Tetrel Cyclic Polyene Dianions as Precursors for the Pyramidal Clusters and Multi‐Decker Sandwiches DOI
Vladimir Ya. Lee, Olga A. Gapurenko

Chemistry - An Asian Journal, Год журнала: 2025, Номер unknown

Опубликована: Май 16, 2025

Abstract In this review, the current state of affairs in application tetrel cyclic polyene dianions, such as cyclobutadiene dianion and cyclopentadiene dianion, preparation pyramidal clusters (pyramidanes) multi‐decker sandwiches is overviewed. The synthesis both main group element transition metal derivatives latter complexes presented, along with a discussion their peculiar structural bonding features. preference for either pyramidanes or sandwiches, depending on nature central atom (main vs. metal), also discussed.

Язык: Английский

Computational investigation of m-acetamide and 3MPAEA: Characterization, toxicity, and molecular docking and dynamic analyses DOI
Nevin Çankaya, Hanifi Kebiroglu, Serap Yalçın Azarkan

и другие.

Drug and Chemical Toxicology, Год журнала: 2025, Номер unknown, С. 1 - 16

Опубликована: Апрель 28, 2025

In this study, 2-(3-methoxyphenylamino)-2-oxoethyl acrylate (3MPAEA) molecule was synthesized in two steps. the first step, 2-chloro-N-(3-methoxyphenyl)acetamide (m-acetamide) obtained. Density functional theory (DFT) calculations were performed to obtain information about electronic and structural properties of molecules. The Raman Spectrum UV-Visible analysis calculated using Gaussian package program. Additionally, Natural Bond Orbital (NBO) Analysis, Electron Localization Function (ELF), Electrostatic Potential Map (ESP), Average Local Ionization Energy (ALIE), toxicological molecules examined. Simultaneously, molecular docking dynamic analyses conducted investigate interaction m-acetamide 3MPAEA with proteins involved nuclear receptor signaling pathways, stress response initiating events, metabolism, as identified protox analysis. findings aligned results. results obtained provide new insights into these

Язык: Английский

Процитировано

0

Tetrel Cyclic Polyene Dianions as Precursors for the Pyramidal Clusters and Multi‐Decker Sandwiches DOI
Vladimir Ya. Lee, Olga A. Gapurenko

Chemistry - An Asian Journal, Год журнала: 2025, Номер unknown

Опубликована: Май 16, 2025

Abstract In this review, the current state of affairs in application tetrel cyclic polyene dianions, such as cyclobutadiene dianion and cyclopentadiene dianion, preparation pyramidal clusters (pyramidanes) multi‐decker sandwiches is overviewed. The synthesis both main group element transition metal derivatives latter complexes presented, along with a discussion their peculiar structural bonding features. preference for either pyramidanes or sandwiches, depending on nature central atom (main vs. metal), also discussed.

Язык: Английский

Процитировано

0