (LBs). Ongoing exploration is crucial further enhancing performance these batteries. Solvation chemistry plays a dominant role determining properties electrolyte, significantly affecting LBs at low temperatures (LTs). This review introduces solvation structures and their impact, discussing how promote fast desolvation processes contribute to improvement battery performance. Additionally, various solvent strategies are highlighted refine LTs, including use linear cyclic ethers/esters, as well functional groups within solvents. The also summarizes impact salts containing organic/inorganic anions on chemistry. Characterization techniques discussed, providing comprehensive analysis that offers valuable insights developing next‐generation ensure reliable across wide temperature range.
Язык: Английский
Процитировано
2
Advanced Functional Materials, Год журнала: 2025, Номер unknown
Опубликована: Фев. 14, 2025
Abstract Lithium‐ion batteries (LIBs), known for their high energy density and long cycle life, have become indispensable in everyday applications. Unfortunately, the increasing demand LIBs raises concerns about sustainability of lithium resources. Non‐lithium metal‐ion therefore garnered significant attention due to abundant resources potential cost advantages. Yet, widespread adoption is hindered by limited availability high‐performance cathode materials. Organic electrode materials (OEMs) emerged as promising candidates, owing structural diversity tunability, allowing them accommodate large cations. Despite potential, most OEMs suffer from unsatisfactory cyclability, poor rate performance, low density. This review summarizes recent advancements improving electrochemical performance OEMs, focusing on molecular engineering approaches mitigate dissolution, enhance conductivity The charge storage mechanism current challenges associated with are first discussed. Various strategies designed address these then explored, including linkage improve stability electronic Finally, insights provided future development next‐generation battery technologies beyond LIBs.
Язык: Английский
Процитировано
2
Nanomaterials, Год журнала: 2024, Номер 14(19), С. 1604 - 1604
Опубликована: Окт. 4, 2024
Sodium-ion batteries (SIBs) have garnered significant interest due to their potential as viable alternatives conventional lithium-ion (LIBs), particularly in environments where low-temperature (LT) performance is crucial. This paper provides a comprehensive review of current research on LT SIBs, focusing electrode materials, electrolytes, and operational challenges specific sub-zero conditions. Recent advancements such carbon-based materials titanium-based are discussed for ability enhance ion diffusion kinetics overall battery at colder temperatures. The critical role electrolyte formulation maintaining efficiency stability under extreme cold highlighted, alongside strategies mitigate capacity loss cycle degradation. Future directions underscore the need further improvements energy density durability scalable manufacturing processes facilitate commercial adoption. Overall, SIBs represent promising frontier storage technology, with ongoing efforts aimed overcoming technical barriers enable widespread deployment cold-climate applications beyond.
Язык: Английский
Процитировано
7
Carbon Neutralization, Год журнала: 2025, Номер 4(1)
Опубликована: Янв. 1, 2025
ABSTRACT In military reserve power supplies, there is an urgent need for superior secondary batteries to replace conventional primary batteries, and lithium‐ion (LIBs) emerge as one of the best choices due their exceptional performance. The life LIBs includes cycle calendar life, with spanning from years decades. Accurate prediction crucial optimizing deployment maintenance in applications. Model‐based prognostics are usually established estimate using accelerated aging methods under various storage conditions. This review firstly outlines general prognostic workflow LIBs, analyzes degradation mechanisms, summarizes influencing factors; then, we introduce models, evolving simplistic empirical models (EMs) nonempirical mechanistic (MMs) based on LIB knowledge then traditional hybrid empirical‐mechanistic (trad‐EMMs). Finally, data‐driven (DDMs) machine learning (ML) discussed limitation methods, pure knowledge‐integrated establishing a comprehensive framework assessment. To our knowledge, this paper presents first field, summarizing offering some insights into future model development directions. can facilitate researchers analysis prolongation, thereby better serving application national economic life.
Язык: Английский
Процитировано
1
Chemical Science, Год журнала: 2024, Номер unknown
Опубликована: Янв. 1, 2024
We comprehensively review the research advances in cation migration of sodium layered oxides, systematically revealing fundamental mechanisms and practical modulation strategies for irreversible leading to battery failure.
Язык: Английский
Процитировано
4
Chemical Communications, Год журнала: 2025, Номер unknown
Опубликована: Янв. 1, 2025
This work constructs an artificial interphase by a simple chemical reaction that can induce uniform deposition of sodium, thus achieving high-performance sodium metal batteries.
Язык: Английский
Процитировано
0
Energies, Год журнала: 2025, Номер 18(3), С. 661 - 661
Опубликована: Янв. 31, 2025
Herein, we investigate the performance and safety of four early-stage, commercial Na-ion batteries available in 2024, representing most popular cathode types across research commercialization: polyanion (Na-VPF), layered metal oxide (Na-NMF), a Prussian blue analog (Na-tmCN). The cells deliver wide range energy density with Na-tmCN delivering least (23 Wh/kg) Na-NMF (127 Wh/kg). Na-VPF cell was between (47 Wg/kg). Capacity retention under specified cycling conditions periodic 0 V excursions robust for both cases. Accelerating rate calorimetry (ARC) nail penetration testing finds that do undergo thermal runaway response to abuse, while exhibit only low self-heating rates (<1 °C/min). During these tests, all exhibited off-gassing, so conducted in-line FTIR equipped heated gas detect CO, CO2, CH4, toxic acid gases (HCN, HF, NH3), typical electrolyte components (carbonate ester solvents). Gases similar those detected during Li-ion failures were found addition HCN cell. Our work compares different first time, allowing more holistic comparison tradeoffs emerging 2024.
Язык: Английский
Процитировано
0
Nanoscale, Год журнала: 2025, Номер unknown
Опубликована: Янв. 1, 2025
Hydrogen bubble evolution presents both challenges and opportunities in Zn-based batteries. While induces electrode instability dendrite formation, it can also optimize mass transfer through controlled fluid dynamics.
Язык: Английский
Процитировано
0
Small Methods, Год журнала: 2025, Номер unknown
Опубликована: Март 13, 2025
Abstract Solid polymer electrolytes (SPEs) have garnered significant attention from both academic and industrial communities due to their high safety feature energy density in combination with lithium(Li) metal anode. Nevertheless, practical applications remain constrained by the relatively low room‐temperature ionic conductivity interface issues. Anion‐derived cation‐anion aggregates (AGGs), derived high‐concentration liquid electrolytes, promote a stable solid‐electrolyte interphase layer, which gradually propelled application SPEs. Meanwhile, unique ion transport mechanism of AGGs SPEs also helps enhance conductivity. However, detail progress poorly understood. Here, it is begin concise historical review on development configuration, followed discussion fundamental mechanisms AGGs‐based Then, focused recent developments, design strategies for are summarized detail. Finally, perspectives provided future developments challenges high‐performance
Язык: Английский
Процитировано
0
Energy & Fuels, Год журнала: 2025, Номер unknown
Опубликована: Апрель 8, 2025
Язык: Английский
Процитировано
0